Safe use of refrigerants for process applications

This paper examines safety issues, with emphasis on central refrigeration plant for process applications. Plantroom hazards including refrigerant leakage, excess pressure, fire and noise are covered. It is concluded that routine surveys which are being conducted in connection with the chlorofluorocarbon and hydrochlorofluorocarbon phase-outs present an opportunity for examining safety issues.     

Time series analysis of coal mine accident experience

This study investigates several forecasting techniques that can be useful to mine safety managers for studying mine accident rate behavior. Three time series models were studied for extrapolation of accident rates. These models are applied to historical accident incidence data from a coal mine. Further, a method is presented for evaluating the three models for the selection of an appropriate model. For this particular mine application, it is concluded that the more complex Box-Jenkins ARMA model as well as first order autoregressive model do not give better results than the simple exponential smoothing model. However, when the random variations or autocorrelations in the accident experience rates between periods are different, the models may predict differently. As such, specific models must be developed for each mine on the basis of statistical analysis of the mine accident experience data over time. Moreover, the importance of incorporating human judgement to interpret the results of statistical forecasting cannot be overemphasized. Integration of policy or operating changes, which may impact mine safety performance, with statistical forecasting techniques is essential to arrive at a realistic prediction of future performance.     

Evaluation of a chemical stabilization process

Environmental Resources Management (ERM) performed an evaluation of a biosolids chemical stabilization process known as BIO*FIX®, marketed by Bio Gro Systems, Inc., of Annapolis, Maryland. The purpose of the evaluation was (1) to assess major characteristics of the process and its final product, (2) to determine the quantity and final disposition of all components in the incoming biosolids, and (3) to determine if the process conforms to new regulations promulgated and administered by the U.S. Environmental Protection Agency (EPA) titled “Standards for the Use or Disposal of Sewage Sludges” (40 CFR Part 503). The BIO*FIX® chemical stabilization process involves the addition of calcium oxide (CaO) to dewatered biosolids at rates that achieve the pathogen reduction and vector attraction reduction requirements of the 503 program while creating a marketable end product used as an agricultural amendment. ERM's project involved the testing of four process streams in order to create a mass balance on the process. Laboratory analyses were performed on samples of the dewatered biosolids, the chemically-stabilized end product, and the scrubber water effluent. The primary components of concern tested in the above process streams were ammonia, metals, odorous compounds, particulate matter, and organic matter. Through the tests described in the article, ERM drew the following conclusions: (1) The major gaseous pollutant resulting from the BIO*FIX® process is gaseous ammonia. The total gaseous ammonia released from the product depends on the ammonia nitrogen content of the biosolids, and pH and temperature levels reached in the process. Additional ammonia is emitted when the end product is loaded in trucks and stored. Any gaseous ammonia remaining in the end product after processing will slowly dissipate over time. (2) Other potential odor pollutants such as hydrogen sulfide (H₂S) and mercaptans were found to be below detectable levels in the uncontrolled exhaust gas. (3) Metals were not found in the exhaust gas in any detectable quantities. They would not be expected to volatilize during the process. Particulate matter emissions were found to be very low. (4) The pathogen reduction and vector attraction reduction requirements of the 40 CFR 503 regulations were met or exceeded. (5) Finally, through observations and tests, ERM found that the BIO*FIX® chemical stabilization process provides for a simple, viable, and effective conversion of biosolids into a beneficial use product in compliance with all pertinent regulations.     

The costs to farmers and estate owners of public access to the countryside

This paper considers the external costs of public access on privately‐owned farm and estate land in Scotland. The increased costs and reductions in income associated with public access are found to be highly variable and site‐specific, with the main effects on land in areas of high population density or high scenic quality, or with recreational attributes. Although costs were on average higher for estates, reflecting their larger area and recreational potential, on a per‐hectare basis the costs of access were greater for the farm sector. Whilst much of the public access exists through de facto rights on open‐access land, there was evidence for an increasing commercialization of open‐air recreation, particularly with respect to more specialized activities. The discussion considers the extent to which the costs of access for land managers are reflected in policies determining the public provision of countryside access.     

