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101.
Ahmed E. Bishara Habib I. Shaban Hamad Al-Adwani Sami H. Ali 《Journal of Polymers and the Environment》2001,9(4):137-147
A novel copolymer system has been synthesized using methyl hydroquinone diacetate (MHQDA), 1,4 naphthalene dicarboxylic acid (1,4 NDCA), and polybutylene terephthalate (PBT) using the melt polymerization technique. The optimum kinetic parameters pertinent to this system are reported in this study. A simple second-order reaction sequence summarizes catalyzed and uncatalyzed reactions between MHQDA, 1,4 NDCA, and PBT. The kinetic parameters for the copolymerization reaction were determined using a new second-order model. This technique was used to compute the moles of acetic acid generated in the polymerization process. The model was compared to that of the experimentally determined data. Close comparison (percentage error of less than 5%) was obtained between the experimental and theoretical data. The kinetic data support block copolyester formation. The thermal data also supports formation of block polymers. 相似文献
102.
Timothy Boe Worth Calfee Paul Lemieux Shannon Serre Ahmed Abdel-Hady Mariela Monge Denise Aslett Bruce Akers John Howard 《补救:环境净化治理成本、技术与工艺杂志》2023,33(4):379-387
This study evaluated the microbiocidal efficacy of a cleaning and disinfection (C&D) treatment using stainless-steel coupons applied to three common types of animal mortality transport vehicles when exposed to agricultural conditions. Metal test coupons, inoculated with bacteriophage MS2, were affixed to the undercarriage of three types of animal mortality transport vehicles at various locations. Coupons were grimed by maneuvering the test vehicles down a series of wet dirt roads. Coupons were attached and extracted at various points to evaluate C&D performance with and without grime. C&D efficacy using a water-supplied pressure washing system and a dilute sodium hypochlorite (NaOCl) solution was determined by comparing the difference in recovered viable virus between positive control coupons and test coupons. The results demonstrated a relatively high surface decontamination efficacy, with all but one location showing >5 log reduction of MS2. Coupons located on the roll-off truck's inside-back bumper contained the highest level of grime and resulted in a 4 log reduction of MS2. There was no significant difference in C&D efficacy across vehicle types, but locations impacted by grime and lack of accessibility achieved lower efficacies on average. These findings suggest that common C&D protocols, when applied to farm mortality transport vehicles, are effective. Hard-to-access locations containing high levels of grime may be candidates for additional targeted treatment. 相似文献
103.
Sihem Guesmi Amel Raouafi Ismail Amri Ahmed Hicham Hamzaoui Abdennacer Boulila Faouzi Hosni Haitham Sghaier 《Environmental science and pollution research international》2020,27(6):5661-5669
The majority of dosimeters currently in use are synthetic and very expensive. Therefore, the study of the dosimetric characteristics of polyphenolic extracts of xerophytes is useful because drought stress causes an increase in the production of these cheap and natural compounds containing benzene rings. Here, the polyphenolic compounds were extracted from Rhamnus lycioides which was collected from Bou-Hedma National Park in Tunisia and identified using liquid chromatography-mass spectrometry (LC-MS). We investigated the impact of cobalt-60 (60Co) irradiation (0–30 kilogray (kGy)) on the color parameters of polyphenolic extracts of R. lycioides using the Konica Minolta CR 300 portable colorimeter and UV–Visible spectroscopy. The structural and morphological characteristics of the irradiated extracts were assessed using Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) technique and scanning electron microscopy (SEM). Overall, our results suggest that exposure to ionizing radiation (IR) of the polyphenolic components of the xerophyte R. lycioides has produced significant dose-dependent changes in their optical and morphological properties. Thus, these extracts can be valorized as biodosimeters in the dose range from 5 to 25 kGy. 相似文献
104.
Khan Fahad Saleem Ahmed Mubarak Nabisab Mujawar Tan Yie Hua Karri Rama Rao Khalid Mohammad Walvekar Rashmi Abdullah Ezzat Chan Mazari Shaukat Ali Nizamuddin Sabzoi 《Environmental science and pollution research international》2020,27(35):43526-43541
Environmental Science and Pollution Research - Substantial discharge of hazardous substances, especially dyes and heavy metal ions to the environment, has become a global concern due to... 相似文献
105.
Murshed Muntasir Nurmakhanova Mira Elheddad Mohamed Ahmed Rizwan 《Environmental science and pollution research international》2020,27(31):38951-38973
Environmental Science and Pollution Research - This study examines the Environmental Kuznets Curve (EKC) hypothesis in the context of 12 members of the OPEC by utilizing data on both the aggregate... 相似文献
106.
Ahmed AS Webster L Pollard P Davies IM Russell M Walsham P Packer G Moffat CF 《Journal of environmental monitoring : JEM》2006,8(2):307-316
The distribution and composition of hydrocarbons in sediment from the Fladen Ground oilfield in the northern North Sea have been investigated. The total PAH concentrations (2- to 6-ring parent and alkylated PAHs, including the 16 US EPA PAHs) in sediments were relatively low (<100 microg kg(-1) dry weight). The PAH, the Forties crude and diesel oil equivalent concentrations were generally higher in sediment of fine grain size and higher organic carbon concentration. PAH distributions and concentration ratios indicated a predominantly pyrolytic input, being dominated by the heavier, more persistent, 5- and 6-ring compounds, and with a high proportion of parent PAHs. The n-alkane profiles of a number of the sediments contained small, high boiling point, UCMs, indicative of weathered oil arising from a limited petrogenic input. The geochemical biomarker profiles of the sediments that contained UCMs showed a small bisnorhopane peak and a high proportion of norhopane relative to hopane, indicating that there was contamination from both Middle Eastern and North Sea oils. Therefore contamination was not directly as a result of oil exploration activity in the area. The most likely source of petrogenic contamination was from general shipping activity. 相似文献
107.
