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排序方式: 共有148条查询结果,搜索用时 503 毫秒
101.
Dechlorination of polychlorinated organic compounds by electrochemical reduction with naphthalene radical anion as mediator 总被引:1,自引:0,他引:1
Electrochemical reduction with electrochemically generated naphthalene radical anion in N,N-dimethylformamide was applied to the dechlorination of five representative POPs, namely HCB, lindane, DDT, PCP and aldrin. Rapid and complete dechlorination was possible for lindane and DDT to give nearly quantitative yields of benzene and 1,1-diphenylethane, respectively. HCB was reduced through complex reaction pathways to yield unknown products. Dechlorination of PCP and aldrin beyond dichlorinated compounds was difficult because of their very negative reduction potential. The reaction pathways for each dechlorination were proposed with the identification of intermediates. 相似文献
102.
Certain chemicals possess the potential to modulate endocrine systems, and thereby interfere with reproduction and developmental processes in the wild. We analyzed endocrine disrupters nonylphenol (NP) and bisphenol A (BPA) levels at various sites in Okinawa and Ishigaki Islands, Japan. River-water samples showed undetectable to low concentrations of NP and BPA at most of the sites investigated. However, an appreciable amount of BPA was detected in sediments at one coral reef site. In addition, significant numbers of river sediment samples showed appreciable amounts of NP and BPA. Most of the sampling sites for this study are located within a distance of 1 km from the coral reefs, which are under influence of river-waters to a variable extent. Therefore, influence of endocrine disrupters may have already begun on adjacent coral reefs. Both endocrine disrupters were positively correlated with human population densities, but not with the contents of red soil generated by farm land reformation. Therefore, it is concluded that NP and BPA pollution is a consequence of human waste discharge, both domestic and industrial, and not by agricultural activities. 相似文献
103.
Hiroshi Shimizu MD PhD Akira Ishiko Arata Kikuchi Masashi Akiyama Kaoru Suzumori Takeji Nishikawa 《黑龙江环境通报》1994,14(6):443-450
An electron microscopic DOPA reaction test of fetal skin was used for the prenatal diagnosis of tyrosinase-negative oculocutaneous albinism (OCA). The subject was a 34-year-old Japanese woman in her second pregnancy. Her first child, born in 1982, had been previously examined and confirmed to have tyrosinase-negative OCA. The parents requested a prenatal diagnosis and we sampled skin from the upper trunk of the fetus. On conventional electron microscopy, the development of melanosomes in interfollicular melanocytes had progressed no further than stage II. Fetal skin samples incubated with L-DOPA solution indicated a lack of tyrosinase activity and showed that the melanosomes had not progressed beyond stage II. In skin samples from the trunks of three Japanese fetuses aborted for other reasons at 19–20 weeks of gestation, most premature melanosomes were further melanized to stage IV after incubation with L-DOPA solution. A prenatal diagnosis of tyrosinase-negative OCA was made. The parents requested a termination and skin biopsies of the abortus confirmed the diagnosis. This study shows that tyrosinase is normally present in melanocytes of the fetal epidermis at 20 weeks' gestation, and that the electron microscopic DOPA reaction test of a fetal skin biopsy specimen is safe and practical, and provides reliable information for making a prenatal diagnosis of tyrosinase-negative OCA in the second trimester. 相似文献
104.
Yutaka Saito Anthony R. Chittenden Kotaro Mori Katsura Ito Atsushi Yamauchi 《Behavioral ecology and sociobiology》2008,63(1):33-42
The number of nests containing egg masses a female makes over her lifetime and the pattern of scattering nests vary among
species in a genus of nest-weaving spider mites (Stigmaeopsis). We hypothesized that the scattered nests of small nest builders have a previously overlooked indirect effect in that the
void nests created after predation take on a new role as hindering devices that effectively decrease predator searching efficiency.
First, we demonstrated that the experimental design used in this study is a good reflection of the nest distribution pattern
of Stigmaeopsis takahashii (an intermediate-sized nest builder) in the field. Using this species as a model, we tested how different nest-scattering
patterns affect the predator to examine how scattering may indirectly provide an anti-predation strategy by increasing a predators
searching time. Next, we observed how artificially arranged void nests disturb predatory behavior in both starved and fully
fed predator females and showed that void nests have a strong hindering effect on predators. Thus, we concluded that the nesting
behavior of this mite species not only has anti-predator effects but must also have a stabilizing effect on predator–prey
interaction systems at the population level. 相似文献
105.
