离子色谱法测定硝酸盐氮研究

文章探讨了一处测定地表水和饮用水中硝酸盐氮的直接方法－离子色谱法，与常用的酚二磺酸比色法相比，该方法具有简便，安全的优点，干扰少，准确度高。     

基于熵权的多目标决策-理想点在山仔水库营养化评价中的应用

多目标决策-理想点模型是一种简便、直观的评价模型,被广泛地用于环境科学研究领域.文章采用熵权和专家权重相结合的方法作为综合权重,充分考虑了客观因素和主观因素,并将其应用多目标决策-理想点模型来评价山仔水库的营养化.结果表明:1998-2002年山仔水库的营养化程度分别为:极富营养、富营养、富营养、中富营养、中营养.这与传统的多目标决策-理想点法一致,也符合实际情况.同时与属性识别理论方法、模糊隶属函数法较之精度更高,说明该方法是合理、有效的.     

微波辅助Cu(Ⅱ)-Fenton体系催化氧化处理对硝基苯酚废水

为了拓宽Fenton反应pH范围,提高降解效率、减少药剂用量,向Fenton体系中添加辅助催化剂Cu(Ⅱ),并对微波辅助催化氧化对硝基苯酚(PNP)模拟废水工艺进行了研究。提出微波辐照-放置处理工艺,并与普通全过程微波处理工艺进行了比较。结果表明,该体系处理工艺将Fenton反应最佳pH范围由2.0~3.5拓宽到2.0~5.5;在pH=5.0时,对于100 mg/L的PNP溶液,当[Cu2+]=0.8 mg/L、[Fe2+]=3.0 mg/L、[H2O2]=0.2 g/L,微波功率250 W,辐照2.0 min、放置4.0 min,PNP去除率可达98%以上;辅助催化剂Cu2+的加入增强了氧化效果,同时节约药品20%以上。通过对比实验发现,Cu2+与Fe2+发生了某种作用机制,联合促进了体系中·OH的生成。该反应体系不仅将传统Fenton反应体系狭窄的pH值范围延伸到接近中性的区域5.0~5.5,又可在短时间内使PNP去除率达到98%以上。     

A hybrid model based on smooth transition periodic autoregressive and Elman artificial neural network for wind speed forecasting of the Hebei region in China

Wind energy, one of the most promising renewable and clean energy sources, is becoming increasingly significant for sustainable energy development and environmental protection. Given the relationship between wind power and wind speed, precise prediction of wind speed for wind energy estimation and wind power generation is important. For proper and efficient evaluation of wind speed, a smooth transition periodic autoregressive (STPAR) model is developed to predict the six-hourly wind speeds. In addition, the Elman artificial neural network (EANN)-based error correction technique has also been integrated into the new STPAR model to improve model performance. To verify the developed approach, the six-hourly wind speed series during the period of 2000–2009 in the Hebei region of China is used for model construction and model testing. The proposed EANN-STPAR hybrid model has demonstrated its powerful forecasting capacity for wind speed series with complicated characteristics of linearity, seasonality and nonlinearity, which indicates that the proposed hybrid model is notably efficient and practical for wind speed forecasting, especially for the Hebei wind farms of China.     

低碳经济背景下我国碳会计信息披露制度的构建

碳会计信息披露制度的构建有利于对每个企业的碳排放进行量化及考核,增加信息可比性,为相关碳信息需求方提供有效的低碳经济信息,提高信息的透明度。因此,企业需要构建一套完善的企业碳会计信息披露制度。在对碳会计的理论基础、质量要求分析的基础上,对碳资产、碳负债、碳成本、碳权益、碳损益的定义、确认、计量及报告作出了系统性研究,指出碳会计信息披露制度不仅需要建立一套具体的碳会计核算体系,同时需要逐渐完善碳会计监督体系及相关的法律体系的建设。     

Utilization of two invasive free-floating aquatic plants (Pistia stratiotes and Eichhornia crassipes) as sorbents for oil removal

