TiO2半导体光催化反应器的研究进展

光催化氧化作为一种高级氧化技术,在环境污染控制方面得到了较快的发展.主要介绍了国内外近年来有关光催化反应中其反应器的设计与研究进展情况,按催化剂在反应器中的存在状态分类论述了各种反应器的结构原理和主要特点,以及反应器在设计中存在的问题和今后发展的方向.     

Adsorption characteristics of copper, lead, zinc and cadmium ions by tourmaline

The adsorption characteristics of heavy metals： Cu（Ⅱ）, Pb（Ⅱ）, Zn（Ⅱ） and Cd（Ⅱ） ions on tourmaline were studied. Adsorption equilibrium was established. The adsorption isotherms of all the four metal ions followed well Langmuir equation. Tourmaline was found to remove heavy metal ions efficiently from aqueous solution with selectivity in the order of Pb（Ⅱ）〉Cu（Ⅱ）〉Cd（Ⅱ）〉Zn（Ⅱ）. The adsorption of metal ions by tourmaline increased with the initial concentration of metal ions increasing in the medium. Tourmaline could also increase pH value of metal solution.The maximum heavy metal ions adsorbed by tourmaline was found to be 78.86, 154.08, 67.25, and 66.67 mg/g for Cu（Ⅱ）, Pb（U）, Zn（Ⅱ） and Cd（U）, respectively. The temperature （25-55℃） had a small effect on the adsorption capacity of tourmaline. Competitive adsorption of Cu（Ⅱ）, Pb（Ⅱ）, Zn（Ⅱ） and Cd（Ⅱ） ions was also studied. The adsorption capacity of tourmaline for single metal decreased in the order of Pb〉Cu〉Zn 〉Cd and inhibition dominance observed in two metal systems was Pb〉Cu, Pb〉Zn, Pb〉Cd, Cu〉Zn, Cu〉Cd, and Cd〉Zn.     

青藏高原农牧区生活垃圾治理水平的地域分异与影响因素研究——以青海省4315个行政村为例

生活垃圾治理是青藏高原农牧区人居环境的突出短板,厘清农牧区生活垃圾治理水平地域分异与影响因素,可为农牧区人居环境综合整治、青藏高原生态环境风险防范提供科学依据.以青海省4315个行政村为例,多尺度解析农牧区生活垃圾集中治理覆盖率和服务人口比重,基于逻辑斯蒂回归模型的总体效应和分区效应估计,定量刻画农牧区生活垃圾治理水平影响因素.结果显示：(1)青海省农牧区生活垃圾集中治理覆盖率低于全国及西部平均水平,呈现由青东河湟谷地农区向柴达木及环湖牧区和青南高原高寒牧区梯度递减;(2)农牧区生活垃圾治理水平受海拔高程、地形地貌、垃圾转运距离等集中治理成本因素的多重影响,高海拔、山区地貌及远距离转运是农牧区生活垃圾集中治理失效的重要原因;(3)少数民族聚居、常住人口规模偏低、村域经济相对滞后的牧区仍是生活垃圾治理弱势区域,而脱贫政策支持和管理者受教育水平提升,亦会对改善生活垃圾治理水平带来积极影响.建议结合集中治理成本和常住人口分布及产污特性,因地制宜实施“村收集-镇转运-县处理”城乡一体化治理（模式Ⅰ）、“村收集-镇处理”乡镇集中治理（模式Ⅱ）及“村收集-村处理”牧区分散治理（模式Ⅲ）3类模式,采...     

产朊假丝酵母CANDIDA UTILIS细胞壁对铜离子吸附位点的研究

目前认为所有生物大分子都对重金属离子有较强吸附性 ,但某些分子可特异地吸附重金属 ,并介导酵母细胞对重金属的抗性[1] .其中细胞表面的高分子聚合物倍受关注 ,酵母细胞壁约含 4 0种蛋白分子 ,但有关这些蛋白质在对重金属离子吸附中的作用目前还未见报道 .产朊假丝酵母Ｃａｎｄｉｄａｕｔｉｌｉｓ是重要单细胞蛋白生产菌株之一 ,因其营养条件要求不高 ,对工业废水有较强耐受和转化能力而广泛用于生产和研究 .我们观察了产朊假丝酵母细胞与分离纯化的细胞壁对铜离子的吸附能力差异 ,并对细胞壁上重金属离子吸附位点进行了研究 .1　材料与方…     

钢管集团清洁生产指标体系评价应用实例

当前,我国已正式颁布实施了针对钢铁行业的一系列清洁生产标准。在这些标准中对钢铁行业的各工序及钢铁行业全流程制定了较为详实的定性、定量及体现整合性的指标体系。但截至目前,钢铁类项目清洁生产指标体系评价的应用情况参差不齐。鉴于此,以天津钢管集团股份有限公司结构调整规划项目为背景案例,分析钢铁行业清洁生产指标体系在实际项目清洁生产水平评价应用中的构架及体系,以通过此应用案例为今后钢铁行业清洁生产评价中的定性分析构架提供参考。     

活性炭及活性炭纤维对CS2的吸附行为研究及其方法探讨

以活性炭纤维(ACF)对水中CS:的吸附处理作为研究对象,并与另外两种活性炭(颗粒活性炭GAC和粉末活性炭PAC)进行对比研究,展示了ACF对CS:的优异吸附性能与处理效果,即吸附容量大,吸附低浓度效果好.同时运用新的宽平衡浓度吸附试验方法,测试了ACF、GAC、PAC对CS2的吸附平衡曲线,并对几种常见的吸附等温方程...     

