带翼斜板设备处理石油污水的研究

在多层斜极分离设备的斜板下方安装一系列与料板垂直的翼板，构成了带翼斜板设备。把该设备用于石油污水的脱油处理，研究发现其具有较高的脱油效率和脱油深度。在进口含油浓度介于200～600mg／L之间，停留时间27.6min，平均脱油效率可达93．8％，出口平均含油浓度为1．8mg／L，粒径大于40μm的油滴基本均可脱除。文中还对进口含油浓度在300～400mg／L之间的出口含油浓度与表面负荷率的关系进行了论述。     

Anthropogenic Calcium Particles Observed in Beijing and Qingdao, China

Analysis of individual particles collected at Beijing in northern China revealed that particles abundant in calcium (Ca) always constituted a large fraction of mineral particles in the urban atmosphere. The particles were characterized by cubic morphologies. The major mineral element in the particles was Ca and few or no other mineral elements were detected. A large number of the particles were in the range of diameter <1 μm, where common natural mineral particles were rarely detected. The contribution of the Ca particles to the volume of total mineral particles greatly exceeded that of other mineral particles during non-dust-storm periods and was comparable to that during dust-storm periods. Reagent film tests showed that particulate sulfate and nitrate formation on the Ca particles was similar to that on common mineral particles. These results indicate that a large portion of Ca in the atmospheric particulate matter in Beijing was from anthropogenic sources rather than from natural sources, and the anthropogenic Ca particles acted as a significant medium for the formation of sulfate and nitrate. Similar particles were also detected at Qingdao, a coastal city in northern China. Data of a dust storm event showed that Ca-abundant particles from East China arrived there and moved out of the continent, similarly to Asian dust storm particles, suggesting possible contributions of anthropogenic Ca even in Asian dust storm samples in the downstream areas. Therefore, Ca may not be a good indicator of Asian dust from natural sources. However, the Ca particles, due to their unique shapes and elemental compositions, may provide an indicator for the atmospheric dispersion of anthropogenic particulate matters in East Asia.     

Degradation of carbon tetrachloride in thermally activated persulfate system in the presence of formic acid

The thermally activated persulfate (PS) degradation of carbon tetrachloride (CT) in the presence of formic acid (FA) was investigated. The results indicated that CT degradation followed a zero order kinetic model, and CO ₂ ^– · was responsible for the degradation of CT confirmed by radical scavenger tests. CT degradation rate increased with increasing PS or FA dosage, and the initial CT had no effect on CT degradation rate. However, the initial solution pH had effect on the degradation of CT, and the best CT degradation occurred at initial pH 6. Cl^– had a negative effect on CT degradation, and high concentration of Cl^– displayed much strong inhibition. Ten mmol·L^–1HCO ₃ ^– promoted CT degradation, while 100 mmol·L^–1NO ₃ ^– inhibited the degradation of CT, but SO ₄ ^2– promoted CT degradation in the presence of FA. The measured Cl–concentration released into solution along with CT degradation was 75.8% of the total theoretical dechlorination yield, but no chlorinated intermediates were detected. The split of C-Cl was proposed as the possible reaction pathways in CT degradation. In conclusion, this study strongly demonstrated that the thermally activated PS system in the presence of FA is a promising technique in in situ chemical oxidation (ISCO) remediation for CT contaminated site.     

Analysis of the toxicogenomic effects of exposure to persistent organic pollutants (POPs) in Slovakian girls: correlations between gene expression and disease risk

