Residential and biological exposure assessment of chemicals from a wood treatment plant

This paper evaluates the results of contamination of residents and residential homes located in close proximity to a Wood Treatment Plant. The plant has produced treated wood products continuously since 1904. The principle chemicals used to treat the wood, which is primarily used for railroad ties (oblong objects laid perpendicular to the rails to act as a base for the tracks), are creosote and pentachlorophenol. For a number of years, the plant burned treated waste wood products containing creosote and pentachlorophenol. First the plant pressure impregnates the wood with creosote and pentachlorophenol, and then the wood is stacked on open ground to allow it to air dry. Chemicals from recently treated wood ties are allowed to evaporate into the air or drip onto the ground surrounding the stacked wood. Small drainage ditches carry the liquid wastes into larger water channels where eventually the waste streams are discharged into a river adjacent to the plant. The river serves as a source of drinking water for the nearby community. Prevailing wind patterns favor a drift of air emissions from the plant's boiler stack over the nearby community and its residents. Over the past few years, the town's residents have become increasingly concerned about their health status and have voiced concerns regarding multiple health problems (including cancer), possibly associated with plant discharges. The intention of this study is to examine a representative sample of the potentially affected residents and to evaluate their residential environment for the presence of dioxin and/or its congeners. Data obtained from EPA's Toxic Release Information (TRI) database revealed the plant routinely discharged creosote, pentachlorophenol, dioxin and dioxin-like compounds into the ambient air via fugitive air emissions and surface waste waters. Sampling of household dust and water sediment within and outside of residences within a 2-mile radius of the plant revealed the presence of significantly elevated levels of dioxins, principally octachlorodibenzo-p-dioxin (OCDD) and 1,2,3,4,6,7,8-hepta-CDD. Biomonitoring of 29 subjects identified the presence of significantly elevated chlorinated dioxins and furan levels (OCDD=1049 ppt for exposed and 374 ppt for controls and 1,2,3,4,6,7,8-hepta CDD=132 ppt for exposed and 45.1 ppt for controls). These levels are consistent with exposures to pentachlorophenol in this group of subjects. And they confirm the presence of unsafe levels of chlorinated dioxins in these persons.     

An experimental examination of implicit stress theory

Implicit theories lead individuals to make assumptions about one trait based on their knowledge of another trait. This study experimentally examined Implicit Stress Theory under conditions of high and low performance information. The objective was to test for evidence of Implicit Stress Theory in ratings of effectiveness, commitment, and burnout. Results indicated moderate support for Implicit Stress Theory such that raters evaluated employee burnout and commitment as higher when the employee was perceived to be working under stressful conditions. Interestingly, the data suggested stronger support (based on the proportion of variance explained) for an Implicit Performance Theory such that information regarding good performance was associated with higher levels of commitment and less burnout than poor performance.     

Implicating waterfronts in regional sustainability

Advocates of sustainable urban development often privilege the region as a scale for coordinated action and investment. However, discourses of sustainability institutionalised through regional planning, and conflated with notions of liveability, lend themselves to recruitment by competing, and opposing, development interests. To be regionally sustainable, an individual land development should, both on-site and through its connections to other sites, contribute to overall sustainability of the region. Using examples of industrial waterfront redevelopment in metropolitan Vancouver, we show how particular urban spaces are misrepresented as lynchpins of regional sustainability. In a plan for residential redevelopment, it is claimed that sustainable redevelopment will reunite citizens with “their waterfront”, reframed as liveable, pure, clean, ecologically vital and non-industrial. At an adjacent site, it is claimed that waterfront industrial land should be protected to combat industrial sprawl. Yet, in both cases the developers have lobbied for the expansion of road transportation making the claims of regional sustainability doubtful.     

Validation of reliable and selective methods for direct determination of glyphosate and aminomethylphosphonic acid in milk and urine using LC-MS/MS

Simple high-throughput procedures were developed for the direct analysis of glyphosate [N-(phosphonomethyl)glycine] and aminomethylphosphonic acid (AMPA) in human and bovine milk and human urine matrices. Samples were extracted with an acidified aqueous solution on a high-speed shaker. Stable isotope labeled internal standards were added with the extraction solvent to ensure accurate tracking and quantitation. An additional cleanup procedure using partitioning with methylene chloride was required for milk matrices to minimize the presence of matrix components that can impact the longevity of the analytical column. Both analytes were analyzed directly, without derivatization, by liquid chromatography tandem mass spectrometry using two separate precursor-to-product transitions that ensure and confirm the accuracy of the measured results. Method performance was evaluated during validation through a series of assessments that included linearity, accuracy, precision, selectivity, ionization effects and carryover. Limits of quantitation (LOQ) were determined to be 0.1 and 10 µg/L (ppb) for urine and milk, respectively, for both glyphosate and AMPA. Mean recoveries for all matrices were within 89–107% at three separate fortification levels including the LOQ. Precision for replicates was ≤7.4% relative standard deviation (RSD) for milk and ≤11.4% RSD for urine across all fortification levels. All human and bovine milk samples used for selectivity and ionization effects assessments were free of any detectable levels of glyphosate and AMPA. Some of the human urine samples contained trace levels of glyphosate and AMPA, which were background subtracted for accuracy assessments. Ionization effects testing showed no significant biases from the matrix. A successful independent external validation was conducted using the more complicated milk matrices to demonstrate method transferability.     