Comparison of dissolved organic matter fractions in a secondary effluent and a natural water

This research compared the structural and chemical characteristics among dissolved organic matter (DOM) fractions within the same source and among different origins. Samples taken from the Taiping Wastewater Treatment Plant (TWTP) (Harbin, China) and from the Songhuajing River (SR), Heilongjiang Province, China were chosen to represent waters containing DOM of wastewater origin and of natural-water origin, respectively. DOM was fractionated using XAD resins into five fractions: hydrophobic acid (HPO-A), hydrophobic neutral (HPO-N), transphilic acid (TPI-A), transphilic neutral (TPI-N) and hydrophilic fraction (HPI). The SR fractions were more UV-sensitive and more reactive with chlorine in formation of trihalomethanes (THMs) than the TWTP secondary effluent (TSE) fractions. The aromatic character peaks in the Fourier-transform infrared (FT-IR) spectra of SR fractions were clearer than those of TSE fractions. On the other hand, the peaks of carbohydrates in TSE fractions were more prominent in comparison with SR fractions. In addition, the amide-2 peak was present in the spectra of all the five TSE fractions but not visible in the spectra of SR fractions. The fluorescence results showed that SR DOM fractions contained more fulvic acid-like fluorescent compounds while TSE DOM fractions had higher amounts of protein-like fluorescent components.     

Optimization of test interval for ageing equipment: A multi-objective genetic algorithm approach

Reducing the unavailability of safety systems at nuclear power plants, by utilizing the probabilistic safety assessment (PSA) methodology, is one of the prime goals in the nuclear industry. In that sense, optimization of test and maintenance activities, which are defined within the technical specifications, represents quite popular and interesting domain. Obtaining optimal test and maintenance schedule is of great significance for improving system availability and performance as well as plant availability in general.On the other side, equipment aging has gradually become a major concern in the nuclear industry since the number of safety systems components, that are approaching their wear-out stage, is rising fast. Nuclear power plants life management programs, considering safety components aging, are being developed and employed. The immense uncertainty associated to the available component aging rates databases poses significant difficulties in the process of incorporation and quantification of the aging effect within the PSA and, subsequently, in the decision-making process.In this paper, an approach for optimization of surveillance test interval of standby equipment with highly uncertain aging parameters, based on genetic algorithm technique and PSA, is presented. A standard standby safety system in nuclear power plant is selected as a case study. A Monte Carlo simulation-based approach is used to assess uncertainty propagation on system level. Optimal test interval is derived on the basis of minimal system unavailability and minimal impact of components aging parameters uncertainty. The results obtained in this application indicate the fact that risk-informed surveillance requirements differ from existing ones in technical specifications as well as show the importance of considering aging data uncertainties in component aging modeling.     

Advances in coastal ocean boundary layer detection technology and equipment in China

Accurate and comprehensive knowledge of the atmospheric environment and its evolution within the coastal ocean boundary layer are necessary for understanding the sources, chemical mechanisms, and transport processes of air pollution in land, sea, and atmosphere. We present an overview of coastal ocean boundary layer detection technology and equipment in China and summarize the progress and main achievements in recent years. China has developed a series of coastal ocean boundary layer detection t...     

Prenatal diagnosis of Myhre syndrome with a heterozygous pathogenic variant in SMAD4 gene presented with thick nuchal translucency and cardiac abnormalities

Prenatal testing was performed in a 39-year-old Chinese pregnant woman referred for increased nuchal translucency measuring 5.7 mm. Non-invasive prenatal testing and SNP array study on amniotic fluid samples were normal. Whole exome sequencing (WES) was initiated further as the fetus had pericardial effusion of 1.2 mm, thickened myocardium over the right ventricular lateral wall and aberrant right subclavian artery. A detailed fetal echocardiogram also revealed persistent left superior vena cava and dilated coronary sinus at 20 weeks. From whole exome sequencing of the trio, a de novo heterozygous variant NM_005359.5(SMAD4): c.1499T>C (p.Ile500Thr) was detected. This pathogenic variant has been reported in the postnatal case cohort of Myhre syndrome. This condition is characterized by facial dysmorphism, intellectual disability, hearing loss, skeletal abnormalities and potential life threatening respiratory or cardiovascular manifestations. Termination of pregnancy was performed at 23 weeks. Small chins, pre-axial polydactyly, brachydactyly and clinodactyly were noted in the abortus. Ultrasound findings of increased nuchal translucency, thickened myocardium and pericardial effusion prompted further genetic evaluation for the prenatal diagnosis of Myhre syndrome by whole exome sequencing.