IMPACT OF WATER CUTBACK ON SUGARCANE PRODUCTION IN THE FLORIDA EVERGLADES1

ABSTRACT: Sugarcane (Saccharum spp.) was planted in six lysimeters containing Pahokee muck (Lithic Mediaprist) where water tables were maintained at 30, 60, and 90 cm depths. The main objective was to study the impact of a 40 percent water cutback (108 mm) on sugarcane production during the period near the end of the dry season (i.e., May). The water cutback treatment was simulated through manipulation of water table depth. Due to the high available water capacity of the muck soil and selection of a sugarcane cultivar ‘CP63-588’ (which has a high tolerance of water table fluctuations), the sugarcane growth, and the yields of sugarcane biomass and sugar were not significantly different as a result of the treatments with and without 40 percent water cutback during a period of two months. This result is in good agreement with the 1981 cane yield in the Everglades Agricultural Area where a 35 percent water cutback was imposed during the 1981 drought.     

Biodegradable nanocomposites based on poly(butylene succinate)/organoclay

In this work, we try to incorporate the inorganic system into the biodegradable polymers to compose an organic/inorganic polymer hybrid. Various nanocomposites of poly(butylene succinates) (PBS) with different ratios of organically modified layered silicates (OMLS) prepared by solution blending were investigated. The OMLS used for the preparation of nanocomposites were functionalized ammonium salts modified montmorillonite. The effects of OMLS on the nanocomposites were investigated by XRD, TEM, DMA and TGA in the aspect of the d-spacing of clay, mechanical and thermal properties. Interestingly, all these nanocomposites exhibited improved properties when compared with the pristine PBS sample. XRD indicates that the layers of clay were intercalated by the modifiers, and the interlayer distance of organoclay in the nanocomposites could be extended to about 29.4 Å. Moreover, the thermal stability of the nanocomposites was enhanced by the addition of organoclay via TGA study, closely related to the organoclay content in the PBS matrix. DMA data shows that the storage and loss moduli were concurrently enhanced by the addition of organoclay as compared to the pristine PBS sample. Moreover, the glass transition temperatures also increased about 5 to 20 °C (from DMA, peak of tanδ) for the various organoclay-containing samples. The enhanced mechanical and thermal properties can be achieved from these organoclay modified-nanocomposites.     

The formation and control of disinfection by-products using chlorine dioxide

In this study, chlorine dioxide (ClO2) was used as an alternative disinfectant with vanillic acid, p-hydroxybenzoic acid, and humic acid as the organic precursors in a natural aquatic environment. The primary disinfection by-products (DBPs) formed were trihalomethanes (THMs) and haloacetic acids (HAAs). Under neutral conditions (pH = 7) for vanillic acid, more total haloacetic acids (THAAs) than total trihalomethanes (TTHMs) were found, with a substantial increase during the later stages of the reaction. In the case of p-hydroxybenzoic acid, the amount of THAAs produced was minimal. Raising the concentration of ClO2 was not favorable for the control of THAAs in low concentrations of vanillic acid. ClO2 could reduce the total amount of TTHMs and THAAs for higher concentration of vanillic acid. It was found that the humic acid treatment dosage was not significant. Under alkaline conditions (pH = 9), the control of TTHMs and THAAs for the treatment of vanillic acid was better and more economical, however, an appreciable amount of inorganic by-products were observed. Under the same alkaline condition, the control of THAA for the treatment of p-hydroxybenzoic acid was not beneficial and for the treatment of humic acid was not significant.     

Dwarfism associated with prenatal ventriculomegaly

Two infants with ventriculomegaly diagnosed by ultrasound during the third trimester of pregnancy were noted to have lethal short-limbed dwarfing syndromes at birth. In one instance, a clinical suspicion of hydramnios and in the other follow-up scan for placental localization revealed ventriculomegaly as an unexpected finding. These observations suggest that when ventriculomegaly is detected during prenatal ultrasound evaluation, limb measurements should be included to exclude a dwarfing syndrome as part of the differential diagnosis.     

