Levels and patterns of C1-C4/C9 organic nitrates were measured for the first time in Antarctica. The sampling was done by adsorptive enrichment on Tenax TA followed by thermodesorption cold-trap high resolution capillary gas chromatography with electron capture detection. 2-70 1 air on-column have been analyzed this way. C1-C9 alkyl mononitrates, C2-C4 alkyl dinitrates, C2-C4 hydroxy alkyl nitrates, and halocarbons could be identified in air samples collected near the German Neumayer Research Station, Antarctica, in February 1999. Volatile biogenic and anthropogenic halocarbons were used to assess the origin of the air parcels analyzed. The average concentration measured for sigmaC2-C6 alkyl nitrates was in the range of 9.2 +/- 1.8 ppt(v), while the sum of the mixing ratios of six C2-C4 hydroxy alkyl nitrates was in the range of 1.1 +/- 0.2 ppt(v). Moreover, C2-C4 alkyl dinitrates were found at levels near the detection limit of 0.1-0.5 ppt(v). The concentrations of organic nitrates found in Antarctic air represent ultimate baseline levels due to chemical and physical loss processes during long-range transport in the air. The South Atlantic and the Antarctic Ocean as a general secondary source for organic nitrates in terms of an air/sea exchange equilibrium has to be evaluated yet, but it seems logical. Our results confirm the common assumption that there are no biogenic marine sources of C2-C9 organonitrates. We have found a level of > 80 ppt(v) for methyl nitrate. This level if it can be confirmed in a systematic survey requires a strong biogenic source of methyl nitrate in the Antarctic Ocean. 相似文献
Here, we review Charles Darwin’s relation to beetles and developments in coleopteran systematics in the last two centuries.
Darwin was an enthusiastic beetle collector. He used beetles to illustrate different evolutionary phenomena in his major works,
and astonishingly, an entire sub-chapter is dedicated to beetles in “The Descent of Man”. During his voyage on the Beagle,
Darwin was impressed by the high diversity of beetles in the tropics, and he remarked that, to his surprise, the majority
of species were small and inconspicuous. However, despite his obvious interest in the group, he did not get involved in beetle
taxonomy, and his theoretical work had little immediate impact on beetle classification. The development of taxonomy and classification
in the late nineteenth and earlier twentieth century was mainly characterised by the exploration of new character systems
(e.g. larval features and wing venation). In the mid-twentieth century, Hennig’s new methodology to group lineages by derived
characters revolutionised systematics of Coleoptera and other organisms. As envisioned by Darwin and Ernst Haeckel, the new
Hennigian approach enabled systematists to establish classifications truly reflecting evolution. Roy A. Crowson and Howard
E. Hinton, who both made tremendous contributions to coleopterology, had an ambivalent attitude towards the Hennigian ideas.
The Mickoleit school combined detailed anatomical work with a classical Hennigian character evaluation, with stepwise tree
building, comparatively few characters and a priori polarity assessment without explicit use of the outgroup comparison method.
The rise of cladistic methods in the 1970s had a strong impact on beetle systematics. Cladistic computer programs facilitated
parsimony analyses of large data matrices, mostly morphological characters not requiring detailed anatomical investigations.
Molecular studies on beetle phylogeny started in the 1990s with modest taxon sampling and limited DNA data. This has changed
dramatically. With very large data sets and high throughput sampling, phylogenetic questions can be addressed without prior
knowledge of morphological characters. Nevertheless, molecular studies have not lead to the great breakthrough in beetle systematics—yet.
Especially the phylogeny of the extremely species rich suborder Polyphaga remains incompletely resolved. Coordinated efforts
of molecular workers and of morphologists using innovative techniques may lead to more profound insights in the near future.
