化学品测试合格实验室体系建设与发展

根据《新化学物质环境管理办法》要求,为新化学物质申报目的提供测试数据的境内测试机构,应当为环境保护部公告的化学物质测试机构,并接受环境保护部的监督和检查。拟通过借鉴国际合格实验室规范(GLP)基本原则和国内其他GLP认证工作经验做法,结合环境保护部已开展的检查考核工作和化学品测试实验室实际情况,探讨化学品测试合格实验室的管理现状和存在的问题,旨在为推动我国化学品测试合格实验室体系建设提供新的管理思路。     

化学品风险评估制度建设进展和建议

化学品风险评估是化学品管理的核心科学依据和主要技术手段,构建化学品风险评估制度对我国加强化学品管理具有重要意义。总结了国际上化学品风险评估制度体系在法规制度建设、指南、模型和数据库开发、风险评估实践等方面的进展和经验,分析了我国化学品风险评估在制度建设、指南标准、科学研究和信息收集方面取得的进展和存在的问题,提出了从立法制度建设、技术体系构建、基础能力建设和调查监测完善等方面建设我国化学品风险评估制度的建议。     

成渝经济区矿产资源开发对其生态环境影响评价

文章以成渝经济区为研究区,根据成渝经济区矿产资源开发和生态环境特点,综合运用RS和GIS技术,结合研究区矿产资源总体规划、生态功能区划、生物多样性保护、自然保护区、水源涵养、土壤保持、生态脆弱区分区等数据,采用空间图层叠加法,分析矿产资源开发利用对生态环境的影响,进一步分析了未来矿产资源的开发对区域主要生态屏障的水源涵养、土壤保持、生物多样性保护等生态功能的影响,并提出针对性的生态环境保护对策措施。     

膨润土的羟基铝改性及对染料工业废水的处理研究

通过对膨润土的羟基铝改性实验大大提高了膨润土对染料废水的处理效率。实验结果表明:改性膨润土对变色酸有很好的去除效果,对H酸有较好的去除效果,对T酸处理效果一般,对吐氏酸几乎没有效果。     

Research of the Response of Ecosystem to LUCC in Miyun County, Beijing： Based on Ecosystem Services Valuation

Miyun County,located in the northeast of Chinese capital Beijing,was underwent remarkable variations in land use in recent years.This paper aimed to detect changes in land use of Miyun from 1997 to 2005,and to qualify the response of ecosystem to LUCC based on ecosystem services valuation.With two-periods TM images,we got land use change data,and then ecosystem services values were calculated using ecosystem services valuation coefficients proposed by Chinese scholar Xie Gaodi.Results showed that water area,farm land and unused land decreased while residential land,forest land,grassland and orchard land increased during the study period.The loss of ESV was RMB 206 million and the main reason was the decrease of water area and farm land area.As for spatial variation,there were most dramatically land use change and ESV decline in reservoir ecological protection region.The coefficient sensitivity analysis indicates that valuation coefficients used in the study are suitable and results are reasonable.The driving forces of ESV loss were rapid population growth and economic development.More work should be done to make eco-environment stay healthy.     

Insights into metals in individual fine particles from municipal solid waste using synchrotron radiation-based micro-analytical techniques

Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste(MSW). In this study, we investigated fine particles of 2 mm, which are small fractions in MSW but constitute a significant component of the total heavy metal content, using bulk detection techniques. A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction. We also discussed the association, speciation and source apportionment of heavy metals. Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of 10 μm within the fine particles. Zn–Cu, Pb–Fe and Fe–Mn–Cr had significant correlations in terms of spatial distribution. The overlapped enrichment, spatial association, and the mineral phases of metals revealed the potential sources of fine particles from size-reduced waste fractions(such as scraps of organic wastes or ceramics) or from the importation of other particles. The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction(such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products.     

