High Canadian waste disposal rates necessitate landfill gas monitoring and accurate forecasting. CO2 estimates in LandGEM version 3.02 currently rest on the assumptions that CO2 is a function of CH4, where the two gases make up nearly 100% of landfill gas content, leading to overestimated CO2 collection estimates. A total of 25 cases (five formulas, five approaches) compared annual CO2 collection at four western Canadian landfills. Despite common use in literature, the 1:1 ratio of CH4 to CO2 was not recommended to forecast landfill gas collection in cold climates. The existing modelling approach significantly overestimated CO2 production in three of four sites, resulting in the highest residual sum of squares. Optimization resulted in the most accurate results for all formulas and approaches, which had the greatest reduction in residual sums of squares (RSS) over the default approach (60.1 to 97.7%). The 1.4 Ratio approach for Lo:Lo-CO2 yielded the second most accurate results for CO2 flow (mean RSS reduction of 50.2% for all sites and subsection models). The annual k-modified LandGEM calculated k’s via two empirical formulas (based on precipitation) and yielded the lowest accuracy in 12 of 20 approaches. Unlike other studies, strong relationships between optimized annual k’s and precipitation were not observed.
The Atacama Desert in Northern Chile is one of the most arid places on earth. However, fog occurs regularly at the coastal
mountain range and can be collected at different sites in Chile to supply settlements at the coast with freshwater. This is
also planned in the fog oasis Alto Patache (20°49′S, 70°09′W). For this pilot study, we collected fog water samples in July
and August 2008 for chemical analysis to find indications for its suitability for domestic use. 相似文献
ABSTRACTEXPOLIS is a European multicenter (Athens, Basel, Grenoble, Helsinki, Milan, and Prague) air pollution exposure study. It is the first international, population-based, large-scale study, where personal exposures to PM2 5 aerosol particles (together with volatile organic compounds and carbon monoxide) are being monitored. EXPOLIS is performed in six different centers across Europe, the sampled aerosol concentrations vary greatly, and the mi-croenvironmental samples are not collected with the same equipment as the personal samples. Therefore careful equipment selection, methods development and testing, and thorough quality assurance and quality control (QA & QC) procedures are essential for producing reliable and comparable PM2.5 data. This paper introduces the equipment, the laboratory test results, the pilot results, the standard operating procedures, and the QA & QC procedures of EXPOLIS. Test results show good comparability and repeatability between personal and microenvironmen-tal monitors for PM2.5 at different concentration levels measured across Europe in EXPOLIS centers. 相似文献
Thermodegradation of organometallics viz. RMX (where M = Mg, Ti, Pd, Sn, Si, Al; and X =halogen atom) provides corresponding haloorganics i.e. RX. 1,2‐Shifts of H and Cl on the carbene species like CH2F. CF and CFCL2, CF produced from R. CF. Si F3 (R = CH2F, CFCl2) are preferred to that of fluorine. The thermolysis of R.CF2. Si Cl3 (R = CH2F) produces chloroolefins via halogen exchange. Major products of thermal degradation of poly (vinyl chloride) (PVC) are HCl and benzene but the mechanism of PVC thermodegradation is still a matter of dispute. The thermal cracking of lignins yields substituted phenols. 相似文献
ABSTRACT: The Nonlinear Risk-Benefit (NRB) Algorithm includes risk as one of the objectives in a multiple-objective optimization problem. The NRB Algorithm is derived by extending the Surrogate Worth Trade-Off method to quadratic programming. This category of problem is common in water resources planning and design, especially multipurpose reservoir systems. Consequently, an example is given using the algorithm for optimally operating a multipurpose reservoir. 相似文献