首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   14792篇
  免费   534篇
  国内免费   5766篇
安全科学   917篇
废物处理   942篇
环保管理   1171篇
综合类   8130篇
基础理论   2612篇
环境理论   2篇
污染及防治   5658篇
评价与监测   547篇
社会与环境   497篇
灾害及防治   616篇
  2024年   3篇
  2023年   224篇
  2022年   681篇
  2021年   545篇
  2020年   408篇
  2019年   429篇
  2018年   535篇
  2017年   656篇
  2016年   811篇
  2015年   1009篇
  2014年   1160篇
  2013年   1616篇
  2012年   1263篇
  2011年   1345篇
  2010年   964篇
  2009年   952篇
  2008年   1012篇
  2007年   922篇
  2006年   825篇
  2005年   603篇
  2004年   420篇
  2003年   549篇
  2002年   483篇
  2001年   408篇
  2000年   432篇
  1999年   473篇
  1998年   422篇
  1997年   351篇
  1996年   333篇
  1995年   284篇
  1994年   235篇
  1993年   188篇
  1992年   151篇
  1991年   88篇
  1990年   69篇
  1989年   54篇
  1988年   47篇
  1987年   30篇
  1986年   25篇
  1985年   13篇
  1984年   15篇
  1983年   18篇
  1982年   11篇
  1981年   12篇
  1979年   2篇
  1978年   3篇
  1976年   2篇
  1975年   4篇
  1974年   2篇
  1966年   1篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
基于中国绿洲喜凉作物(chimonophilous crop)分布区39个站点1960~2016年逐日平均气温资料,运用线性趋势法、反距离加权插值(IDW)、Morlet小波、Mann-Kendall检验等方法,研究中国绿洲喜凉作物气候生长期的时空变化对变暖停滞的响应.结果表明:①变暖停滞期,中国绿洲喜凉作物气候生长期起、止日及生长期日数以-0.2d/10a、0.33d/10a、0.53d/10a的趋势变化,较1960~2016年起始日提前趋势减缓1.01d/10a,终止日推迟减缓1.28d/10a,生长期日数延长减缓2.3d/10a,对变暖停滞有响应.②中国绿洲喜凉作物气候生长期起始日对变暖停滞响应的站点有44%,终止日和生长期日数均为49%,主要分布在南疆、柴达木盆地和河西绿洲,其中河西绿洲对变暖停滞响应最明显,南疆次之,柴达木最小,而北疆绿洲不存在滞缓现象,显然空间差异明显.③M-K检验显示,中国绿洲喜凉作物气候生长期起、止日及生长期日数分别在2001年、1990年和1997年发生突变,起始日晚于变暖停滞起始年份,终止日和生长期日数早于变暖停滞起始年,且分绿洲生长期日数突变年与变暖停滞起始年相接近.④Morlet小波得出变暖停滞期其变化稳定存在2.4~4.3a的震荡周期,表明未来几年中国绿洲喜凉作物气候生长期仍持续延长.  相似文献   
82.
To meet the challenges posed by global arsenic water contamination, the MgAlMn-LDHs with extraordinary efficiency of arsenate removal was developed. In order to clarify the enhancement effect of the doped-Mn on the arsenate removal performance of the LDHs, the cluster models of the MgAlMn-LDHs and MgAl-LDHs were established and calculated by using density functional theory (DFT). The results shown that the doped-Mn can significantly change the electronic structure of the LDHs and improve its chemical activity. Compared with the MgAl-LDHs that without the doped-Mn, the HOMO-LUMO gap was smaller after doping. In addition, the -OH and Al on the laminates were also activated to improve the adsorption property of the LDHs. Besides, the doped-Mn existed as a novel active site. On the other hand, the MgAlMn-LDHs with the doped-Mn, the increased of the binding energy, as well as the decreased of the ion exchange energy of interlayer Cl, making the ability to arsenate removal had been considerably elevated than the MgAl-LDHs. Furthermore, there is an obvious coordination covalent bond between arsenate and the laminates of the MgAlMn-LDHs that with the doped-Mn.  相似文献   
83.
某些芳香化合物生物降解性研究   总被引:29,自引:2,他引:29       下载免费PDF全文
研究了5类32种芳香化合物生物降解性,选用城市污水场污泥富集的混合菌种做菌源,在好氧生物解实验条件下,苯甲酸类、苯酚类和甲苯是较容易降解的;苯和苯的同系物是可生物降解的;苯磺酸类和含氮芳氮芳香化合物均是难降解的。  相似文献   
84.
