Application of a permethrin immunosorbent assay method to residential soil and dust samples

A low-cost, high throughput bioanalytical screening method was developed for monitoring cis/trans-permethrin in dust and soil samples. The method consisted of a simple sample preparation procedure [sonication with dichloromethane followed by a solvent exchange into methanol:water (1:1)] with bioanalytical detection using a magnetic particle enzyme-linked immunosorbent assay (ELISA). Quantitative recoveries (83–126 %) of cis/trans-permethrin were obtained for spiked soil and dust samples. The percent difference of duplicate ELISA analyses was within ± 20 % for standards and ± 35 % for samples. Similar sample preparation procedures were used for the conventional gas chromatography/mass spectrometry (GC/MS) analysis except that additional cleanup steps were required. Recoveries of cis/trans-permethrin ranged from 81 to 108 % for spiked soil and dust samples by GC/MS. The ELISA-derived permethrin concentrations were highly correlated with the GC/MS-derived sum of cis/trans-permethrin concentrations with a correlation coefficient (r) of 0.986. The ELISA method provided a rapid qualitative screen for cis/trans-permethrin in soil and dust while providing a higher sample throughput with a lower cost as compared to the GC/MS method. The ELISA can be applied as a complementary, low-cost screening tool to prioritize and rank samples prior to instrumental analysis for exposure studies.     

Variations in the Emissions of Volatile Organic Compounds from the Toner for a Specific Photocopier

ABSTRACT

A laboratory thermal desorption apparatus was used to measure emissions from a number of nominally identical photocopier toners—manufactured to meet the specifications of one specific model copier—when these toners were heated to fuser temperature (180-200 °C). The objective was to assess how potential volatile organic compound (VOC) emissions from the toner for a given copier can vary, depending upon the production run and the supplier. Tests were performed on a series of toner (and associated raw polymer feedstock) samples obtained directly from a toner manufacturer, representing two production runs using a nonvented extrusion process, and on toner cartridges purchased from two local retailers, representing three different production lots (histories unknown). The results showed that the retailer toners consistently had up to 350% higher emissions of some major compounds (expressed as |ig of compound emit-ted/g of toner), and up to 100% lower emissions of others, relative to the manufacturer toners (p ≤ 0.01). The manufacturer toners from one production run had emissions of certain compounds, and of total VOCs, that were modestly higher (13-18%) than those from the other run (p ≤ 0.01). The emission differences between the retailer and manufacturer toners are probably due to differences     

Social organization in deer: Implications for localized management

Populations of white-tailed deer (Odocoileus virginianus) inhabiting many state and national parks and suburban areas have grown to the point that they conflict with human activities. Conflicts range from destruction of vegetation through browsing to public perception that diseases carried by deer pose threats to human health. Traditional modes of hunting to control populations are inappropriate in many of these areas because of intense human development and activity. This article explores an alternative approach for population reduction based on deer social organization. Female white-tailed deer are highly philopatric and female offspring remain near their dams for life. This suggests that a population expands slowly as a series of overlapping home ranges in a form analogous to the petals on a rose. Incorporating the rose petal concept into a model of population growth shows that removal of deer by family unit can potentially alleviate conflicts in localized areas for as many as 10–15 yr.     

Cultural landscapes and environmental ethics: The case of puslinch township's historic roadside trees

Conclusion I have argued, then, that is simplistic and potentially dangerous to suppose that a contractarian model can adequately account for all of the moral relations in agriculture or serve singularly as a basis for policy. Conversely, I do not naively argue that we ought simply to replace a contractarian based agricultural ethic with an ethic of care such as the one I have outlined. A single farmer may be a spouse, parent, son or daughter, caretaker of land, keep of animals, business operator and partner, employer, processor, and consumer. Agriculture itself encompasses all of these relations. Both our ethical systems and social and economic policies must reflect and build on this diversity of contexts and associated practices.     

Nitrogen in aquatic ecosystems

Aquatic ecosystems respond variably to nutrient enrichment and altered nutrient ratios, along a continuum from fresh water through estuarine, coastal, and marine systems. Although phosphorus is considered the limiting nutrient for phytoplankton production in freshwater systems, the effects of atmospheric nitrogen and its contribution to acidification of fresh waters can be detrimental. Within the estuarine to coastal continuum, multiple nutrient limitations occur among nitrogen, phosphorus, and silicon along the salinity gradient and by season, but nitrogen is generally considered the primary limiting nutrient for phytoplankton biomass accumulation. There are well-established, but nonlinear, positive relationships among nitrogen and phosphorus flux, phytoplankton primary production, and fisheries yield. There are thresholds, however, where the load of nutrients to estuarine, coastal and marine systems exceeds the capacity for assimilation of nutrient-enhanced production, and water-quality degradation occurs. Impacts can include noxious and toxic algal blooms, increased turbidity with a subsequent loss of submerged aquatic vegetation, oxygen deficiency, disruption of ecosystem functioning, loss of habitat, loss of biodiversity, shifts in food webs, and loss of harvestable fisheries.     

HEAVY RAINSTORMS IN CHICAGO: INCREASING FREQUENCY,ALTERED IMPACTS,AND FUTURE IMPLICATIONS1

ABSTRACT: Operations of a dense raingage network in the Chicago area since 1989 provided data to assess the temporal and spatial distributions of heavy rainstorms. The 12‐year average was 4.4 storms per year, 40 percent more than in the 1948 to 1980 period, reflecting an ongoing Midwestern increase in heavy rains. The total rainfall from the 53 heavy rainstorms maximized over the city, reflecting previous observations that the influence of the city and Lake Michigan on the atmosphere causes an increase in heavy rains. Impacts from the record high number of eight storms in 2001 revealed that efforts to control flooding including the Deep Tunnel system, had reduced street and basement flooding in the moderate intensity storms, but the two most intense storms, each with 100‐year rainfall values, led to excessive flooding and a need to release flood waters into Lake Michigan. Results suggest continuing increases in the number of heavy rainstorms in future years, which has major implications for water managers in Chicago and elsewhere.     

The role of the social and physical environment in privacy maintenance among the Iban of Borneo

Altman's (1977) theory of privacy as a cultural universal is examined by analyzing the privacy mechanisms of the Iban of Sarawak (Borneo). The Sarawak Dayaks live in communal longhouses which appear to offer little physical opportunity for individual privacy. However, the authors found that social mechanisms were utilized to obtain privacy. Thus, despite the communal physical environment of the Sarawak Iban, support is found for a system of privacy. The implications of these findings for other cultures and settings where the physical environment appears to limit control of privacy is discussed.     

WATER QUALITY SIMULATION AND PUBLIC LAW 92–500 Case Study: Southwestern Illinois1

ABSTRACT: Section 208 of the Federal Water Pollution Control Act Amendments of 1972 has provided the Southwestern Illinois Metropolitan and Regional Planning Commission (SIMAPC) with a unique opportunity for comprehensive planning of the region's water quality. SIMAPC initiated the 208 study by researching available technology for the analysis of point and nonpoint sources of pollution and establishing criteria by which to judge the various technniques. This led to SIMAPC'S choice of continuous simulation of stream and reservoir water quality as the most appropriate analytical tool for their needs. A continuous simulation model was calibrated and verified on three basins in the SIMPAC region. It was then used to produce load source analysis, pollution event frequency analysis, and pollution event duration analysis for ten pollutants under existing stream conditions and then under alternative future conditions. These results enabled the weighting of pollutant sources, analysis of the effectiveness of control measures, and quantitative analysis of the marginal benefit of each alternative.