The final aim is to develop a well-founded phylogeny, which truly reflects the evolution of this immensely species rich group
of organisms. 相似文献
In 1994, a large survey of soil chemistry was undertaken in thecounty of Värmland in central Sweden (Lundström et al., 1998).The southern part of the county was affected by soilacidification whereas there were no such indications in thenorthern part. To investigate the influence of soil chemistryon the trees at the specific sites, the survey was continued byan analysis of needle chemistry (Norway spruce) which wasundertaken at 150 of the 180 sites, and of tree growth at 65 ofthe 180 sites. Growth was expressed as a ratio between expectedgrowth, estimated with a national, empirical growth model, andthe growth observed in the field. In statistical analyses,using rank correlation, PCA and PLS, there were only weakindications of an influence of soil chemistry on needlechemistry and on tree growth. A moderate correlation betweennitrogen and sulphur in needles was found, which wasinterpreted as an effect of deposition and of processes in thetree canopy. No obvious regional pattern of the growth ratiowas found, in contrast to the clear pattern of soilacidification. The statistical analysis could not with anycertainty point out any of the soil chemistry variables asespecially important for the tree growth ratio. 相似文献
Call centre workplaces are in many ways a challenge to occupational health and safety. The occupation itself can be described as an IT information technology-supported, communication-intensive form of work with often unusual working hours and a high rate of part-time employment. Data on the employee turnover as well as absenteeism related to occupational disability is quite contradictory. Occupational safety and its proponents still have to find new ways into the corporate structures and cultures of this relatively new and rapidly growing branch of industry. In a 2-year research and development project, using a holistic approach and under consideration of all the relevant disciplines, call centre workplaces were studied, and organisational measures were developed and field tested by putting them into practice. Practical help was developed for a sustainable strategy for successful and healthy work in call centres. 相似文献
Environmental Science and Pollution Research - The potential use of a metal-tolerant sunflower mutant line for biomonitoring Cu phytoavailability, Cu-induced soil phytotoxicity, and Cu... 相似文献
Young forests can be manipulated in diverse ways to enhance their ecological values. We used stem maps from two dense, second-growth stands in western Washington and a spatially explicit light model (tRAYci) to simulate effects of five silvicultural manipulations on diameter distribution, species composition, spatial patterning, and light availability. Each treatment removed 30% of the basal area, but differed in how trees were selected for removal. Three primary treatments were thin from below (removing the smallest trees), random thin (removing trees randomly), and gap creation (removing all trees in circles ∼1 tree height in diameter). Two additional treatments combined elements of these approaches: random ecological thin (a mixture of thin from below and random thin) and structured ecological thin (a mixture of thin from below and gap creation). 相似文献
With the development of ambient air quality standards (AAQS), the need arises to describe the characteristics of regional surface air-pollutant concentration frequency distributions. In the evaluation of land use plans, numerous agencies will be concerned with evaluating the effectiveness of emission zoning and/or control actions. On a regional basis, one means of performing this assessment lies in determining the changes in the pollutant frequency distributions resulting from control actions. This study presents new data concerning the surface air-pollutant concentration frequency distributions observed for area sources and continuous point sources, and compares these distributions with those of the pertinent meteorological variables describing the transport and diffusion of the pollutant. The observed surface air pollutant frequency distributions are compared to those corresponding to simple modeling concepts from either an urban area source or a continuous point source. For an urban source and a relatively inert pollutant like CO, we found that the observed frequency distribution for CO surface air concentration parallels the approximately log-normal frequency distribution of the reciprocal of the wind speed. We show that the constant relating these two well-correlated frequency distributions can be determined either experimentally or with a numerical simulation model of air pollution. The usefulness of numerical models in air pollution is discussed. 相似文献
Rock ptarmigan (Lagopus muta) and willow ptarmigan (L. lagopus) are Arctic birds with a circumpolar distribution but there is limited knowledge about their status and trends across their circumpolar distribution. Here, we compiled information from 90 ptarmigan study sites from 7 Arctic countries, where almost half of the sites are still monitored. Rock ptarmigan showed an overall negative trend on Iceland and Greenland, while Svalbard and Newfoundland had positive trends, and no significant trends in Alaska. For willow ptarmigan, there was a negative trend in mid-Sweden and eastern Russia, while northern Fennoscandia, North America and Newfoundland had no significant trends. Both species displayed some periods with population cycles (short 3–6 years and long 9–12 years), but cyclicity changed through time for both species. We propose that simple, cost-efficient systematic surveys that capture the main feature of ptarmigan population dynamics can form the basis for citizen science efforts in order to fill knowledge gaps for the many regions that lack systematic ptarmigan monitoring programs.