Fate of heavy metals and radioactive metals in gasification of sewage sludge

The fates of radioactive cadmium, strontium, cesium, cobalt, arsenic, mercury, zinc, and copper spiked into sewage sludge were determined when the sludge was gasified by a process that maximizes production of char from the sludge (ChemChar process). For the most part the metals were retained in the char product in the gasifier. Small, but measurable quantities of arsenic were mobilized by gasification and slightly more than 1% of the arsenic was detected in the effluent gas. Mercury was largely mobilized from the solids in the gasifier, but most of the mercury was retained in a filter composed of char prepared from the sludge. The small amounts of mercury leaving the gasification system were found to be associated with an aerosol product generated during gasification. The metals retained in the char product of gasification were only partially leachable with 50% concentrated nitric acid.     

Polycyclic aromatic hydrocarbon release from a soil matrix in the in vitro gastrointestinal tract

Soil ingestion is an important exposure route by which immobile soil contaminants enter the human body. We assessed polycyclic aromatic hydrocarbon (PAH) release from a contaminated soil, containing 49 mg PAH kg(-1), using a SHIME (Simulator of the Human Intestinal Microbial Ecosystem) reactor comprising the stomach, duodenal, and colon compartments. Polycyclic aromatic hydrocarbon release was defined as that fraction remaining in the digest supernatant after centrifugation for 5 min at 1500 x g. The PAH release in the stomach digest was only 0.44% of the total PAH present in soil, resulting in PAH concentrations of 23 micrograms PAH L(-1) chyme. The lower PAH releases in duodenum (0.13%) and colon (0.30%) digests, compared with the stomach digest, were thought to be attributed to combined complexation and precipitation with bile salts, dissolved organic matter, or colon microbiota. We studied these complexation processes in an intestinal suspension more in depth by preparing mixtures of 9-anthracenepropionic acid, a Bacillus subtilis culture, and cholin as model compounds for PAHs, organic matter, and bile salts, respectively. Bile salts or organic matter in the aqueous phase initially enhance PAH desorption from soil. However, desorbed PAHs may form large aggregates with bile and organic matter, lowering the freely dissolved PAH fraction in the supernatant. Using the model compounds, mathematical equations were developed and validated to predict PAH complexation processes in the gastrointestinal tract. Contaminant release and subsequent complexation in the gut is an important prerequisite to intestinal absorption and thus bioavailability of that contaminant. The data from this research may help in understanding the processes to which PAHs are subjected in the gastrointestinal tract, before intestinal absorption.     

Nitrogen and nature

Anthropogenic changes to the global N cycle are important in part because added N alters the composition, productivity, and other properties of many natural ecosystems substantially. Why does added N have such a large impact? Why is N in short supply in so many natural ecosystems? Processes that slow the cycling of N relative to other elements and processes that control ecosystem-level inputs and outputs of N could cause N supply to limit the dynamics of ecosystems. We discuss stoichiometric differences between terrestrial plants and other organisms, the abundance of protein-precipitating plant defenses, and the nature of the C-N bond in soil organic matter as factors that can slow N cycling. For inputs, the energetic costs of N fixation and their consequences, the supply of nutrients other than N, and preferential grazing on N-fixers all could constrain the abundance and/or activity of biological N-fixers. Together these processes drive and sustain N limitation in many natural terrestrial ecosystems.     

Method for the determination of sub-ppm concentrations of perfluoroalkylsulfonate anions in water

The determination of sub-ppm concentrations of aqueous perfluoroalkylsulfonate (PFSt) anions, including perfluorooctylsulfonate (PFOS), has been accomplished with a relatively simple mass spectrometric procedure that does not require extraction of the analytes into an organic solvent or a chromatographic separation prior to injection into the negative-ion electrospray ionization mass spectrometer. Sample pretreatment was minimized and consisted of dilution of the aqueous samples of groundwater, surface water, tap water, and distilled water with acetonitrile, addition of dodecylsulfate (DDS) as an internal standard, and, in some cases, addition of known amounts of perfluorobutylsulfonate (PFBS) or PFOS for standard-addition experiments. The linear-response range for PFOS is 25.0 microg L(-1) to 2.5 mg L(-1). The lower limit of this range is three orders of magnitude lower than an equally straightforward chromatographic method. The relative errors for standard aqueous solutions containing only 25.0 microg L(-1) and 2.5 mg L(-1) PFOS are +/- 14% and +/- 7%, respectively, with 133 microg L(-1) DDS as the internal standard. The detection limit and quantification limit for PFOS in these standards are 5.0 microg L(-1) and 25.0 microg L(-1), respectively. Six different PFS anions, containing three to eight carbon atoms, were identified and quantified in an aqueous film-forming foam (AFFF) formulation using the method of standard additions. Two alkylsulfate anions and two perfluoroalkylcarboxylate anions were also identified in the AFFF formulation.     