为研究污泥静态好氧发酵中板结对强制通风和发酵进程的影响,降低通风能耗,基于理论研究确定了压降为强制通风风量的决定性因素,并通过实验获取不同发酵阶段和强制通风条件下的堆体通风量和抗剪强度数据,分析堆体内板结的形成规律,通过计算验证板结的形成和消失对通风的影响,提出了需要改善通风的时间节点;然后基于风机的变频控制研究了风机功率变化对强制通风的影响。提出的通风解决方案采用阶段变频通风,实现了堆体温度和通风风量的有效控制。  相似文献   
85.
河流枯水流量特征研究   总被引:19,自引:0,他引:19  
本文以泾、洛、渭三河流干流在陕西境内的主要控制断面为例,分析了14个时段枯水流量的概率分布特征,选定了理论分布线型,揭示了各枯水序列的时段平均流量均值、变差系数和偏态系数的变化规律,建立了推求不同频率不同时段的枯水流量的经验公式。绘制了相应的关系曲线,应用十分方便。  相似文献   
86.
Size-resolved biogenic secondary organic aerosols(BSOA) derived from isoprene and monoterpene photooxidation in Qinghai Lake, Tibetan Plateau(a continental background site) and five cities of China were measured using gas chromatography/mass spectrometry(GC/MS). Concentrations of the determined BSOA are higher in the cities than in the background and are also higher in summer than in winter. Moreover, strong positive correlations(R2= 0.44–0.90) between BSOA and sulfate were found at the six sites,suggesting that anthropogenic pollution(i.e., sulfate) could enhance SOA formation,because sulfate provides a surface favorable for acid-catalyzed formation of BSOA. Size distribution measurements showed that most of the determined SOA tracers are enriched in the fine mode( 3.3 μm) except for cis-pinic and cis-pinonic acids, both presented a comparable mass in the fine and coarse( 3.3 μm) modes, respectively. Mass ratio of oxidation products derived from isoprene to those from monoterpene in the five urban regions during summer are much less than those in Qinghai Lake region. In addition, in the five urban regions relative abundances of monoterpene oxidation products to SOA are much higher than those of isoprene. Such phenomena suggest that BSOA derived from monoterpenes are more abundant than those from isoprene in Chinese urban areas.  相似文献   
87.
ABSTRACT

The present study was carried out to investigate the effect of three organic matters (stalk powder, microbial fertilizer, and manure) on Leymus chinensis germination, growth, and urease activity and available nitrogen (N) in coastal saline soil. The study was conducted in a completely randomized design with eight treatments: J0V0Y0, J1V0Y0, J0V1Y0, J0V0Y1, J1V1Y0, J1V0Y1, J0V1Y1, J1V1Y1. The notations were based on the quantities of each agent added to 1 kg of coastal saline soil: J0 – no straw powder, J1 – 0.2 kg straw powder, Y0 – no manure, Y1 – 0.3 kg manure, V0 – no microbial fertilizer, V1 – 0.2 L microbial fertilizer, each in quantic repeat. L. chinensis was sown as 50 seeds per pot. Results indicated that addition of organic agents exerted a significantly enhanced germination, increase in fresh weight and elevated soil urease activity. Soil available N levels were significantly positively correlated with soil urease activity and fresh weight, but not with germination rate. It is noteworthy that the halophyte L. chinensis showed improved characteristics when grown in coastal saline soil with addition of organic amendments.  相似文献   
88.
主要介绍了电梯的意外轿厢移动保护功能。轿厢意外移动对乘客安全存在巨大隐患,为实现意外移动保护,利用门区及辅助轿门触点构成检测单元;AGSR及BCR检测继电器组合控制UCMR继电器,形成控制单元;UCMR继电器分别控制安全回路及抱闸回路,形成执行单元。  相似文献   
89.
MnO2 microspheres with various surface structures were prepared using the hydrothermal method, and Au/MnO2 catalysts were synthesized using the sol-gel method. We obtained three MnO2 microspheres and Au/MnO2 samples: coherent solid spheres covered with wire-like nanostructures, solid spheres with nanosheets, and hierarchical hollow microspheres with nanoplatelets and nanorods. We investigated the properties and catalytic activities of formaldehyde oxidation at room temperature. Crystalline structures of MnO2 are the main factor affecting the catalytic activities of these samples, and γ-MnO2 shows high catalytic performance. The excellent redox properties are responsible for the catalytic ability of γ-MnO2. The gold-supported interaction can change the redox properties of catalysts and accelerate surface oxygen species transition, which can account for the catalytic activity enhancement of Au/MnO2. We also studied intermediate species. The dioxymethylene (DOM) and formate species formed on the catalyst surface were considered intermediates, and were ultimately transformed into hydrocarbonate and carbonate and then decomposed into CO2. A proposed mechanism of formaldehyde oxidation over Au/MnO2 catalysts was also obtained.  相似文献   
90.
Environmental Science and Pollution Research - Microfaunal identification and analysis are very complex; thus, an image analysis method was utilized in this paper to overcome the shortcomings of...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号