Organophosphate and phthalate esters in indoor air: a comparison between multi-storey buildings with high and low prevalence of sick building symptoms

An extensive study has been conducted on the prevalence of organophosphorous flame retardants/plasticizers and phthalate ester plasticizers in indoor air. The targeted substances were measured in 45 multi-storey apartment buildings in Stockholm, Sweden. The apartment buildings were classified as high or low risk with regard to the reporting of sick building symptoms (SBS) within the project Healthy Sustainable Houses in Stockholm (3H). Air samples were taken from two to four apartments per building (in total 169 apartments) to facilitate comparison within and between buildings. Association with building characteristics has been examined as well as association with specific sources by combining chemical analysis and exploratory uni- and multivariate data analysis. The study contributes to the overall perspective of levels of organophosphate and phthalate ester in indoor air enabling comparison with other studies. The results indicated little or no difference in the concentrations of the target substances between the two risk classifications of the buildings. The differences between the apartments sampled within (intra) buildings were greater than the differences between (inter) buildings. The concentrations measured in air ranged up to 1200 ng m(-3) for organophosphate esters and up to 11?000 ng m(-3) for phthalate esters. Results in terms of sources were discerned e.g. PVC flooring is a major source of benzylbutyl phthalate in indoor air.     

Effects of Modern Forest Management on Winter Grazing Resources for Reindeer in Sweden

Boreal forests in Sweden are exploited in a number of ways, including forestry and reindeer husbandry. In the winter, reindeer feed mainly on lichens, and lichen-rich forests are a key resource in the herding system. Commercial forestry has mainly negative effects on reindeer husbandry, and conflicts between these two industries have escalated over the last century. This article reviews the effects of modern forest management practices on the winter resources available for reindeer husbandry. Forestry affects reindeer husbandry at both the stand level and the landscape level and over various time scales. Clear-cutting, site preparation, fertilization, short rotation times, and forest fragmentation have largely resulted in a reduced amount of ground growing and arboreal lichens and restricted access to resource. This article also discusses alternative forestry practices and approaches that could reduce the impacts of forestry on reindeer husbandry, both in the short and long term.     

The Swedish Environmental Classification and Information System for Pharmaceuticals — An empirical investigation of the motivations,intentions and expectations underlying its development and implementation

In 2005 the Swedish Association of the Pharmaceutical Industry (LIF) initiated a national environmental classification and information system for pharmaceuticals. This investigation reports the results from a survey, conducted among the persons involved in the start-up process. The aim of this study is to generate knowledge contributing to the clarification of the motivations, expectations, and intentions underlying the development and implementation of the system. The decision to implement a classification and information system for pharmaceuticals was the result of a combination of several driving forces, mainly political pressure and a possibility to increase the industries' goodwill, while at the same time keeping the process under the industries' control. The expected possible effects of the system, other than increased goodwill, are according to this survey assumed to be low. The system offers little guidance for end-users in the substitution of one pharmaceutical for another. One possible reason for this could be that LIF needs to observe the interests of all its members' and should not affect competition. The affiliation of the involved actors correlates to how these actors view and value the system, but this has not hampered the collaborative process to develop and implement it.     

Distribution,fate and persistence of organochlorine compounds formed during production of bleached pulp

The processes governing distribution of a xenobiotic compound discharged initially into the environment are discussed, and attention is drawn to (a) binding to organic matter in the sediment phase which affects both persistence and toxicity to biota and (b) the role of atmospheric transport for compounds of low water solubility and high vapour pressure. Important limitations in the use of sum parameters such as EOCI are pointed out. The important distinction between biodegradation and biotransformation is pointed out, and significant experimental determinants noted. Pathways for the aerobic metabolism of chlorophenolic compounds are discussed, and attention is drawn to the role of O‐methylation as an environmentally significant alternative to biodegradation. Evidence for the biodegradation of chlorinated aliphatic acids and hydrocarbons under both aerobic and anaerobic conditions is presented. Anaerobic metabolism of chlorophenolic compounds is discussed with respect to (a) de‐O‐methylation of chloroguaiacols, (b) dechlorination of chlorocatechols and (c) reduction of chlorovanillins. It is emphasized that current evidence provides a complex metabolic picture, and that only partial dechlorination may occur. Brief attention is given to the important issue of the persistence of chlorolignin, and attention drawn to technical issues which render this problem difficult of access by traditional procedures. Biohalogenation—particularly by fungi—is noted, though its quantitative contribution cannot be estimated at the moment. A number of important unresolved issues are underscored: (a) the problem of determining rates of microbial reactions which may be translated to environmental situations, (b) the cardinal role not only of the number of chlorine atoms in an aromatic compound but also the substitution pattern and (c) limitations in current understanding of the role of anaerobic bacteria in bringing about biodegradation and biotransformation.     

