Field studies of ethoprop movement and degradation in two Florida soils

Unsaturated- and saturated-zone field studies were conducted under two different agricultural conditions in Florida, U.S.A., to measure the movement and degradation of ethoprop.When ethoprop was applied to a sand soil in an orange grove located on the Florida central ridge, soil residues declined with a half-life of 13 days to near the limit of detection (0.01 μg g⁻¹ within 2 months. Ethoprop residues were generally contained in the upper 2 m of soil. Although low levels of ethoprop were found in four groundwater samples within the first 3 months after application, the cause of these isolated and transient residues could not be determined. The data show that there was no widespread plume of ethoprop residues beneath or downgradient from the treated area.On a flatwood soil on the west coast of Florida, ethoprop was incorporated into raised beds and protected by a plastic mulch in which tomatoes were grown. When the plastic mulch was present, ethoprop soil residues declined with a half-life of 40 days and were confined to the upper 0.3 m of soil. After the mulch was removed at crop harvest, the remaining ethoprop dissipated with a half-life of 12 days. Groundwater residues in excess of 1 μg L⁻¹ were confined to a single sample collected after the well had been damaged during a rototilling operation. Resides of < 1 μg L⁻¹ were present in three later samples from this well. At the sampling interval where the highest residues were detected in the damaged well, ethoprop residues of < 1 μg L⁻¹ were also found in three other wells but no residues were detected in these wells in later samples.     

Removal of low concentrations of carbon tetrachloride in compost-based biofilters operated under methanogenic conditions.

Research was performed to demonstrate the removal of carbon tetrachloride (CT) using compost biofilters operated under methanogenic conditions. Biofilters were operated at an empty-bed residence time of 2.8 minutes using nitrogen as the atmosphere. Hydrogen and carbon dioxide were supplied as an electron donor and carbon source, respectively, during acclimation of the bed medium microbes. Once methanogenesis was demonstrated, CT flow to the biofilter was established. Biofilters were operated over a CT concentration range from 20 to 700 ppbv for 6 months. Bed medium microbes were able to remove up to 75% of the inlet CT. At excessively high CT concentrations (> 500 ppmv), methane production and hydrogen utilization by the bed medium microbes appeared to be inhibited. CT removal by the biofilter decreased when the hydrogen supply was removed from the biofilter inlet, indicating that hydrogen acted as the electron donor for reductive dechlorination. The removal efficiency and relatively low empty bed residence times demonstrated by these laboratory-scale biofilters indicate that anaerobic biofiltration of CT may be a feasible full-scale process.     

FLOW PERSISTENCE AS A MODIFIER OF SEASONAL RUNOFF PATTERNS1

ABSTRACT: The effect of flow persistence on seasonal patterns of watershed runoff was modeled by using runoff of the immediate antecedent month as an index. Monthly runoff was expressed as a function of monthly rainfall, season of the year, and runoff of the antecedent month. The three independent variables were expressed functionally as sliding polynomials, thus producing a piece-wise, form-free, three-dimensional causative structure. A model form allowing complete interactivity of the three independent variables could not be optimized because of insufficient data with high values of both antecedent runoff and monthly rainfall. A model with reduced interactivity was successfully optimized. Data sets from five watersheds ranging from 0.14 to 398 square miles were analyzed. Results were presented as a series of contour maps that showed contours of monthly runoff in the data space of season and monthly rain. In the series of maps, the patterns of the runoff contours changed with changing values of antecedent runoff. During the wet season of the year the contours changed significantly with antecedent runoff, but changes in the dry season were minimal. The quantitative change of runoff was more readily portrayed with cross-sections through the contoured surfaces.     

The Kirton Adaption - Innovation Inventory: A re-examination of the factor structure

Although the Kirton Adaption - Innovation Inventory (KAI) has almost always been used as a single scale purporting to measure a dimension of cognitive style, the KAI Manual characterizes three factors. This paper provides further confirmatory evidence of the structure of the three-factor model and of the high reliability coefficients of the three subscales. However, it questions whether three factors are sufficient and examines four- and five-factor models. Evidence is provided that the ‘O’ subscale in the orthodox three-factor model contains two conceptual elements, a major component concerned with idea generation and a minor component concerned with preference for stability/change. A four-factor model of KAI is proposed and an argument is advanced which leads to concern about the idea generation element of the ‘O’ subscale as a measure purely of cognitive style. Some implications for the development of the KAI are outlined.