Integrating Satellite Imagery with Simulation Modeling to Improve Burn Severity Mapping

Both satellite imagery and spatial fire effects models are valuable tools for generating burn severity maps that are useful to fire scientists and resource managers. The purpose of this study was to test a new mapping approach that integrates imagery and modeling to create more accurate burn severity maps. We developed and assessed a statistical model that combines the Relative differenced Normalized Burn Ratio, a satellite image-based change detection procedure commonly used to map burn severity, with output from the Fire Hazard and Risk Model, a simulation model that estimates fire effects at a landscape scale. Using 285 Composite Burn Index (CBI) plots in Washington and Montana as ground reference, we found that an integrated model explained more variability in CBI (R ² = 0.47) and had lower mean squared error (MSE = 0.28) than image (R ² = 0.42 and MSE = 0.30) or simulation-based models (R ² = 0.07 and MSE = 0.49) alone. Overall map accuracy was also highest for maps created with the Integrated Model (63 %). We suspect that Simulation Model performance would greatly improve with higher quality and more accurate spatial input data. Results of this study indicate the potential benefit of combining satellite image-based methods with a fire effects simulation model to create improved burn severity maps.     

Geographic variation in allele frequency of the gamete recognition protein M7 lysin throughout a mosaic blue mussel hybrid zone

Divergence at gamete recognition loci is hypothesized to result in speciation in broadcast spawning invertebrates. Many gamete recognition loci evolve quickly and show patterns of positive selection, yet the advantage of divergence is rarely known. M7 lysin is a sperm protein in the Mytilus edulis species complex that shows evidence of adaptive evolution. This locus is polymorphic with two distinct clades within Mytilus galloprovincialis, one of which, the D clade, shows the strongest signal of positive selection. We tested whether the geographic patterns in allele frequency were consistent with the hypothesis that positive selection on D clade alleles (G _D ) was due to reinforcement. Populations of M. edulis showed little evidence of introgression of G _D alleles, but there was no consistent evidence of reproductive character displacement. The lack of consistent patterns expected of reinforcement suggests that another mechanism is likely responsible for the adaptive divergence of M7 lysin.     

Uniting multi‐adult households during emergency evacuation planning

When a no‐notice emergency prompts an evacuation, family members in different locations throughout a city may unite so that they can evacuate as a group. This paper draws on data from more than 300 interviews conducted in the metropolitan area of Chicago, Illinois, United States. The study uses discrete choice models to analyse the expectations of respondents regarding whether their likely plans for evacuation involve gathering spouses, parents, adult‐age children, and/or non‐family members. In addition, it addresses the matter of whether respondents plan to reunite with family members at home. Individuals' access to a personal car is the dominating factor in predicting whether respondents plan to gather a spouse. Being the parent of a child under the age of 18 years increases the tendency to report planning to reunite with family members at home. Both commute mode and car availability are not significantly associated with plans to reunite at home.     

An examination of beliefs about older workers: Do stereotypes still exist?

This study examined individuals' beliefs about older workers. Of particular interest was the relationship between those beliefs and individuals' (a) interactions with older workers, (b) supervisory status, and (c) demographic variables. Findings indicated that although older workers hold more positive beliefs about older workers than younger workers hold, even younger workers tended to have generally positive beliefs. Chronological age was found to moderate two relationships. First, the number of younger workers' interactions with older workers significantly, positively affected younger workers' beliefs about older workers. Second, an examination of the interaction between supervisory status and age found that older supervisors hold more negative beliefs about older workers than younger supervisors.     

POTENTIAL,ACTUAL, AND EQUILIBRIUM EVAPOTRANSPIRATION IN A WHEAT FIELD 1

ABSTRACT: This paper examines the relationship between both potential (E*) and nonpotential evapotranspiration and equilibrium evapotranspiration (EQ) in an irrigated wheat field in southcentral Alberta, Canada. The control exercised by surface wetness and root reservoir moisture content in determining the value of the Priestley-Taylor constant a is explored. Also investigated is the relationship between a and the vapor flux fraction ET/(R-G) where ET is the actual evapotranspiration, R the net radiation, and G the soil heat flux. It is shown that evapotranspiration occurred at the potential rate (E*) when the available soil moisture (ASM) within the root zone was ≥3 percent. a varied from 0.84 for a dry soil to 1.49 for a saturated soil. The mean a for E* was 1.24. Surface wetness sustained evapotranspiration at the potential rate when such wetting exceeded 2mm d^?1 following a period of prolonged drawdown of soil moisture, α and ET/(R-G) were positively correlated and this correlation strengthened with increasing soil moisture for constant values of the energy partitioning factor s+γ/s where s is the slope of the saturation humidity-temperature curve and γ is the psychrometric constant. ET=EQ when ETI(R-G) lay within the range of 0.59 to 0.82 corresponding to Bowen ratio (β) values of 0.22 and 0.69, respectively.