全文获取类型
收费全文 | 1242篇 |
免费 | 7篇 |
国内免费 | 14篇 |
专业分类
安全科学 | 19篇 |
废物处理 | 91篇 |
环保管理 | 85篇 |
综合类 | 203篇 |
基础理论 | 202篇 |
环境理论 | 1篇 |
污染及防治 | 391篇 |
评价与监测 | 191篇 |
社会与环境 | 68篇 |
灾害及防治 | 12篇 |
出版年
2023年 | 29篇 |
2022年 | 62篇 |
2021年 | 43篇 |
2020年 | 14篇 |
2019年 | 20篇 |
2018年 | 55篇 |
2017年 | 44篇 |
2016年 | 74篇 |
2015年 | 28篇 |
2014年 | 76篇 |
2013年 | 111篇 |
2012年 | 50篇 |
2011年 | 74篇 |
2010年 | 68篇 |
2009年 | 65篇 |
2008年 | 77篇 |
2007年 | 62篇 |
2006年 | 46篇 |
2005年 | 39篇 |
2004年 | 37篇 |
2003年 | 33篇 |
2002年 | 31篇 |
2001年 | 14篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 2篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1979年 | 2篇 |
1966年 | 2篇 |
1965年 | 3篇 |
1964年 | 5篇 |
1963年 | 5篇 |
1962年 | 2篇 |
1961年 | 4篇 |
1960年 | 5篇 |
1959年 | 2篇 |
1958年 | 2篇 |
1957年 | 6篇 |
1942年 | 2篇 |
1941年 | 2篇 |
1927年 | 1篇 |
排序方式: 共有1263条查询结果,搜索用时 109 毫秒
41.
Preparation, Thermal Properties and Thermal Reliability of Form-Stable Paraffin/Polypropylene Composite for Thermal Energy Storage 总被引:1,自引:0,他引:1
This study is focused on the preparation, characterization, and determination of thermal properties and thermal reliability
of paraffin/polypropylene (PP) composite as a novel form-stable phase change material (PCM) for thermal energy storage applications.
In the composite, paraffin acts as a PCM when PP is operated as supporting material. The composites prepared at different
mass fractions of paraffin (50, 60, 70, 80, and 90 w/w%) by solution casting method were subjected to leakage test by heating
the composites over the melting temperature of the PCM. The paraffin/PP composite (70/30 w/w%) is found as the maximum paraffin
containing composite and was characterized using Fourier transform infrared spectroscopy, optic microscopy, differential scanning
calorimetry (DSC), and thermal gravimetric analysis (TGA) techniques. DSC analysis indicated that the form-stable paraffin/PP
composite melts at 44.77–45.52 °C and crystallizes at 53.55–54.80 °C. It has latent heats of 136.16 and −136.59 J/g for melting
and crystallization, respectively. These thermal properties make it potential PCM for latent heat thermal energy storage (LHTES)
purposes such as solar space heating applications. Accelerated thermal cycling tests indicated that the form-stable PCM had
good thermal reliability. TGA also showed that the form-stable PCM degrades in two distinguishable steps and had good chemical
stability. 相似文献
42.
Daniel Gorman Touria Bajjouk Jacques Populus Mickaël Vasquez Axel Ehrhold 《Marine Biology》2013,160(2):309-325
We address the global deficit of data describing kelp forest distribution, relative covers and biomass by testing the ability of species distribution models to predict these attributes at locations where data are currently limited. We integrated biological ground truth data with high-resolution environmental datasets to develop generalized additive models that accurately predict the structure of Laminaria forests within the Bay of Morlaix (48°42′42″N, 3°55′40″W). Forest distribution and proportional covers were predicted using water depth, light availability, wave exposure and sediment dynamics. The biomass of individual kelp species was modeled by supplementing these same variables with measures of seafloor slope and benthic position. Biomass predictions for Laminaria digitata and Laminaria hyperborea contrast the physiological tolerances of these species to light and wave exposure gradients. As a direct management output, we produced high-resolution maps (25 m2 grids) that closely match independent field data and provide vital information for marine spatial planning. 相似文献
43.
