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121.
122.
通过微波消解法、标准测试方法(SMT)和碱熔法分别测定了水系沉积物成分分析标准物质GBW07307a(GSD-7a)中的总磷(TP)含量,并分别采用3种方法对采集于黄河流域甘宁蒙段表层沉积物样品进行TP含量和样品加标回收率的测定。结果表明:测定标准物质的相对误差绝对值:微波消解法碱熔法SMT法;变异系数:微波消解法碱熔法SMT法。同时,微波消解法提取的表层沉积物TP含量的范围为634.3~909.2μg/g;SMT法TP含量的范围为627.1~889.5μg/g;碱熔法TP含量的范围为559.1~784.8μg/g。微波消解法的测定结果相对偏高,SMT法的测定结果相对偏低。样品加标回收率平均值:微波消解法SMT法碱熔法;变异系数:微波消解法碱熔法SMT法。综合测定标准物质中TP含量以及样品加标回收率实验结果的准确度和精密度,对于黄河甘宁蒙段表层沉积物,使用SMT法提取TP较优于微波消解法和碱熔法。 相似文献
123.
124.
Lan Q Cui K Zeng F Zhu F Liu H Chen H Ma Y Wen J Luan T Sun G Zeng Z 《Environmental monitoring and assessment》2012,184(8):4921-4929
Phthalate esters (PAEs) were examined in indoor and outdoor dust samples from the subtropical city of Guangzhou, China. The ∑(16)PAEs concentrations ranged from 121 to 3,223 μg g(-1) dust, with the median concentration of 840 μg g(-1) dust. Significantly higher concentrations of PAEs in dust samples were found in offices where electrical and electronic devices, carpet pads, and office furniture were widely used. Of the 16 PAEs, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), and di(2-ethylhexyl) phthalate (DEHP) dominated the PAEs in indoor and outdoor dust samples, and accounted for >96.8% and >93.1% of the ∑(16)PAEs concentrations, respectively. The median daily inhalation exposure of ∑(16)PAEs were 3.53 and 0.247 μg kg(-1) body weight day(-1), and at the 95(th) percentile were 7.62 and 0.530 μg kg(-1) body weight day(-1), up on the measured concentrations and estimated dust ingestion rates, respectively, for toddles and adults. The ubiquitous distribution of PAEs as noted in this study suggests the need for detailed assessment of PAEs concentrations using more sites and to further investigate the factors influencing PAEs exposure in China. 相似文献
125.
目的:探讨白杨素(Chrysin,5,7-二羟基黄酮,ChR)衍生物7-二氟亚甲基-5-烯丙基黄酮(7-difluorinmethylene-5-allyl flavone,DFMeAlChR)在体外抑制人乳腺癌细胞系MCF-7细胞生长和诱导细胞凋亡的作用及机制,以期获得高效、低毒的乳腺癌治疗新型候选药物.方法:应用软琼脂克隆形成法检测不同浓度的DFMeAlChR体外对人乳腺癌细胞系(MCF-7)细胞的锚定非依赖性增殖及生长作用的影响;采用WesternBlot分析不同浓度的DFMeAlChR对人乳腺癌细胞系(MCF-7)细胞蛋白激酶CK2,β-Catenin,NF-KB蛋白表达及活性的影响.结果:DFMeAlChR对体外培养MCF-7细胞具有抑制增殖及生长作用,呈剂量依赖性.Western Blot分析结果表明DFMeAlChR以时间-剂量依赖方式引起蛋白激酶CK2、β-Catenin、NF-KB下调,与先导化合物ChR比较,DFMeAlChR更为有效(P0.05).图3,参11. 相似文献
126.
奈芳 《中国个体防护装备》2009,(2)
本文简单概括和介绍了《缺氧危险作业安全规程》(GB8958-88)及香港《工厂及工业经营(密闭空间)规例》,并提出了密闭空间安全作业的一些方法和建议。 相似文献
127.
Rui Xu Peter E. Mortimer Rong Ping Kuang Jun He Wu Di Zhang Fang Yin 《Journal of environmental science and health. Part. B》2013,48(8):651-657
This study focuses on assessing the impact of sublethal doses of paraquat on the survival, the emergence, the life span and the parasitic behavior of Diaeretiella rapae M’Intosh (Hymenoptera: Braconidae). The impact of sublethal doses was measured at room temperature using different densities of the cabbage aphid Brevicoryne brassicae. The results reveal that the field dose of paraquat caused 100% mortality in D. rapae. The percentage emergence of D. rapae decreased from 80.5% in the control group to 71.5% when treated with the lowest concentration of paraquat. Similarly, the life span of parasitoids that emerged from the mummy treated with paraquat also decreased significantly. Oviposition capability and ovipositor thrusting frequency of D. rapae also treated with sublethal dose paraquat decreased significantly along with a shortened patch residence time in the foraging area. 相似文献
128.