Snappers (Lutjanidae) are one of the important fisheries resources in tropical and subtropical waters. However, there have
been few studies clarifying the ecology of newly settled juvenile snappers. The aims of the present study were to clarify
the seasonality and lunar periodicity of the larval settlement, and the microhabitat association of newly settled juveniles
for Lutjanus gibbus in an Okinawan coral reef. Fifteen coral patches were chosen and underwater visual surveys were conducted during a 2-year
period. The larval settlement of the species mainly occurred between May and October during the 2-year survey period. In terms
of lunar periodicity of the settlement, the newly settled juveniles were mainly found between the last quarter moon and new
moon during the main settlement season. Back calculations of settlement dates based on otolith microstructure showed that
most juveniles settled during the last quarter moon and new moon. Stepwise multiple regression analyses revealed that the
newly settled juveniles were mainly found on coral patches with a large number of holes on the top of the coral patch and
this tendency was mainly consistent during the study period. The volume of holes at the base of coral patches had also a positive
effect on the abundance of newly settled juveniles in some cases. The results of the present study suggest that larval settlement
has a strong seasonal and lunar periodicity, and newly settled juveniles select coral patches with available refuge spaces. 相似文献
106.
Atsushi Terazono Yuichi Moriguchi Shin-ichi Sakai Hiroshi Takatsuki 《Journal of Material Cycles and Waste Management》2000,2(2):80-88
This study evaluated the environmental impacts of sprayed-on asbestos, which had been used as insulation material in buildings,
from multiple perspectives, mainly at the disposal stage. The health risks from asbestos emission and energy consumption were
estimated. Two disposal scenarios were assumed for the asbestos: melting for reduced-risk disposal and ordinary packaging/landfilling.
We estimated the asbestos emission and health risk in the case of packaging/landfilling, assuming uncontrolled management
of the landfill site. A difficulty with introducing health-risk concepts into life cycle assessment (LCA) is the pulse–flux
problem, which is discussed in the light of these estimations. In order to solve this problem, we proposed a method using
a conversion factor representing exposure-dose/emission, and showed that emission could be converted into health risk. We
also estimated the energy consumption for melting asbestos in the disposal stage, which can decrease the health risk. If we
consider the energy consumption for the life cycle of asbestos, only a little energy is required for melting, compared with
the large amount of energy saved in the use stage owing to the insulating effect of the asbestos. The trade-off relationship
between health risk and energy consumption for the disposal scenarios indicated the need for weighting methods to handle trade-offs
such as this.
Received: July 2, 1998 / Accepted: December 20, 1999 相似文献
107.
Aikawa M Hiraki T Tamaki M Kasahara M Kondo A Uno I Mukai H Shimizu A Murano K 《Environmental monitoring and assessment》2006,122(1-3):61-79
An intensive field survey, with 6-h measurement intervals, of concentrations of chemical species in particulate matter and gaseous compounds was carried out at coastal sites on the Sea of Japan during winter. The concentration variation of SO2(g) and HNO3(g) were well correlated, whereas the NH3(g) concentration variation had no correlation with those of SO2(g) and HNO3(g). The NH4
+ (p)/non-sea-salt- (nss-)SO4
2 −(p) ratio in particulate matter was mainly affected by the location of the sampling site. One or more concentration peaks of nss-Ca2 + for survey period were observed. Backward trajectories analyses for the highest nss-Ca2 + concentration peaks showed some inconsistency in pathways. We consider that insufficient mixing of the atmosphere and/or insufficient time for the transported air pollutants to react with those discharged locally are the most likely explanations for the discrepancies between the measured products [HNO3][NH3] and the calculated values. 相似文献
108.
109.
Masami Fukushima Xuefei Tu Apichaya Aneksampant Atsushi Tanaka 《Journal of Material Cycles and Waste Management》2018,20(1):176-184
Parameters that affect the degree of humification for humic substances (HSs) are deeply related to the maturity of the compost. In general, the matured composts contain HSs with a higher degree of humification. In addition, microbial activities during composting are also one of the indices for compost maturation. Branched-chain fatty acids are metabolites as the result of microbial activities in a soil environment. Such branched-chain fatty acids, regarded as humic precursors, are incorporated into HSs during the composting process. To determine whether branched-chain fatty acids in HSs can be used as biomarkers during composting processes or not, HSs were extracted from three types of composts with the different maturation, and the branched-chain fatty acids in the HSs were analyzed by pyrolysis–gas chromatography/mass spectrometry with tetramethylammonium hydroxide (TMAH-py–GC/MS). HSs with a higher degree of humification (higher aromaticity and lower molecular weight) contained higher levels of branched-chain fatty acids. These results show that branched-chain fatty acids in HSs from matured compost samples can be used as biomarkers, which indicate the history of microbial activities during overall composting process. 相似文献
110.