A compilation of field surveys on gaseous elemental mercury (GEM) from contrasting environmental settings in Europe,South America,South Africa and China: separating fads from facts

Mercury is transported globally in the atmosphere mostly in gaseous elemental form (GEM, \( {\text{Hg}}_{\text{gas}}^{0} \) ), but still few worldwide studies taking into account different and contrasted environmental settings are available in a single publication. This work presents and discusses data from Argentina, Bolivia, Bosnia and Herzegovina, Brazil, Chile, China, Croatia, Finland, Italy, Russia, South Africa, Spain, Slovenia and Venezuela. We classified the information in four groups: (1) mining districts where this contaminant poses or has posed a risk for human populations and/or ecosystems; (2) cities, where the concentration of atmospheric mercury could be higher than normal due to the burning of fossil fuels and industrial activities; (3) areas with natural emissions from volcanoes; and (4) pristine areas where no anthropogenic influence was apparent. All the surveys were performed using portable LUMEX RA-915 series atomic absorption spectrometers. The results for cities fall within a low GEM concentration range that rarely exceeds 30 ng m^?3, that is, 6.6 times lower than the restrictive ATSDR threshold (200 ng m^?3) for chronic exposure to this pollutant. We also observed this behavior in the former mercury mining districts, where few data were above 200 ng m^?3. We noted that high concentrations of GEM are localized phenomena that fade away in short distances. However, this does not imply that they do not pose a risk for those working in close proximity to the source. This is the case of the artisanal gold miners that heat the Au–Hg amalgam to vaporize mercury. In this respect, while GEM can be truly regarded as a hazard, because of possible physical–chemical transformations into other species, it is only under these localized conditions, implying exposure to high GEM concentrations, which it becomes a direct risk for humans.     

Costa Rica — Assessing Climate Mitigation Pathways to Support NDC Implementation

Environmental Modeling & Assessment - Costa Rica has set a very ambitious Nationally Determined Contribution (NDC). Despite the low-carbon footprint of its power sector, the goal set in its NDC...     

Norovirus Contamination of Bell Pepper from Handling During Harvesting and Packing

To evaluate the impact of harvesting and packinghouse operation on the contamination of green bell pepper (GBP) with viruses and enteric bacteria. Hands of 97 workers plus 40 GBP were sampled from field and packinghouse areas. RT-nested PCR were used for the identification of Noroviruses (NV) and Chromogenic agar for the quantification of coliforms and Escherichia coli. NV was found in 30.9 and 23.7% of workers’ hands, before and after 3 h of work, respectively, while 45 and 30% of field and packed GBP was positive for NV. Fecal coliforms and Escherichia coli were present in 68 and 57.3% and 12.4 and 11.1% of workers’ hands before and after 3 h of work, respectively. Fecal coliforms were detected in 85 and 15% of field and packed GBP, respectively, while E. coli was absent. There was no significant correlation between bacterial indicator and NV in the analyzed samples (P > 0.05). Handling of fresh produce by workers during harvesting and packing operations has negative impacts on fresh produce safety.     

Soil carbon sequestration in a changing global environment

Throughout its long history the Earth has undergone warm periods with high atmospheric concentrations of greenhouse gases (GHG), and has responded with different buffering mechanisms whereby atmospheric C has been transferred to other geochemical compartments. Strategies for the mitigation and adaptation to the current climatic forcing may thus be generated by the acceleration of such natural mechanisms, especially those involved in short cycles, mainly in the biosphere and the pedosphere. Although these contain smaller C stocks than other compartments (< 0.01% of the total C), they circulate large amounts of C from the atmosphere through photosynthesis and mineral weathering (e.g., 120 Pg C are circulated through terrestrial ecosystems and total C in the atmospheric compartment is 805 Pg C). Increased C sequestration can thus be achieved in terrestrial ecosystems, by: (1) favouring growth of biomass; (2) promoting and facilitating carbonation processes; (3) reducing erosion and favouring pedogenesis; (4) developing organic matter-rich horizons; (5) recovering degraded or contaminated soils, and/or (6) managing waste by use of systems that minimize emissions of GHG. Within the latter option, the following actions are considered here in more detail: 1) production of Technosols, and 2) production of biochar. All of the above options should form part of a strategy for the mitigation and adaptation to global climate change. In this review, we analyze those focused on promoting soil conservation, soil restoration and soil formation.     

Reduction in ecological cost through biofuel production from cooking oils: An ecological solution for the city of Campinas, Brazil

The aim of the present study was to produce biodiesel from mixtures of cooking oil and provide a possible environmental solution for the region of Campinas (state of São Paulo, Brazil) based on the theory of environmental cost accounting (ECA). Cooking oil collected from homes in Campinas was mixed with ethanol at a ratio of 7:1 and transesterified at 60 °C for one hour for the obtainment of biodiesel using NaOH as a catalyst. The results of the physicochemical analyses demonstrated that the biodiesel possessed characteristics close to those required by Brazilian standards. A recent survey carried out in the city of Campinas revealed that residents are not concerned with the increased of environmental impact and ecological costs in the region caused by the disposal of used cooking oil, which is discarded in sewers and soil. Urgent action is recommended, beginning with raising awareness among the population and the implementation of a policy to determine the storage, periodic collection and use of cooking oil for the production of biodiesel. This fuel could be used for buses, trucks and machines or sold to fuel distributors, offering a savings of US$ 0.8 to 4.5 millions. Campinas could then gain environmental credits and become a sustainable city. Moreover, used cooking oil constitutes low-cost biodiesel with no consumption of raw materials and will reduce worldwide criticism directed at Brazil regarding the use of oleaginous plants for biodiesel production.     