USING LANDSAT DATA TO CLASSIFY LAND USE FOR ASSESSING THE BASINWIDE RUNOFF INDEX1

Remote sensing data in the form of Landsat computer compatible tapes (CCT) was used to determine land use and land cover as an aid in hydrologic studies that were used to estimated a basinwide runoff index. With the use of the General Electric Image 100 multispectral image processing system in conjunction with the Earth Resources Laboratory Application Software (ELAS), CCT's on February 9, 1976, were analyzed by spectral differences to determine unique land use conditions within the Econlockhatchee (Econ) River Basin, Florida. The result showed that the Landsat data can be successfully used to monitor the USGS land use Level 1. An advantage of using the Landsat data for land use classification is that new data are periodically available for updating the land use information. The Soil Conservation Service curve number was used to establish a basinwide runoff index which includes a prime variable of land use changes with the time. The basinwide runoff index in 1972 (with USGS 1972 Land Use maps) was similar to the one in 1976 (with Landsat data dated February 9, 1976). This implies that the runoff from the entire Econ Basin was not noticeably changed during the period of 1972 and 1976.     

USING CROP YIELD AND EVAPOTRANSPIRATION RELATIONS FOR REGIONAL WATER REQUIREMENT ESTIMATION1

ABSTRACT: Values of dry biomass of corn, sugarcane, sorghum, rice, taro, millet, cotton, cowpeas, soybeans, and velvet beans as related to the evapotranspiration (ET) were studied. The linear regression model was sufficiently accurate to establish the crop dry biomass and ET relations. A water-use efficiency index (WUE), which is defined as the additional crop dry biomass per unit ET, is used in this study. The WUE were grouped into high, medium, and low categories. The WUE varied from greater than 35 kg ha^-1/mm for the high category, between 15 and 35 kg ha^-1/mm for the medium category, and less than 15 kg ha^-1/mm for the low category. Application of the established model to the Everglades Agricultural Area, Florida, showed that the regional El can be predicted from the known regional crop yields. The crop yield and ET relations could be used as a potential tool to improve water resources planning and management practices for crop production.     

GENERATION OF SYNTHETIC AND MISSING CLIMATIC DATA FOR PUERTO RICO1

ABSTRACT: Climatic data such as temperature, solar radiation, relative humidity, and wind speed have been widely used to estimate evapotranspiration. Moat of the solar radiation data and portions of the relative humidity data are either not available or missing from the records in Puerto Rico. Depending upon the availability and data characteristics of records, three methods (including a regression technique, an averaging of historical data, and a regional average) were used to generate missing data, and a time series analysis was used to synthesize a series of climatic data. The limitations and applicability of each method are discussed. The results showed that the time series analysis method can be successfully used to synthesize a series of monthly solar radiations for several stations. The regression technique and the regional average can be successfully applied to generate missing monthly solar radiation data. The regression technique and the averaging of historical data have been satisfactorily used to interpolate missing monthly relative humidity. The explained variance (R²) varied from 0.68 to 0.88, which are both significant at the 0.05 level of significance.     

Decomposition of SF6 in an RF plasma environment

Sulfur hexafluoride (SFd)-contained gas is a common pollutant emitted during the etching process used in the semiconductor industry. This study demonstrated the application of radio-frequency (RF) plasma in the decomposition of SF6. The decomposition fraction of SF6 [etaSF6 (C(in)-C(out))/C(in) x 100%] and the mole fraction profile of the products were investigated as functions of input power and feed O2/SF6 ratio in an SiO2 reactor. The species detected in both SF6/Ar and SF6/O2/ Ar RF plasmas were SiF4, SO2, Fe2, SO2F2, SOF2, SOF4, S2F10, S2OF10, S2O2F10, and SF4. The results revealed that at 40 W, etaSF6 exceeded 99%, and the reaction products were almost all converted into stable compounds such as SiF4, SO2, and F2 with or without the addition of oxygen. Sulfur oxyfluorides such as SO2F2, SOF2, SOF4, S2OF10, and S2O2F10 were produced only below 40 W. The results of this work can be used to design a plasma/chemical system for online use in a series of a manufacturing process to treat SF6-containing exhaust gases.     

SUBJECTIVE DECISION-MAKING FOR URBAN WATER RESOURCES DEVELOPMENT1

ABSTRACT: Bayesian decision theory provides a procedure for the use of subjective data in a decision-making situation related to urban water resources development. This procedure is effectual in pursuing a set of goals and in transforming individual or group indecisiveness into satisfactory decisions. This approach is highlighted due to its capability to incorporate seemingly unquantifiable, abstract factors into the decision-making process. It is realized that the soliciting of expert and general public opinion is indispensable in making choices for the welfare of the general public from alternative courses of action under uncertainty. The analysis presented here considers engineering alternatives, quality, quantity, cost and the intangible public response in an integrated effort for the selection of optimum strategies in urban water resources development.