Displacement and sweep efficiencies in a DNAPL recovery test using micellar and polymer solutions injected in a five-spot pattern

Soil washing with micellar solutions is a promising alternative for the remediation of DNAPL source zones. As with any flushing technology, the success of soil washing with micellar solutions depends in a very large part on the ability of the solution to contact the contaminant (sweep efficiency) and then on the efficiency of contaminant removal once this contact is made (displacement efficiency). We report here on a field test where a micellar solution was used to recover a DNAPL in an open five-spot pattern in which polymer solutions were also injected before and after the washing solution to improve sweep efficiency. The washing solution formulation was optimised in the laboratory prior to the test to obtain good dissolution capacity. For a high-concentration and low-volume soil flushing remediation test such as the one performed (0.8 pore volumes of actual washing solution injected), slug sizing of the washing solution is critical. It was evaluated by an analytical solution. In a five-spot pattern, the displacement efficiency of the washing solution was observed to vary in the porous medium as a function of the radial distance from the injection well because: (1) the volume of the washing solution flowing through a section of the test cell changes (maximum close to the injection well and minimal at the pumping wells); (2) the in situ velocity changes (maximum at the wells and minimum between the wells) and; (3) the contact time of the washing solution with the NAPL changes as a function of the distance from the injection well. The relative importance of the recovery mechanisms, mobilisation and dissolution, was also observed to vary in the test cell. The reduced velocity increased the contact time of the washing solution with the DNAPL enhancing its dissolution, but the decrease of the capillary number caused less mobilisation. The washing process is much more extensive around the injection well. The use of an injection-pumping pattern allowing a complete sweep of the remediated area is essential. Following a comprehensive characterisation, modeling is an efficient tool to design the injection-pumping scheme and to optimise injection and pumping rates providing the best areal sweep. The vertical sweep can be controlled by using a polymer solution (Xanthan gum). The polymer solution also has a positive effect on front stability between the solutions injected. The injection rate of the polymer solution that follows the washing solution must be kept minimal initially to prevent dilution of the washing solution by fingering.     

Joint influence of surfactants and humic matter on PAH solubility. Are mixed micelles formed?

Mobilization of polycyclic aromatic hydrocarbons (PAH) by surfactants, present at contaminated sites or deliberately introduced for remediation purposes, is inevitably associated with the influence of humic substances, which are ubiquitous in natural systems. Therefore, the solubilizing effects of anthropogenic and natural amphiphiles must be considered in their combined action since synergistic or antagonistic effects may be expected, for instance, as a consequence of mixed micellization.

In this paper, solubilization of ¹⁴C-labeled pyrene in single-component and mixed solutions of surfactants and humic acid (coal-derived) was investigated up to the micellar concentration range. At low concentrations, antagonistic effects were observed for systems with cationic as well as anionic surfactants. Solubility enhancements in the presence of humic acid were canceled on addition of a cationic surfactant (DTAB) since charge compensation at humic colloids entailed precipitation. Solubility was also found to be decreased in the presence of an anionic surfactant (SDS), which was attributed to a competitive effect in respect of pyrene–humic interaction. This explanation is based on octanol–water partitioning experiments with radiolabeled humic acid, yielding evidence of different interaction modes between humic colloids and cationic/anionic surfactants. At higher concentrations, the effects of humic acid and SDS were found to be additive. Thus, a formation of mixed micelles is very unlikely, which was confirmed by size exclusion chromatography of mixed systems. It can be concluded that remediation measures on the basis of micellar solubilization are not significantly affected by the presence of natural amphiphilic compounds.     