Genomic analyses of metal resistance genes in three plant growth promoting bacteria of legume plants in Northwest mine tailings,China

To better understand the diversity of metal resistance genetic determinant from microbes that survived at metal tailings in northwest of China, a highly elevated level of heavy metal containing region, genomic analyses was conducted using genome sequence of three native metal-resistant plant growth promoting bacteria(PGPB). It shows that: Mesorhizobium amorphae CCNWGS0123 contains metal transporters from P-type ATPase, CDF(Cation Diffusion Facilitator), Hup E/Ure J and CHR(chromate ion transporter) family involved in copper, zinc, nickel as well as chromate resistance and homeostasis. Meanwhile, the putative Cop A/Cue O system is expected to mediate copper resistance in Sinorhizobium meliloti CCNWSX0020 while Znt A transporter, assisted with putative Czc D, determines zinc tolerance in Agrobacterium tumefaciens CCNWGS0286. The greenhouse experiment provides the consistent evidence of the plant growth promoting effects of these microbes on their hosts by nitrogen fixation and/or indoleacetic acid(IAA) secretion,indicating a potential in-site phytoremediation usage in the mining tailing regions of China.     

Predicting heavy metals’ adsorption edges and adsorption isotherms on MnO2 with the parameters determined from Langmuir kinetics

Although surface complexation models have been widely used to describe the adsorption of heavy metals, few studies have verified the feasibility of modeling the adsorption kinetics,edge, and isotherm data with one p H-independent parameter. A close inspection of the derivation process of Langmuir isotherm revealed that the equilibrium constant derived from the Langmuir kinetic model, K S-kinetic, is theoretically equivalent to the adsorption constant in Langmuir isotherm, K S-Langmuir. The modified Langmuir kinetic model(MLK model) and modified Langmuir isotherm model(MLI model) incorporating p H factor were developed. The MLK model was employed to simulate the adsorption kinetics of Cu(II), Co(II), Cd(II), Zn(II) and Ni(II) on Mn O2 at p H 3.2 or 3.3 to get the values of K S-kinetic. The adsorption edges of heavy metals could be modeled with the modified metal partitioning model(MMP model), and the values of K S-Langmuir were obtained. The values of K S-kinetic and K S-Langmuir are very close to each other, validating that the constants obtained by these two methods are basically the same. The MMP model with K S-kinetic constants could predict the adsorption edges of heavy metals on Mn O2 very well at different adsorbent/adsorbate concentrations. Moreover, the adsorption isotherms of heavy metals on Mn O2 at various p H levels could be predicted reasonably well by the MLI model with the K S-kinetic constants.     

基于GIS与RUSLE的武陵山区小流域土壤侵蚀评价研究

以长江中下游武陵山区女儿寨小流域为研究区，基于数据观测积累及实地调查采样等方法，计算了研究区降雨侵蚀力、土壤可蚀性等因子，运用GIS与RUSLE评价了流域土壤侵蚀强度并分析了其与土地利用方式、海拔高度的关系。结果表明，流域平均土壤侵蚀强度为78844 t/（km2·a），属微度侵蚀，流域面积9518%的范围发生轻度以下的侵蚀，强烈以上侵蚀仅占1.19%。从土地利用类型来看，耕地、果园侵蚀强度较大，均达到中度侵蚀，有林地除竹林地为轻度侵蚀外均属微度侵蚀，耕地、果园、竹林地是今后水土流失防治的主要地类。不同海拔高度中，低海拔（200～400 m）区域侵蚀量占到流域侵蚀总量的6442%，是水土流失防治的重点地带。研究为应用修正通用土壤流失方程在武陵山区进行土壤侵蚀评价提供范例，为研究区防治土壤侵蚀和流域管理规划决策提供相应参考     

《安全生产行业标准管理规定》

第一章 总则 第一条为加强安全生产行业标准(以下统称安全生产标准)的管理，规范安全生产标准的制定和修订程序，根据《标准化法》、《标准化法实施条例》等有关规定，制定本规定。