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971.
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散射光下铁(Ⅲ)-丙酮酸盐配合物还原铬(Ⅵ)的研究 总被引:1,自引:0,他引:1
研究了在散射光下铁(Ⅲ)-丙酮酸盐配合物对铬(Ⅵ)的光还原反应;考察了溶液pH、铁(Ⅲ)、丙酮酸钠、铬(Ⅵ)浓度对反应的影响;分析了铬(Ⅵ)光还原反应的动力学。实验结果表明:铁(Ⅲ)-丙酮酸盐配合物体系能在较弱的散射光下还原铬(Ⅵ)。在铬(Ⅵ)浓度为19.2μmol/L、铁(Ⅲ)浓度为10.0μmol/L、丙酮酸钠浓度为240μmol/L、pH为3.0、光照240min的条件下,铬(Ⅵ)的还原率达到99.7%。从表观动力学方程的反应级数看,铁(Ⅲ)的级数(0.83)最高,铁(Ⅲ)浓度是影响铬(Ⅵ)光还原反廊速率的主要因素.铁(Ⅱ)是铬(Ⅵ)光还原的主要还原剂。 相似文献
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北京申办2008年奥运成功举国欢腾,如何建好奥运场馆举世瞩目.我们作为从事高保安智能锁具研制多年的中国科技工作者深感有义不容辞的责任,愿借此机会与大家交流,以求建好奥运场馆,推进高保安锁具发展. 相似文献
976.
Yuxin Shi Tengfei Pan Di Mu Hongqin Wu Qingqiang Meng Shuting Qi 《Environmental Chemistry Letters》2014,12(3):401-405
Phosphorus (P) is both a nutrient and a pollutant. For instance, excess P induces water eutrophication followed by death of fishes and other water life. Determination of organic P content in sediments is therefore important to study P cycling and environmental pollution. The most widely used method to determine organic P in sediments is NaOH–EDTA extraction followed by 31P-NMR detection. However, some organic P compounds are difficult to extract using NaOH–EDTA due to the low solubility, thus can not be detected by 31P NMR. Here, we used foam separation to determine organic P in sediment of North Canal of Tianjin City, China. Organic P was first enriched using foam separation coupled with NaOH extraction. The enriched organic P was then analyzed with 31P NMR. The results showed that, compared with the traditional extraction method, foam separation coupled with NaOH extraction enriched more P compound because 31P NMR detected an extra signal of teichoic acid at chemical shift 1.14. This teichoic acid signal was not detected in the extract prepared using only NaOH–EDTA. Our finding demonstrates that determination using foam separation followed by 31P NMR is feasible. 相似文献
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Zhenyan Zhang Xiaoji Fan W.J.G.M. Peijnenburg Meng Zhang Liwei Sun Yujia Zhai Qi Yu Juan Wu Tao Lu Haifeng Qian 《环境科学学报(英文版)》2021,33(1):1-9
Freshwater cyanobacterial blooms have drawn public attention because they threaten the safety of water resources and human health worldwide. Heavy cyanobacterial blooms outbreak in Lake Taihu in summer annually and vanish in other months. To find out the factors impacting the cyanobacterial blooms, the present study measured the physicochemical parameters of water and investigated the composition of microbial community using the 16S rRNA gene and internal transcribed spacer amplicon sequencing in the months with or without bloom. The most interesting finding is that two major cyanobacteria, Planktothrix and Microcystis, dramatically alternated during a cyanobacterial bloom in 2016, which is less mentioned in previous studies. When the temperature of the water began increasing in July, Planktothrix appeared first and showed as a superior competitor for M. aeruginosa in NO3?-rich conditions. Microcystis became the dominant genus when the water temperature increased further in August. Laboratory experiments confirmed the influence of temperature and the total dissolved nitrogen (TDN) form on the growth of Planktothrix and Microcystis in a co-culture system. Besides, species interactions between cyanobacteria and non-cyanobacterial microorganisms, especially the prokaryotes, also played a key role in the alteration of Planktothrix and Microcystis. The present study exhibited the alteration of two dominant cyanobacteria in the different bloom periods caused by the temperature, TDN forms as well as the species interactions. These results helped the better understanding of cyanobacterial blooms and the factors which contribute to them. 相似文献
978.
现在一说起食品,神经不免会抽动、会紧张,脑子里一片茫然,不知道食品中又会出现啥问题,真不知道吃什么才可以放心。回顾2005年,食品安全问题不断亮起红灯,苏丹红、孔雀石绿、奶粉碘超标、库存奶回用、早产奶、甲醛啤酒、致癌的保鲜膜,韩国泡菜被检出寄生虫卵,亨氏、肯德基、雀巢、立顿等跨国公司的食品也被质疑,让人目瞪口呆, 直冒冷汗。“民以食为天”。当下人们的平常食品和进口名牌食品会有如此之多的问题, 而有问题的食品为什么会充斥市场,很 相似文献
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Qu Yang Luo Hongjie Gao Guolei Wang Yaowu Wu Linli Gao Yang Xing Yulong 《Journal of Material Cycles and Waste Management》2023,25(2):1130-1141
Journal of Material Cycles and Waste Management - Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and... 相似文献
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