The Worldwide Availability of Phosphate Rock

The US Bureau of Mines has investigated the resource potential of 201 phosphate mines and depositee in 28 market economy countries and 17 mines and deposits in the USSR and China. The 201 mines and deposits contain an estimated 34.2 billiong tonnes (t) of recoverable phosphate rock (at the demonstrated resource level), with Morocco and Western Sahara accounting for 61% (21 billion t) and with the USA accounting for 19% (6.4 billion t). The 17 mines and deposits evaluated in the USSR and China contain approximately 1.5 billion t of potentially recoverable phosphate rock. Potential annual capacity from low-cost, high-grade producing mines in the USA is estimated to decline significantly during the latter half of the next decade, and the US phosphate fertilizer industry will have to obtain phosphate rock by developing new, higher-cost, lower-grade mines or import phosphate rock to satisfy anticipated demand in the next century. Of the world's new production capacity that are likely to be developed over the next decade, slightly over one-third could be produced at an estimated 1981 cost of $40/t or less, and about two-thirds would cost in the $40 to $50 per tonne range (including a 15% rate of return). In comparison, most of the competing phosphate rock from producing mines in Morocco could be produced for less than $40/t.     

BEDLOAD TRANSPORT IN A POOL-RIFFLE SEQUENCE OF A COASTAL ALASKA STREAM1

ABSTRACT: A Helley-Smith pressure differential bedload sampler was used to measure bedload transport at consecutive riffle sections of a riffle-pool-riffle sequence on Bambi Creek, a small (154 ha), second-order stream on Chichagof Island, Alaska, during four storms over a 2-year period. Maximum bedload transport rate measured was 4920 kg/h at a streamflow of 2.35 m³/s corresponding to a storm having a 5-year return interval. Transport of larger sediment (> 8 mm) varied systematically with streamflow at the two sampling locations. At flows up to approximately bankfull, transport of large sediment was greatest at the upstream site; at flows above bankfull, transport of large sediment was greatest at the downstream site. The net import of large sediment to the pool during moderate stormflows and net export of large sediment from the pool during flows above bankfull may be related to a “convergence” or “reversal” of competence between the upstream riffle and subsequent pool at flows approximating bankfull stage. Cross-sections monitored within the study reach indicate that stormflows resulted in net filling of the riffle sections and net scour of the pool; periods of low streamflow resulted in net scour of the riffles and net filling of the pooL     

FRACTIONAL DIFFERENCING MODELING IN HYDROLOGY1

ABSTRACT: Fractional differencing is a tool for modeling time series which have long-term dependence; i.e., series in which the correlation between distant observations, though small, is not negligible. Fractionally differenced ARIMA models are formed by permitting the differencing parameter d in the familiar Box-Jenkins ARIMA(p, d, q) models to take nonintegral values; they permit the simultaneous modeling of the long-term and short-term behavior of an observed time series. This paper discusses the usefulness of fractional differencing to time-series modeling, with emphasis on hydrologic applications. A methodology for fitting fractionally differenced ARIMA models is described, and examples are presented.     

Impacts of hydroelectric development on riparian vegetation in the Sierra Nevada region,California, USA

Fourteen streams in the Sierra Nevada in the USA were sampled to determine whether diversions of streamflow for hydroelectric development had caused significant changes in riparian vegetation. Several streams showed significant differences in vegetation cover, community composition, or community structure between pairs of diverted and undiverted reaches. On some streams, environmental conditions rather than streamflow diversions may have been responsible for vegetation differences. Streams in the Sierra Nevada respond individualistically to diversions. Prediction of vegetation responses must take into consideration environmental characteristics of specific stream reaches.     

ALTERNATIVES TO THE USE OF AGRICULTURAL DRAINAGE WELLS1

ABSTRACT: A large number of agricultural drainage wells (ADWs) are located in north-central Iowa. These wells permit sediments, pesticides, nitrate, and bacteria in surface and subsurface drainage water to enter regional aquifers that are currently being used for drinking-water supplies, mostly by rural families and communities. This paper reports some possible alternatives to control the entry of surface and subsurface drainage waters into groundwater systems, and describes a methodology to make comprehensive economic feasibility studies of alternative drainage outlets. The estimated cost of providing main subsurface drains varied from $220 to $960 per hectare. If the use of ADWs was completely eliminated without providing alternative drainage, it is estimated that the average annual loss to the farmers of the area would be at least $270 per hectare in reduced crop yields. Of course, losses would be weather dependent and highly variable. Management practices to reduce the pollutant load in water draining to ADWs are also discussed.