Effect on herbicide adsorption of organic forestry waste products used for soil remediation

Organic soil amendments can be useful for improving degraded soil, but this increase in organic matter (OM) may influence adsorption of herbicides subsequently applied to the treated soil, even though the particle size of amendments and their nature differ from typical soil OM. In this study, a batch equilibrium method was used to measure adsorption of five herbicides following application to two organic media, wood pulp and sawdust, comparing these with two cropping soils. Herbicide adsorption, quantified by distribution coefficients (k_d), was much higher in the two organic media than in the cropping soils. The increases in adsorption were strongly correlated to the percentage of organic carbon. When the k_d was normalized to adsorption coefficients corrected for OM content (k_oc), variation in results between the media was greatly reduced, indicating that OM is an important factor influencing adsorption in these media. The results of this study suggest that herbicides will be less effective when applied to soils in which sawdust and wood pulp have been added. Using organic amendments to remediate soil will increase adsorption of pesticides, reducing their bio-availability and efficacy, but also reducing their tendency to leach into root zones of deep-rooted crops and into groundwater.     

Effectiveness of nanoscale zero-valent iron for treatment of a PCE-DNAPL source zone

Nanoscale zero-valent iron (nZVI) has received considerable attention as a potential in situ remediation technology for treating chlorinated solvent source zones. Experimental and mathematical modeling studies were conducted to investigate the performance of nZVI in the transformation of tetrachloroethene (PCE) entrapped as a dense nonaqueous phase liquid (DNAPL). Injection of a 60 g/L suspension of nZVI into a column containing 20-30 mesh Ottawa sand and PCE-DNAPL at a residual saturation of 5.5% resulted in a uniform distribution of nZVI and minimal displacement of PCE. Subsequent flushing with 267 pore volumes of water containing 3mM CaCl(2) at a Darcy velocity of 0.75 m/day resulted in steady-state effluent concentrations of PCE near the solubility limit (ca. 200mg/L) and production of dissolved-phase ethene (10-30 mg/L). Over the duration of the experiment, approximately 30% of the initial PCE-DNAPL mass reacted to form ethene, 50% was eluted as dissolved-phase PCE, and 20% remained in the column as PCE-DNAPL. To further explore the implications of the nZVI column results, a multiphase transport model was developed that incorporated rate-limited PCE-DNAPL dissolution and reactions with nZVI. Using a fitted pseudo first-order transformation rate coefficient of 1.421/h, the model accurately captured observed trends in effluent concentrations of PCE and ethene and overall mass balance. A model sensitivity study reveals a strong dependence of treatment effectiveness on system characteristics. The sensitivity analysis suggests that an increase in the extent of PCE transformation is facilitated by decreasing flow rate, emplacement of nZVI down-gradient of the DNAPL source zone, and decreasing length of the DNAPL source zone. These findings indicate that, although emplacement of high concentrations of nZVI within a PCE-DNAPL source zone can result in substantial transformation of the parent compound, careful attention to design parameters (e.g. flow rate, location and amount nZVI delivered) will be required to achieve complete conversion to benign reaction products.     

Hydraulics Near Unscreened Diversion Pipes in Open Channels: Large Flume Experiments

Most of the water diversions on the Sacramento and San Joaquin Rivers (California, United States) and their tributaries are currently unscreened. These unscreened diversions are commonly used for irrigation and are potentially harmful to migrating and resident fishes. A large flume (test section: 18.29 m long, 3.05 m wide and 3.20 m high) was used to investigate the hydraulic fields near an unscreened water diversion under ecologically and hydraulically relevant diversion rates and channel flow characteristics. We investigated all combinations of three diversion rates (0.28, 0.42, and 0.57 m³/s) and three sweeping velocities (0.15, 0.38, and 0.61 m/s), with one additional test at 0.71 m³/s and 0.15 m/s. We measured the three‐dimensional velocity field at seven cross sections near a diversion pipe and constructed regression equations of the observed maximum velocities near the pipe. Because the velocity components in three directions (longitudinal, transverse, and vertical) were significantly greater near the diversion pipe inlet compared with those farther from it, they cannot be neglected in the modeling and design of fish guidance and protection devices for diversion pipes. Our results should be of great value in quantifying the hydraulic fields that are formed around fish guidance devices to design more effective protection for fishes from entrainment into unscreened water‐diversion pipes.     

Sustainable cropping pattern in North Iran: application of fuzzy goal programming

Due to the important role that the application of mathematical programming models have in determining optimal cropping patterns, this research presents a sustainable cropping pattern that considers selected economic, environmental, and social goals together. Using a random sampling method, a sample size of 168 farmers was selected in the Sari County, Iran. Our results showed that economic, self-sufficiency, environmental, and social goals have a distinctly different impact on cropping pattern performance. Compared to the current cropping pattern, the gross margins for economic and social goals increased by nearly 11 and 2 %, respectively, and the gross margins for self-sufficiency and environmental goals decreased by nearly 2 and 36 %. Interestingly, it has been found that the performance of the current cropping pattern has an average positive impact of 6 % if economic, self-sufficiency, environmental, and social (employment) goals are realized simultaneously.     