Design of aquifer remediation systems: (1) describing hydraulic structure and NAPL architecture using tracers

Aquifer heterogeneity (structure) and NAPL distribution (architecture) are described based on tracer data. An inverse modelling approach that estimates the hydraulic structure and NAPL architecture based on a Lagrangian stochastic model where the hydraulic structure is described by one or more populations of lognormally distributed travel times and the NAPL architecture is selected from eight possible assumed distributions. Optimization of the model parameters for each tested realization is based on the minimization of the sum of the square residuals between the log of measured tracer data and model predictions for the same temporal observation. For a given NAPL architecture the error is reduced with each added population. Model selection was based on a fitness which penalized models for increasing complexity. The technique is demonstrated under a range of hydrologic and contaminant settings using data from three small field-scale tracer tests: the first implementation at an LNAPL site using a line-drive flow pattern, the second at a DNAPL site with an inverted five-spot flow pattern, and the third at the same DNAPL site using a vertical circulation flow pattern. The Lagrangian model was capable of accurately duplicating experimentally derived tracer breakthrough curves, with a correlation coefficient of 0.97 or better. Furthermore, the model estimate of the NAPL volume is similar to the estimates based on moment analysis of field data.     

Effects of different management strategies on long-term trends of Australian threatened and near-threatened mammals

Monitoring is critical to assess management effectiveness, but broadscale systematic assessments of monitoring to evaluate and improve recovery efforts are lacking. We compiled 1808 time series from 71 threatened and near-threatened terrestrial and volant mammal species and subspecies in Australia (48% of all threatened mammal taxa) to compare relative trends of populations subject to different management strategies. We adapted the Living Planet Index to develop the Threatened Species Index for Australian Mammals and track aggregate trends for all sampled threatened mammal populations and for small (<35 g), medium (35–5500 g), and large mammals (>5500 g) from 2000 to 2017. Unmanaged populations (42 taxa) declined by 63% on average; unmanaged small mammals exhibited the greatest declines (96%). Populations of 17 taxa in havens (islands and fenced areas that excluded or eliminated introduced red foxes [Vulpes vulpes] and domestic cats [Felis catus]) increased by 680%. Outside havens, populations undergoing sustained predator baiting initially declined by 75% but subsequently increased to 47% of their abundance in 2000. At sites where predators were not excluded or baited but other actions (e.g., fire management, introduced herbivore control) occurred, populations of small and medium mammals declined faster, but large mammals declined more slowly, than unmanaged populations. Only 13% of taxa had data for both unmanaged and managed populations; index comparisons for this subset showed that taxa with populations increasing inside havens declined outside havens but taxa with populations subject to predator baiting outside havens declined more slowly than populations with no management and then increased, whereas unmanaged populations continued to decline. More comprehensive and improved monitoring (particularly encompassing poorly represented management actions and taxonomic groups like bats and small mammals) is required to understand whether and where management has worked. Improved implementation of management for threats other than predation is critical to recover Australia's threatened mammals.     

Eutrophication trends in forest soils in Galicia (NW Spain) caused by the atmospheric deposition of nitrogen compounds

We calculated the sensitivity of Galician forest soils to eutrophication caused by atmospheric deposition of nitrogen compounds, using the Simple Mass Balance (SMB) method as described by [Posch, M., de Vries, W., Hettelingh, J.-P., 1995. Critical loads of sulphur and nitrogen. In: Posch, M., de Smet, P.A.M., Hettelingh, J.-P., Downing, R.J. Calculation and Mapping of Critical Thresholds in Europe. Status Report 1995, Coordination Center for Effects, National Institute for Public Health and the Environment, Bilthoven, The Netherlands, pp. 31-42]. Deposition values were used to calculate critical loads exceedance. Galician natural forest ecosystems can support nitrogen deposition loads of more than 10 kg Nha (-1) yr (-1). The lowest critical loads (approximately 10 kg Nha (-1) yr (-1)) mainly occurred in forest stands in the interior zone, while highest critical load values (approximately 68 kg Nha (-1) yr (-1)) were observed in eucalyptus stands at low altitudes in the littoral area. Exceedances based on N deposition levels, calculated from data recorded in 2001, occurred in 40% of the forest soils, showing the need to control N emissions in these areas to prevent possible eutrophication of soils and waters. Analysis of rainfall bulk composition revealed that ammonium, probably derived from agricultural and cattle activities, was the main compound responsible for N deposition in Galicia.     

Ketoprofen Loaded in Natural Rubber Latex Transdermal Patch for Tendinitis Treatment

Ketoprofen is an analgesic with potent anti-inflammatory activity against acute inflammation, subacute inflammation, for the acute and long-term treatment of various inflammatory pathologies, as rheumatoid arthritis and colonic adenocarcinoma. In order to minimize the incidence of systemic events related to ketoprofen, the transdermal drug delivery system development has been most important. The advantages of using natural rubber latex membranes include not only the reduction of adverse systemic events, but also the suitability of the low cost of the material together with its physicochemical properties such as flexibility, mechanical stability, surface porosity and water vapor permeability, and besides being a biocompatible material also presents biological activity to stimulate the angiogenesis, being able to be used in tissue repair. This study demonstrated that ketoprofen was successfully incorporated into natural latex membranes for drug delivery. FTIR indicated that the drug did not interact chemically with the membrane. Moreover, the natural latex membranes released 60% of the ketoprofen incorporated in 50 h. SEM images indicated that a portion of the drug was present on the membrane surface, being this portion responsible for the burst release. The tensile tests showed that the addition of the drug into the natural latex membrane did not influence on the polymer mechanical behavior. In addition, drug-natural latex membranes presented no red blood cell damaging effects. Our data shows that the ketoprofen loaded natural latex membranes is a promising system for sustained drug delivery which can be used to minimize the adverse side effects of high dose systemic drug delivery.