The chemical composition of persistent organic pollutants (POPs) in the environment is not uniform throughout the world, and these contaminants contain many structurally different lipophilic compounds. In a well-defined study cohort in the Slovak Republic, the POP chemicals present in the peripheral blood of exposed children were chemically analyzed. The chemical analysis data revealed that the relative concentration and profile of structurally different organic pollutants, including polychlorinated biphenyls (PCBs), 2,2′-bis(4-chlorophenyl)-1,1-dichloroethylene (p,p′-DDE), 2,2′-bis(4-chlorophenyl)-1,1,1-trichloro-ethane (p,p′-DDT), hexachlorobenzene (HCB) and β-hexachlorocyclohexane (β-HCH), may vary from individual to individual, even within the same exposure area. These chemicals can be broadly classified into two groups. The first group, the PCB congeners, primarily originated from industrial compounds and their byproducts. The second group of compounds originated from or was commonly used in the agricultural sector (e.g., DDT, HCB). The objective of this study was to examine the effects of the two POP exposure profiles on gene expression. For the study population, we selected pre-pubertal girls (mean age of 46.2 ± 1.4 months) with high POP concentrations in their blood (> 75% tile of total POP) and classified them in the high ‘PCB’ group when the total PCB concentration was significantly higher than the total concentration of other POP components and in the ‘Other Than PCB’ (OTP) group, when the total PCB concentration was significantly lower than the concentration of the other major POP constituents. A matched control group of girls (< 25% tile of total POP) was selected for comparison purpose (n = 5 per group). Our aims were to determine whether there were any common effects of high POP exposure at a toxicogenomic level and to investigate how exposure may affect physiological functions of the children in two different exposure scenarios. Global gene expression analysis using a microarray (Affymetrix Gene Chip Human genome U133 Plus 2.0 Array) platform was conducted on the total RNA of peripheral blood mononuclear cells from the girls. The results were analyzed by Partek GS, Louis, MI, which identified twelve genes (ATAD2B, BIVM, CD96, CXorf39, CYTH1 ETNK1, FAM13A, HIRA, INO80B, ODG1, RAD23B, and TSGA14) and two unidentified probe sets, as regulated differentially in both the PCB and OTP groups against the control group. The qRT-PCR method was used to validate the microarray results. The Ingenuity Pathway Analysis (IPA) software package identified the possible molecular impairments and disease risks associated with each gene set. Connective tissue disorders, genetic disorders, skeletal muscular disorders and neurological diseases were associated with the 12 common genes. The data therefore identified the potential molecular effects of POP exposure on a genomic level. This report underscores the importance of further study to validate the results in a random population and to evaluate the use of the identified genes as biomarkers for POP exposure.     

重氮偶联法测定水中亚硝酸盐氮的改进

重氮偶联法作为测定亚硝酸盐氮的标准方法,因具有方法灵敏、选择性强、仪器较易获得等优点,被实验室广泛采用,但也存在测定上限较低,适用样品范围较窄等缺点。通过将显色剂中磷酸改为盐酸,把重氮试剂含量提高到国标法的3倍,明显提高亚硝酸盐氮的测定上限,即由原国标法上限的0.2 mg/L提高到0.6 mg/L,灵敏度与国标法接近,且准确度和精密度良好,6组标准溶液平行测定的相对误差为1.60%,相对标准偏差为1.34%,加标回收率为96.5%~104.9%,适用于生活污水、工业废水、地表水、养殖废水等水体的测定。     

强震前淮北台地倾斜短临异常的探讨

地倾斜观测是目前我国作为探索地震前兆的重要手段之一,实践证明地倾斜与地震存在着一定的对应关系.本文尝试利用淮北台FSQ型及JB型倾斜仪的观测结果,通过分析,获取与全球、全国强震有关的短临前兆信息以及总结其基本特征,得到了一些经验性认识.     

用CAF涡凹气浮设备处理含油污水

用CAF涡凹气浮设备进行含油污水处理的试验，结果表明：当进水油、CODCr平均浓度分别为40.7mg/L、883.8mg/L，平均去除率分别为86.05%,32.62%，出水可满足后续生化处理的进水要求。     

构建生态文明的旅游观

生态文明是以人与自然协调发展为核心的观念。旅游业可持续发展中面临着“旅游景区”开发过程中的盲目性、生态旅游发展过程中的盲目性、文物古迹修缮过程中的盲目性，以及国民生态意识淡薄、旅游行为非生态化等问题。构建生态文明的旅游观，是旅游业摆脱困境，实现可持续发展的根本保证。     

生态学原理在城市改造中的应用——以天津市为例

随着中国城市化进程的加快,城市改造的速度也在加快,但是由于缺少科学的理论指导,城市改造往往表现为盲目的重建。天津市在城市的改造中,以生态学原理指导城市改造,注重城市景观多样性的保护和发展,成功地对部分城区进行了改造。对城市改造应遵循的生态学理念进行了阐述,并指出,生态学原理的运用是解决目前中国城市改造中存在的问题的有效途径;并结合天津市“五大道”和海河改造的实例说明生态学原理在城市改造中的应用。     

含模糊随机变量的水污染控制系统研究

在水流量为模糊随机变量且河流中工业污水含量标准给定的条件下,以极小化污水处理费用为目标,建立了水污染控制系统问题的模糊随机机会约束规划模型。采用将模糊随机模拟、神经元网络及遗传算法相结合的混合遗传算法来求解该模型,并用算例进行了验证,结果表明该算法是有效可行的。