Free-floating aquatic plants Pistia stratiotes and Eichhornia crassipes are well-known invasive species in the tropics and subtropics. The aim of this study was to utilize the plants as cost-effective and environmentally friendly oil sorbents. Multilevel wrinkle structure of P. stratiotes leaf (PL), rough surface of E. crassipes leaf (EL), and box structure of E. crassipes stalk (ES) were observed using the scanning electron microscope. The natural hydrophobic structures and capillary rise tests supported the idea to use P. stratiotes and E. crassipes as oil sorbents. Experiments indicated that the oil sorption by the plants was a fast process. The maximum sorption capacities for different oils reached 5.1–7.6, 3.1–4.8, and 10.6–11.7 g of oil per gram of sorbent for PL, EL, and ES, respectively. In the range of 5–35 °C, the sorption capacities of the plants were not significantly different. These results suggest that the plants can be used as efficient oil sorbents.     

改性前后陶粒去除H2S的对比实验研究

分别以改性前后陶粒作为生物滴滤塔填料,进行去除H2S的对比实验研究.结果表明,改性后陶粒表面性质优于改性前陶粒;改性后陶粒挂膜时间短,对H2S降解菌有较强的吸附周定作用,适宜H2S降解菌生长,生物含量高;在H2S初始质量浓度为124～4 396 mg/m3时,改性后陶粒对H2S的去除能力优于改性前陶粒.     

Enhanced degradation of bioremediation residues in petroleum-contaminated soil using a two-liquid-phase bioslurry reactor

A study was performed to determine the potential of two-liquid-phase (TLP) bioslurry reactors using silicon oil as solvent for degradation of residual contaminants in petroleum-contaminated soil. The residues were characterized by gas chromatography–mass spectrometry and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. This allowed for the identification of a mixture of residual biomarkers, metabolic byproducts, oxygenated and hetero-polynuclear aromatic hydrocarbons in the contaminated soil. The removal amount of total extractable organics (TEO) was 15 900 mg kg⁻¹ soil in the TLP reactor within 12 weeks. However, TEO remained intact in the bioslurry reactor without the addition of silicon oil for the duration of the experiment, due to high toxicity of metabolites to the microorganisms. The availability of TEO was calculated using a mild extraction with Triton X-100, and the amount of TEO extracted was in accord with the amount of biodegraded TEO. Significantly reduced toxicity in soil was observed at week 12 through TLP remediation. Dehydrogenase activity in the bioslurry reactor was strongly suppressed. Fluorescein diacetate was significantly hydrolyzed by the composition of bioremediation residues in the contaminated soil. Microbial adhesion to the solvent was revealed by the determination of microbial activity in the water-immiscible-liquid.     

Hydrolysis and soil sorption of insecticide pyraclofos

The hydrolysis of the insecticide pyraclofos in buffered solutions at pH 5.0, 7.0 and 9.0, and its sorption on four soils of different physicochemical properties were investigated. The results showed that the degradation of pyraclofos in buffered solutions followed pseudo-first-order kinetics. At 40°C, the rate constants for the hydrolysis of pyraclofos at pH 5.0, 7.0 and 9.0 were 0.0214, 0.1293, and 2.1656 d^?1, respectively. Pyraclofos was relatively stable under both acidic and neutral conditions, while it was readily hydrolyzed under basic conditions. The sorption of pyraclofos on four soils was well described by the Freundlich equation. The sorption constant, K _f, increased with an increase in soil organic carbon content, suggesting that organic carbon content was an important factor affecting sorption. The K _oc values for Xiaoshan clay loam soil, Hangzhou I clay loam soil, Hangzhou II soil, and Fuyang silt loam soil were 30.4, 6.7, 5.3, and 7.1, respectively. These results suggest that the sorption of pyraclofos on the tested soils was relatively weak.     

Purification of leachate from sludge treatment beds by subsurface flow constructed wetlands: effects of plants and hydraulic retention time

Environmental Science and Pollution Research - Sludge treatment beds (STBs) have been used widely in many countries due to low energy consumption, low operating and maintenance costs, and better...