Merlin Aydın Hale Tozlu Sebnem Kemaloglu Ayse Aytac Guralp Ozkoc 《Journal of Polymers and the Environment》2011,19(1):11-17
In this study, the influence of alkali (NaOH) treatment on the mechanical, thermal and morphological properties of eco-composites
of short flax fiber/poly(lactic acid) (PLA) was investigated. SEM analysis conducted on alkali treated flax fibers showed
that the packed structure of the fibrils was deformed by the removal non-cellulosic materials. The fibrils were separated
from each other and the surface roughness of the alkali treated flax fibers was improved. The mechanical tests indicated that
the modulus of the untreated fiber/PLA composites was higher than that of PLA; on the other hand the modulus of alkali treated
flax fiber/PLA was lower than PLA. Thermal properties of the PLA in the treated flax fiber composites were also affected.
Tg values of treated flax fiber composites were lowered by nearly 10 °C for 10% NaOH treatment and 15 °C for 30% NaOH treatment.
A bimodal melting behavior was observed for treated fiber composites different than both of neat PLA and untreated fiber composites.
Furthermore, wide angle X-ray diffraction analysis showed that the crystalline structure of cellulose of flax fibers changed
from cellulose-I structure to cellulose-II. 相似文献
44.
Nazan Karsavuran Mohammad Charehsaz Hayati Celik Bayram Murat Asma Cengiz Yakıncı 《毒物与环境化学》2013,95(10):1564-1570
Hydrogen cyanide (HCN) poisoning due to amygdalin (AMY) in apricot seeds is one of the public health issues in Turkey. The aim of this study was to investigate the AMY content of 13 different apricot seeds including bitter and sweet ones, and which are either sulfurized or roasted. The AMY content was determined by a high-performance liquid chromatography. Release of HCN was predicted and total amount of seeds which can cause poisoning was calculated. The mean AMY content of bitter seeds was 26 ± 14 mg g?1 and that of sweet seeds was 0.16 ± 0.09 mg g?1. The consumption of small amounts of bitter seeds may cause cyanide poisoning. 相似文献
45.
Predictive value of cardiovascular parameters in stages 1 and 2 of twin-to-twin transfusion syndrome
46.
Nur Okur A. Levent Tuna Bülent Okur Hakan Altunlu H. Hüsnü Kayikçioğlu Hasan S. Civelek 《Environmental monitoring and assessment》2010,165(1-4):389-397
Efficacious botanical derivatives can provide an alternative to synthetic pesticides for organic farming systems. However, there is lack of information regarding the side effects of organic pesticides on key soil ecological processes. In this study, we investigated the effects of aqueous extracts from Urginea maritima and Euphorbia myrsinites exhibiting translaminar and systemic activity against pests on microbial biomass and enzymatic activities in soil. Two grams of plant material was extracted with 100 ml of water and then diluted 1:100, 2:100, and 4:100 with distilled water. Diluted plant extracts were applied around hypocotyl of tomato by soil drench. The effect of both plant extracts on microbial biomass C, amount of total N and organic C, and enzymatic activity in soil was significant. After the last application, the highest microbial biomass C was determined in the lowest U. maritima concentration (U 1:100). Soils treated with the highest concentration of U. maritima (U 4:100) had always lower SMBC content than control soil. All concentrations of E. myrsinites decreased microbial biomass C by 18% to 27% compared to the control. Total nitrogen and organic carbon decreased in soils without (control) and with treated U. maritima extract from first application to last application. Phosphatase, urease, and β-glucosidase activities were monitored in plant extract-treated soils. Except U. maritima 1:100 treatments of second and fourth applications, the other treatments of plant extracts negatively affected enzymatic activity in soil. U. maritima and E. myrsinites plant extracts exhibited different effects on soil microbial biomass and activity, probably because of their different chemical contents. 相似文献
47.
Z. Szigeti I. Rácz É. Darkól D. Lásztity E. Lehoczki 《Journal of environmental science and health. Part. B》2013,48(3):599-604
Abstract Paraquat/atrazine coresistant (PqAR) and paraquat resistant (PqR) horseweed (Conyza canadensis /L./ Cronq.) plants showed ‐ in the first hour after 0.5 mM paraquat spraying ‐ a decreased catalase activity followed by a slight increase. However, the enzyme activity remained always below the initial value. Sensitive plants showed a significant increase of catalase activity in the first 4 hour after spraying. The transient character of paraquat inhibition, the recovery of photosyn‐thetic activity of the PqAR Conyza plants (characterized by variable fluorescence) after spraying remained unaffected by the Superoxide dismutase (SOD) inhibitor, diethyldithiocarbamate. This indicates that SOD is not involved in the resistance mechanism. Untreated resistant biotypes showed about 2.5 times higher total polyamine and putrescine level than the sensitive one. 100 μM of exogenously added putrescine was observed as having a protecting effect against paraquat in floated leaves of the sensitive biotype only. The resistant leaves were unaffected probably on account of their higher endogenous polyamine level. It is concluded that polyamines may play a role in the paraquat resistance of Conyza canadensis. 相似文献
48.