Artificial neural network modeling of dissolved oxygen in the Heihe River, Northwestern China 总被引:2,自引:0,他引:2
Xiaohu Wen Jing Fang Meina Diao Chuanqi Zhang 《Environmental monitoring and assessment》2013,185(5):4361-4371
Identification and quantification of dissolved oxygen (DO) profiles of river is one of the primary concerns for water resources managers. In this research, an artificial neural network (ANN) was developed to simulate the DO concentrations in the Heihe River, Northwestern China. A three-layer back-propagation ANN was used with the Bayesian regularization training algorithm. The input variables of the neural network were pH, electrical conductivity, chloride (Cl?), calcium (Ca2+), total alkalinity, total hardness, nitrate nitrogen (NO3-N), and ammonical nitrogen (NH4-N). The ANN structure with 14 hidden neurons obtained the best selection. By making comparison between the results of the ANN model and the measured data on the basis of correlation coefficient (r) and root mean square error (RMSE), a good model-fitting DO values indicated the effectiveness of neural network model. It is found that the coefficient of correlation (r) values for the training, validation, and test sets were 0.9654, 0.9841, and 0.9680, respectively, and the respective values of RMSE for the training, validation, and test sets were 0.4272, 0.3667, and 0.4570, respectively. Sensitivity analysis was used to determine the influence of input variables on the dependent variable. The most effective inputs were determined as pH, NO3-N, NH4-N, and Ca2+. Cl? was found to be least effective variables on the proposed model. The identified ANN model can be used to simulate the water quality parameters. 相似文献
129.
Model simulations of dissolved oxygen characteristics of Minnesota lakes: Past and future 总被引:1,自引:0,他引:1
A deterministic, one-dimensional, unsteady numerical model has been developed, tested, and applied to simulate mean daily
dissolved oxygen (DO) characteristics in 27 lake classes in the state of Minnesota. Reaeration and photosynthesis are the
oxygen sources, while respiration, sedimentary, and biochemical water column oxygen demand are the sinks of oxygen in the
model. The lake classes are differentiated by surface area (A
s), maximum depth (H
max), and trophic status expressed as Secchi depth (Z
s). Because lake stratification is most important to lake oxygen dynamics, simulated DO characteristics are plotted in terms
of a stratification parameterA
s/H
max
0.25
and Secchi depthZ
s. Simulations provide DO profiles on a daily time scale. Specific DO characteristics of ecological and environmental interest
are epilimnetic DO, hypolimnetic DO, DO gradient from surface to bottom, and DO minima and maxima. Specific results are as
follows: Simulated mean daily and weekly DO values in the epilimnion of all lakes for both past and future climate scenarios
are near saturation over the summer season. Hypolimnetic DO values depend strongly on lake morphometry, trophic status, and
time throughout the summer season. Future climate conditions are specified as the historical records from 1955 to 1979, adjusted
(monthly) by the 2 × CO2 GISS model output to account for doubling of atmospheric CO2. With this climate change, weekly averaged epilimnetic DO is projected to drop by less than 2 mg/liter, and will remain above
7 mg/liter throughout the open water season. The hypolimnetic DO reductions after climate change are on the order of 2–8 mg/liter.
Periods of anoxia are longer by as much as 80 days. Those changes would alter water quality dynamics in lakes and have a profound
effect on lake ecosystems including indigenous fishes. The results presented are useful for evaluating environmental management
options. 相似文献
130.
五氯酚对环境污染及居民健康影响研究 总被引:2,自引:0,他引:2
中国长期以来使用五氯酚纳盐杀灭亡血吸虫的中间宿主──—钉螺.为评价它对环境的污染及居民健康危害,1990-1993年在我省开展了五氯酚环境污染及对居民健康影响研究.在研究区采集环境样品(空气、水体、土壤及底泥、蔬菜、肉、蛋、鱼等)共173份;生物材料(人血、尿)共457份,分析五氯酚浓度.结果在明,在五氯酚使用区,环境中PCP浓度稍高于对照区,而生物材料尿、血中PCP浓度明显高于对照区.全血胆碱脂酶活性用药区明显低于对照区,统计学分析有显著差异(P<0.001),证实了长期低剂量使用可造成环境及生物蓄积. 相似文献