Ahmed A. Al-Taani Nazem M. El-Radaideh Wesam M. Al Khateeb Abeer Al Bsoul 《Environmental monitoring and assessment》2018,190(10):604
Jordan relies heavily on reservoirs building and development to cope with water supply challenges, where monitoring and assessment of reservoir water quality are critically important for the sustainable use of these water supplies. Mujib Dam is an important water supply source in central western Jordan. Evaluation of water quality parameters and their spatial distributions (vertical and horizontal) showed near-neutral pH values with nearly similar values from surface to bottom. The vertical profile of DO and TDS in the dammed reservoir showed slight decreasing trends with increasing depth. Although Ca, Mg, Na, and K concentrations varied slightly with depths, their variations showed no trends. Similarly, the vertical and horizontal distribution patterns of Cl, SO4, HCO3, NO3, and PO4 in Mujib reservoir water showed insignificant variations in surface water layer and relatively unchanged values or decreasing trends through the water column. Higher values of TN have been observed, especially in the western part, suggesting that agricultural activities and livestock farming in the upstream catchment are impacting water quality. Results revealed that weathering and dissolution of rocks are the major source of water chemistry. The majority of trace metal levels (Cd, Cr, Cu, Fe, Mn, Pb, Zn, Co, Ni, Sr, and B) in water showed relatively similar surface and bottom values. The concentrations of COD and BOD5 in surface water were relatively low with higher concentrations observed in the northwestern corner, coincided with higher levels of chlorophyll a. The average ratio of TN to TP in surface water suggests that phosphorus is the limiting factor for the algal blooms, whereas the average chlorophyll a level in surface water indicates oligo-mesotrophic water. 相似文献
108.
109.
Aarif H. El-Mubarak Ahmed I. Rushdi Khalid F. Al-Mutlaq Abdulqader Y. Bazeyad Staci L. M. Simonich Bernd R. T. Simoneit 《Environmental science and pollution research international》2014,21(1):558-567
In an effort to assess the occurrence and sources of polycyclic aromatic hydrocarbons (PAHs) in the ambient air of Riyadh, Saudi Arabia, PM10 samples were collected during December 2010. Diagnostic PAH concentration ratios were used as a tool to identify and characterize the PAH sources. The results reflect high PM10 and PAH concentrations (particulate matter (PM)?=?270–1,270 μg/m3). The corresponding average PAH concentrations were in the range of 18?±?8 to 1,003?±?597 ng/m3 and the total concentrations (total PAHs (TPAHs) of 17 compounds) varied from 1,383 to 13,470 ng/m3 with an average of 5,871?±?2,830 ng/m3. The detection and quantification limits were 1–3 and 1–10 ng/ml, respectively, with a recovery range of 42–80 %. The ratio of the sum of the concentrations of the nine major non-alkylated compounds to the total (CPAHs/TPAHs) was 0.87?±?0.10, and other ratios were determined to apportion the PM sources. The PAHs found are characteristic for emissions from traffic with diesel being a predominant source. 相似文献
110.
Rim Khlifi Pablo Olmedo Fernando Gil Molka Feki-Tounsi Bouthaina Hammami Ahmed Rebai Amel Hamza-Chaffai 《Environmental science and pollution research international》2014,21(3):2032-2042
Chronic exposure to heavy metals has long been recognized as being capable of increasing head and neck cancer (HNC) incidence, such as laryngeal (LC) and nasopharyngeal (NPC), among exposed human populations. The aim of the present study was to evaluate the concentrations of arsenic (As) and cadmium (Cd) in the blood of 145 patients (LC and NPC) and 351 controls in order to establish a potential relationship between these factors and the occurrence of LC and NPC. Mean blood levels of As and Cd in patients (5.67 and 3.51 μg/L, respectively) were significantly higher than those of controls (1.57 and 0.74 μg/L, respectively). The blood levels of As and Cd were mostly significantly higher than those of controls (p?<?0.05) after controlling the other risk factors of HNC including tobacco smoking and chewing, and alcohol drinking. Cd levels in blood increase significantly with the number of occupational exposure years for patients (p?<?0.05). However, seafood was not found to be contributing as an exposure source. Among these risk factors, smoking (>30 pack years) and occupational exposure (>20 years) presented the most significant association with HNC (OR?=?10.22 and 10.38, respectively, p?<?0.001). Cd level in blood sample of cases that are occupationally exposed/tobacco users (smokers and chewers) were higher than that of non-occupationally exposed/nontobacco users (p?<?0.001). The logistic regression model illustrated that HNC (LC?+?NPC) was significantly associated with blood levels of As (OR?=?2.41, p?<?0.001) and Cd (OR?=?4.95, p?<?0.001). 相似文献