Estimations of Real-World N2O Emissions from Road Vehicles by Means of Measurements in a Traffic Tunnel

Abstract

Ambient air measurements of N₂O, NO_x, CO, and HC based on grab sampling were conducted in a major traffic tunnel in Sweden, that carries up to 4,000 vehicles per hour, in order to estimate real-world emissions of N₂O for road traffic. Two different methods—relative and mass balance—were used to calculate a N₂O emission factor for the mixed vehicle fleet, which gave an average emission factor, at average speeds of 30-70 km/h, of approximately 25 mg N₂O/ km, with a range of 7-56 mg/km.     

Toxicity assessment of textile effluents treated by advanced oxidative process (UV/TiO2 and UV/TiO2/H2O2) in the species Artemia salina L.

Textile industry wastes raise a great concern due to their strong coloration and toxicity. The objective of the present work was to characterize the degradation and mineralization of textile effluents by advanced oxidative processes using either TiO₂ or TiO₂/H₂O₂ and to monitor the toxicity of the products formed during 6-h irradiation in relation to that of the in natura effluent. The results demonstrated that the TiO₂/H₂O₂ association was more efficient in the mineralization of textile effluents than TiO₂, with high mineralized ion concentrations (NH ₄ ⁺ , NO ₃ ^? , and SO ₄ ^2? ) and significantly decreased organic matter ratios (represented by the chemical oxygen demand and total organic carbon). The toxicity of the degradation products after 4-h irradiation to Artemia salina L. was not significant (below 10 %). However, the TiO₂/H₂O₂ association produced more toxicity under irradiation than the TiO₂ system, which was attributed to the increased presence of oxidants in the first group. Comparatively, the photogenerated products of both TiO₂ and the TiO₂/H₂O₂ association were less toxic than the in natura effluent.     

Health impact assessment of Roma housing policies in Central and Eastern Europe: A comparative analysis

Marginalised Roma communities in European countries live in substandard housing conditions the improvement of which has been one of the major issues of the Decade of Roma Inclusion, the ongoing intergovernmental European Roma programme. The paper presents EU-funded health impact assessments of national Roma housing policies and programmes in 3 Central and Eastern European countries in light of the evaluation of a completed local project in a fourth CEE country so as to compare predicted effects to observed ones. Housing was predicted to have beneficial health effects by improving indoor and outdoor conditions, access to services, and socioeconomic conditions. Negative impacts were predicted only in terms of maintenance expenses and housing tenure. However, observed impacts of the completed local project did not fully support predictions especially in terms of social networks, satisfaction with housing and neighbourhood, and inhabitant safety. In order to improve the predictive value of HIA, more evidence should be produced by the careful evaluation of locally implemented housing projects. In addition, current evidence is in favour of planning Roma housing projects at the local rather than at the national level in alignment with the principle of subsidiarity.     

12th EuCheMS International Conference on Chemistry and the Environment

Environmental Science and Pollution Research -     

Bioassessment tools in novel habitats: an evaluation of indices and sampling methods in low-gradient streams in California

Biomonitoring programs are often required to assess streams for which assessment tools have not been developed. For example, low-gradient streams (slope ≤1%) comprise 20–30% of stream miles in California and are of particular interest to watershed managers, yet most sampling methods and bioassessment indices in the state were developed in high-gradient systems. This study evaluated the performance of three sampling methods [targeted riffle composite (TRC), reach-wide benthos (RWB), and the margin–center–margin modification of RWB (MCM)] and two indices [the Southern California Index of Biotic Integrity (SCIBI) and the ratio of observed to expected taxa (O/E)] in low-gradient streams in California for application in this habitat type. Performance was evaluated in terms of efficacy (i.e., ability to collect enough individuals for index calculation), comparability (i.e., similarity of assemblages and index scores), sensitivity (i.e., responsiveness to disturbance), and precision (i.e., ability to detect small differences in index scores). The sampling methods varied in the degree to which they targeted macroinvertebrate-rich microhabitats, such as riffles and vegetated margins, which may be naturally scarce in low-gradient streams. The RWB method failed to collect sufficient numbers of individuals (i.e., ≥450) to calculate the SCIBI in 28 of 45 samples and often collected fewer than 100 individuals, suggesting it is inappropriate for low-gradient streams in California; failures for the other methods were less common (TRC, 16 samples; MCM, 11 samples). Within-site precision, measured as the minimum detectable difference (MDD) was poor but similar across methods for the SCIBI (ranging from 19 to 22). However, RWB had the lowest MDD for O/E scores (0.20 versus 0.24 and 0.28 for MCM and TRC, respectively). Mantel correlations showed that assemblages were more similar within sites among methods than within methods among sites, suggesting that the sampling methods were collecting similar assemblages of organisms. Statistically significant disagreements among methods were not detected, although O/E scores were higher for RWB samples than TRC. Index scores suggested impairment at all sites in the study. Although index scores did not respond strongly to several measurements of disturbance in the watershed, percent agriculture showed a significant, negative relationship with O/E scores.