Perrier F Richon P Crouzeix C Morat P Le Mouël JL 《Journal of environmental radioactivity》2004,71(1):17-32
Radon-222 activity concentration has been monitored since 1999 in an underground limestone quarry located in Vincennes, near Paris, France. It is homogeneous in summer, with an average value of 1700 Bq m(-3), and varies from 730 to 1450 Bq m(-3) in winter, indicating natural ventilation with a rate ranging from 0.5 to 2.4 x 10(-6) s(-1) (0.04-0.22 day(-1)). This hypothesis is supported by measurements in the vertical access pit where, in winter, a turbulent air current produces a stable radon profile, smoothly decreasing from 700 Bq m(-3) at 20 m depth to 300 Bq m(-3) at surface. In summer, a thermal stratification is maintained in the pit, but the radon-222 concentration jumps repeatedly between 100 and 2000 Bq m(-3). These jumps are due to atmospheric pressure pumping, which induces ventilation in the quarry at a rate of about 0.1 x 10(-6) s(-1) (0.009 day(-1)). Radon-222 monitoring thus provides a dynamical characterisation of ventilation regimes, which is important for the assessment of the long-term evolution of underground systems. 相似文献
49.
Nitrate and endosulfan (alpha+beta) removal was studied in an upflow biological denitrification reactor packed with wheat straw as carbon source and support particles for microorganisms. While almost complete nitrate elimination and between 65% and 70% endosulfan (alpha+beta) elimination occurred when the temperature was higher than 20 degrees C; below that value, nitrate removal efficiency decreased to about 10%. Nitrate, dissolved organic carbon (DOC), and endosulfan (alpha+beta) removal efficiencies decreased considerably at 1500 microg/l endosulfan concentration in the batch experiments. Although a high removal efficiency was observed for endosulfan (alpha+beta) and nitrate in the biological denitrification continuous reactor, the effluent water could not be used for drinking purpose because of the unacceptable levels of endosulfan (alpha+beta), colour and dissolved organic content. During the continuous study, 23.4% of the initial weight of wheat straw was lost and 24 g was consumed per gram of nitrogen removed. The results of the continuous study showed that 21.3% of the endosulfan removal was achieved by adsorption onto the wheat straw and 68.2% of the endosulfan removal occurred by biological activity and the remaining portion was detected in the effluent water. 相似文献
50.
The levels of 1,1,1-trichloro-bis-2,2'-(4-chlorophenyl) ethane (p,p'-DDT) and its metabolites, hexachlorobenzene (HCB), hexachlorocyclohexane isomers (HCHs), chlordanes (trans- and cis-chlordane, oxychlordane and trans-nonachlor), 11 polychlorinated biphenyl (PCB) congeners, and 7 polybrominated diphenyl ether (PBDE) congeners were measured in 37 individual human milk samples from Kahramanmara? region, Turkey. Organochlorine pesticides were the major contaminants in the milk samples. p,p'-DDE and p,p'-DDT were detected in all samples, while beta-HCH had a detection frequency of 97%. The sum of the DDTs in human milk samples varied between 0.52 and 315.8 ng/g wet weight (ww) with a mean ratio between p,p'-DDE and p,p'-DDT equal to 31.1. p,p'-DDD could be measured only in six samples. beta-HCH was the most prevalent HCH isomer with a mean value of 2.08 ng/g ww. The mean concentration of gamma-HCH was 0.38 ng/g ww, while alpha-HCH was not detected in any sample. HCB is found in 95% of the milk samples with a mean concentration of 0.30 ng/g ww. The mean value for the sum of chlordanes was 0.39 ng/g ww, with oxychlordane and trans-nonachlor being the principal contributors. PCBs could be measured only in 8 out of 37 samples and their concentration ranged between <0.15 and 1.92 ng/g ww for the sum of PCBs. PCB profiles were dominated by congeners 153, 180 and 138. PBDEs were detected only in 3 out of 37 samples, with the highest value being 0.014 ng/g ww (0.40 ng/g lipid weight) and BDE 47 was the dominant congener. Although the number of samples is relatively low and they are not representative for the whole Turkish population, the results of the present study are important to provide additional data on the concentrations of persistent organochlorinated pollutants in Turkey and show as first the PBDE levels in Turkish population. 相似文献