Fingerprinting and Groundwater Model Application to Evaluate Hydraulic Barrier Efficiency (Italy)

Remediation actions at contaminated sites are based on multiple numerical model scenarios considering different parameter distributions, source positions and contaminant transport paths. In some cases the excess of scenarios is due to uncertainties in the conceptual model as a result of the spread of contamination through heterogeneities in the physical system. Reduction of project hypotheses and conceptual model uncertainty is therefore needed. This result can be achieved by coupling hydrogeological investigations with environmental forensic techniques, better localization of the source and understanding of contamination history. In this respect, in the present study, compositional fingerprinting and groundwater flow modeling were applied to a former oil storage facility where, even though a hydraulic barrier had been built to stop the hydrocarbon plume, the presence of some hydrocarbons was still found in downgradient monitoring wells. The final aim was to evaluate the efficacy of the hydraulic barrier and identify of the source of pollution. Fingerprinting results indicated pollution with a gasoline-diesel mixture much altered by water washing and/or biodegradation. Comparison of seven groundwater samples collected in wells and monitoring wells was performed by analyzing the volatile fraction (BTEX) and the total ion chromatogram (TIC), focusing attention on: n-alkanes (m/z 85), alkylcyclohexanes (m/z 83), isoprenoids (m/z 113), C4-alkylbenzenes (m/z 134), C3-C6 alkylbenzenes and polycyclic aromatic hydrocarbons (PAHs). The most probable scenario was then identified by combining the results of fingerprinting with different contaminant paths obtained using the numerical model.     

ANN-based mapping of monthly reference crop evapotranspiration by using altitude, latitude and longitude data in Fars province, Iran

The main goal of this study was to evaluate the different feed-forward back-propagation artificial neural networks’ (ANNs) potential to estimate and interpolate the reference crop evapotranspiration (ET₀) in Fars province of Iran. ET₀ was calculated using the FAO-56 Penman–Monteith method over 24 synoptic stations. Then, altitude, latitude, longitude and the month’s number as inputs and the monthly ET₀ as output (target) were used to train the ANNs. In addition, the three-layered ANNs optimized with different training algorithms including gradient descent back-propagation (gd), gradient descent with adaptive learning rate back-propagation (gda), gradient descent with momentum and adaptive learning rate back-propagation (gdx) and scaled conjugate gradient back-propagation (scg). The results indicated that scg algorithm with architecture (4 2 1) had more satisfactory results with the RMSE and R correlation coefficient equal to 18.538 mm and 0.967 in validation phase, respectively. Based on the mentioned architecture of scg algorithm, and input data form different parts of Fars province and surrounding areas, monthly ET₀ maps were produced and annual one achieved by summation of monthly maps. The maps particularly annual one showed that highest values of ET₀ could be found in the southern and especially southeastern regions, while the lowest values of ET₀ could be seen in the northern parts. Contribution of geographic and topographic variables improved the accuracy and spatial details of the resulting maps. It is interesting to note that the fundamental capability of this model is the usage of just a few parameters for ET₀ mapping. Since ET₀ is a key parameter in water demand planning, therefore, the derived maps could be useful and applicable for many purposes mainly irrigation scheduling in Fars province, Iran.     

Comparison of understorey bird species in relation to edge–interior gradient in an isolated tropical rainforest of Malaysia

Forest fragmentation results in a loss of forest interior and an increase in edge habitat. As a result, these changes may affect the bird species distribution and composition. We studied how understorey bird community composition and habitat variables changed along an edge-to-interior gradient in a fragmented lowland rainforest in Peninsular Malaysia. Birds and environmental variables were recorded at each of the 93 sampling points distributed along the 14 parallel transects that were systematically placed across the gradient of distance from the forest edge to the forest interior. Species composition was different along the edge–interior gradient, although only a few species were strictly confined to either edge or interior habitat. Based on bird–habitat associations along the edge–interior gradient, some of these edge-preferred species occurred in high numbers at the matrix surrounding the patch. In contrast, the interior-specialist group, mainly terrestrial insectivores, avoided the forest edge and was positively associated with humidity, canopy cover, the number of dead trees, percentage of litter cover, and depth of the litter layer. Species endemic to the Sunda subregion were more abundant in the interior of the forest. From a conservation perspective, forest remnants in the lowlands of Peninsular Malaysia that have a deep leaf litter layer, dense canopy cover, high number of dead trees, and high relative humidity are able to support understorey bird species that are sensitive to edge effects. The forest has important conservation value even though it is fragmented and isolated.     

The significance of a small, level-3 'semi evacuation' hospital in a terrorist attack in a nearby town

Terrorist attacks can occur in remote areas causing mass-casualty incidents MCIs far away from level-1 trauma centres. This study draws lessons from an MCI pertaining to the management of primary and secondary evacuation and the operational mode practiced. Data was collected from formal debriefings during and after the event, and the medical response, interactions and main outcomes analysed using Disastrous Incidents Systematic Analysis through Components, Interactions and Results (DISAST-CIR) methodology. A total of 112 people were evacuated from the scene-66 to the nearby level 3 Laniado hospital, including the eight critically and severely injured patients. Laniado hospital was instructed to act as an evacuation hospital but the flow of patients ended rapidly and it was decided to admit moderately injured victims. We introduce a novel concept of a 'semi-evacuation hospital'. This mode of operation should be selected for small-scale events in which the evacuation hospital has hospitalization capacity and is not geographically isolated. We suggest that level-3 hospitals in remote areas should be prepared and drilled to work in semi-evacuation mode during MCIs.     

The dynamic nexus between air transport,technological innovation,FDI, and economic growth: evidence from BRICS-MT countries

Environmental Science and Pollution Research - This study examines the endogenous growth theory for technological innovation and economic growth with the role of foreign direct investment (FDI) and...     

Microplastics in urban waters and its effects on microbial communities: a critical review

Environmental Science and Pollution Research - Microplastic (MP) pollution is one of the emerging threats to the water and terrestrial environment, forcing a new environmental challenge due to the...