有害物品运输的总风险分析

随着工业的发展,有害物品的生产量和运输量均在逐年增加,有害物品对环境和人的危害正在扩大和加深。有害物品运输中的风险是有害物品对于人类、环境和财产等方面威胁的最为重要的组成部分。笔者将有害物品的运输风险分为人口风险、环境风险和财产风险3个部分;在基于事故发生率和事故产生的后果两个方面,分别对人口风险、环境风险和财产风险进行了度量,并给出了风险度量的模型。同时由于各个部分风险度量的量纲并不统一,笔者对3部分风险进行了度量的统一化,获得了总风险的构成,并与传统的单独考虑人口风险的情况进行了对比,为有害物品的运输提供了参考依据。     

SCR系统中板式和蜂巢式催化剂的选取

选择性催化氧化还原法(SCR)是当今国际上最为成熟、有效的烟气脱硝技术。催化剂作为SCR工艺流程中最重要的设备部件，对SCR工艺的效率起着决定性的作用。分析了2种脱硝催化剂的物理、化学特性，以及它的优缺点，为催化剂的选取提供参考。     

REGIONAL HYDROLOGIC RESPONSE OF LOBLOLLY PINE TO AIR TEMPERATURE AND PRECIPITATION CHANGES1

ABSTRACT: Large deviations in average annual air temperatures and total annual precipitation were observed across the southern United States during the last 50 years, and these fluctuations could become even larger during the next century. We used PnET-IIS, a monthly time-step forest process model that uses soil, vegetation, and climate inputs to assess the influence of changing climate on southern U.S. pine forest water use. After model predictions of historic drainage were validated, the potential influences of climate change on loblolly pine forest water use was assessed across the region using historic (1951 to 1984) monthly precipitation and air temperature which were modified by two general circulation models (GCMs). The GCMs predicted a 3.2°C to 7.2°C increase in average monthly air temperature, a -24 percent to + 31 percent change in monthly precipitation and a -1 percent to + 3 percent change in annual precipitation. As a comparison to the GCMs, a minimum climate change scenario using a constant 2°C increase in monthly air temperature and a 20 percent increase in monthly precipitation was run in conjunction with historic climate data. Predicted changes in forest water drainage were highly dependent on the GCM used. PnET-IIS predicted that along the northern range of loblolly pine, water yield would decrease with increasing leaf area, total evapotranspiration and soil water stress. However, across most of the southern U.S., PnET-IIS predicted decreased leaf area, total evapotranspiration, and soil water stress with an associated increase in water yield. Depending on the GCM and geographic location, predicted leaf area decreased to a point which would no longer sustain loblolly pine forests, and thus indicated a decrease in the southern most range of the species within the region. These results should be evaluated in relation to other changing environmental factors (i.e., CO₂ and O₃) which are not present in the current model.     

A COMPARISON OF GEOSTATISTICAL METHODOLOGIES USED TO ESTIMATE SNOW WATER EQUIVALENT1

ABSTRACT: The need to monitor and forecast water resources accurately, particularly in the western United States, is becoming increasingly critical as the demand for water continues to escalate. Consequently, the National Weather Service (NWS) has developed a geostatistical model that is used to obtain areal estimates of snow water equivalent (the thtal water content in all phases of the snowpack), a major source of water in the West. The areal snow water equivalent estimates are used to update the hydrologic simulation models maintained by the NWS and designed to produce extended streamflow forecasts for river systems throughout the United States. An alternative geostatistical technique has been proposed to estimate snow water equivalent. In this research, we describe the two methodologies and compare the accuracy of the estimates produced by each technique. We illustrate their application and compare their estimation accuracy using snow data collected in the North Fork Clearwater River basin in Idaho.     

USING UNCENSORED TRACE-LEVEL MEASUREMENTS TO DETECT TRENDS IN GROUND WATER CONTAMINATION1

ABSTRACT: Environmental decision making involving trace-levels of contaminants can be complicated by censoring, the practice of reporting concentrations either as less than the limit of detection (LOD) or as not detected (ND) when a test result is less than the LOD. Censoring can result in data series that are difficult to meaningfully summarize, graph, and analyze through traditional statistical methods. In spite of the relatively large measurement errors associated with test results below the LOD, simple and meaningful analyses can be carried out that provide valuable information not available if data are censored. For example, an indication of increasing levels of contamination at the fringe of a plume can act as an early warning signal to trigger further study, an increased sampling frequency, or a higher level of remediation at the source. This paper involves the application of nonparametric trend analyses to uncensored trace-level groundwater monitoring data collected between March 1991 and August 1994 on dissolved arsenic and chromium for seven wells at an industrial site in New York.     

SNOWPACK CHANGES RESULTING FROM TIMBER HARVEST INTERCEPTION,REDISTRIBUTION, AND EVAPORATION1

ABSTRACT: Three processes were examined as causing snowpack changes in forest clearings. Two of the three contribute to increases and one counteracts by reducing snowpack. The two that increase snowpack are redistribution and decreased loss to interception. Snow evaporation from a clearing counteracts snowpack increases. Research has indicated that as vegetation density increases, so too does the loss to interception. As snow in the canopy reaches the limit that the canopy can hold (the threshold amount) evaporation increases. Aerodynamics of the forest canopy were studied as well. As timber is cut, wind patterns are disturbed, creating disruptions in the wind velocity gradient depositing snow in openings. This redistribution leads to an increased snow water equivalent and augments runoff. Snow evaporation was shown to increase proportionally with opening size. Evaporation offsets the water yield gains derived from forest cut. It was found that this offset is inclusive to the measurements of water yield changes in experimental forests. An optimal size of harvest block may be five tree heights in width as suggested by numerous studies.