SELECTED NUTRIENTS AND HEAVY METALS IN SEWAGE SLUDGE FROM NEW JERSEY POTWs1

ABSTRACT: In order to determine appropriate application rates and to ensure low pollutant levels in sewage sludge, knowing the chemical composition of sewage sludge is of great importance in a land application program. The objective of this study is to evaluate the variability of selected chemical characteristics of sewage sludge from New Jersey publicly owned treatment works (POTWs). Measurements of total Kjeldahl nitrogen (TKN), NH₄⁺‐N, P, K⁺, Cd, Cu, Pb, and Zn reported by 98 facilities in the 1996 and 1997 New Jersey Sludge Quality Assurance Regulations (SQAR) reports were statistically analyzed. Sewage sludge from Category 5 POTWs (greater than 10 percent industrial input) showed higher Cd, Cu, and Pb concentrations than Category 3 and Category 4 facilities (less than 10 percent industrial input). Even though only two years of data were analyzed, there was an indication that Cd and Pb concentrations in sewage sludge are decreasing with time. The yearly mean of only a few facilities exceeded the federal pollution concentration limits (40 CFR Part 503, Table 3). Phosphorus and Cd values showed the highest variability within facilities based on the coefficient of variation. Due to the variability of sewage sludge constituents, the use of the yearly rolling mean of nutrient concentrations to determine application rates was considered inadequate. An actual analysis of the sewage sludge to be applied is more appropriate to determine application rates than historical data.     

Environmental hazard screening of a metal-polluted site using pressurized liquid extraction and two in vitro bioassays

Rapid screening methods can improve the cost effectiveness, throughput, and quality of risk assessments of contaminated sites. In the present case study, the objective was to evaluate a combination of pressurized liquid extraction and 2 in vitro bioassays for the hazard assessment of surface soil sampled from 46 points across a pyrotechnical industrial site. Pressurized liquid extraction was used to rapidly produce soil-water extracts compatible with 2 high-capacity bioassays. Hazard assessment using combined toxicological and chemical screening revealed zones with relatively high potential risks of metal pollution. Multivariate data analysis provided indications that significant inhibition in the bioassays was correlated with levels of metals in the extracts, suggesting an elevated toxic potential from certain metals. Low pH and high concentrations of dissolved organic carbon were associated with increased cytotoxicity of extracts, indicating that these factors influence metal bioavailability. The cytotoxicity observed was more strongly correlated to metal concentrations in the extracts than in the soil, suggesting that measurements of total metal concentrations in soils do not provide good indications of the soil's potential toxicity.     

Training future experts in “biodiversity and ecosystem services”: a progress report

Biodiversity is essential for multiple aspects of human life and well-being, but many current assessments of the functioning of biodiversity and ecosystems, understanding of risks posed by environmental change and the best practice of their management of ecosystems are lacking a unified scientific and conceptual basis. Methods such as scenario analysis, and terms such as ecosystem services, are widely used, but their meaning is understood in many different ways depending on context, user needs and experience of researchers. In order to advance the conceptual basis for ecosystem analysis and management in a rapidly changing world, as well as the ability of young scientists to reflect upon these concepts, we have organised five 2-week-long summer schools in Peyresq, a remote village in the Southern French Alps. In total 173 participants have worked intensively with 69 experienced researchers and a team of conveners and tutors in order to discuss a broad range of views on topics on ecosystem analysis and functioning. Topics ranged from conditions of and threats to various ecosystems due to environmental change, models and scenarios for assessment, stakeholder perceptions and needs for information, to the social and economic contexts for biodiversity. We report our experience from these schools, present the training concept which has emerged from them and suggest lines of further development.

A stakeholder dialogue on European vulnerability

A stakeholder dialogue was embedded in the ATEAM project to facilitate the development and dissemination of its European-wide vulnerability assessment of global change impacts. Participating stakeholders were primarily ecosystem managers and policy advisers interested in potential impacts on ‘Agriculture’, ‘Forestry’, ‘Water’, ‘Carbon storage’, ‘Biodiversity’ and ‘Mountain environments’ sectors. First, stakeholder dialogue approaches to integrated assessment are introduced. Methodological considerations on stakeholder selection and dialogue implementation and evaluation follow. The dialogue content and process are evaluated from the perspectives of stakeholders and scientists. Its usefulness in the research process and the relevance of outcomes for stakeholders are particularly considered. The challenging compromises required to perform innovative research, which seeks to achieve both peer scientific credibility and societal relevance, are emphasized. Effective stakeholder dialogues play a substantial role in raising the visibility and meaningfulness of vulnerability assessments as critical means to improve awareness on global change and its potential worrying impacts on society. They further provide scientists with critical information on ecosystem management and sectoral adaptive capacity. These processes of mutual learning and knowledge exchange moreover foster a better understanding of the potential and limits of global change modelling and vulnerability assessment for policy and ecosystem management.