Combined Non-Catalytic Reduction of NOx and SO2 by Ammonia Liquor during Staged Fluidized-Bed Combustion

Emissions of NOx and SO2 were monitored in the presence of ammonia liquor in a 0.09 m2 and 2 m high stainless-steel fluidized-bed combustor. Experiments were carried out at 2 m/s fluidizing velocity, 40% excess air, and 870 °C bed temperature. Ammonia liquor with 7% ammonia by weight was injected into the freeboard of the combustor 52 cm above the distributor through a water-cooled injector. A 65 : 34 primary/secondary air ratio was maintained throughout the investigation. Approximately 70% of NO and 20% of SO2 was reduced at an NH3/NO molar ratio of 2 : 1, respectively. However, a higher reduction in SO2 emissions (62%) was achieved at a very high NH3/NO molar ratio of 7 : 1. These experiments showed that ammonia addition did have a significant effect in SO2 reduction if injected in an excess amount. The injection of ammonia liquor combined with staged combustion was found to be very effective in reducing NOx emissions. A reduction of about 50% was achieved at an NH3/NO molar ratio of 0.6 : 1 which is also coupled with a very low level of ammonia in the flue.     

Interactive effects of nitrogen deposition and fire on plant and soil chemistry in an alpine heathland

The response of alpine heathland vegetation and soil chemistry to N additions of 0, 10, 20 and 50 kg N ha⁻¹ year⁻¹ in combination with simulated accidental fire (+/−) was monitored over a 5-year period. N addition caused rapid and significant increases in plant tissue N content and N:P and N:K of Calluna vulgaris, suggesting increasing phosphorus and potassium limitation of growth. Soil C:N declined significantly with N addition, indicating N saturation and increasing likelihood of N leakage. Fire further decreased soil C:N and reduced potential for sequestration of additional N. This study shows that alpine heathlands, which occupy the headwaters of many rivers, have limited potential to retain deposited N and may rapidly become N saturated, leaking N into downstream communities and surface waters.     

Experimental and modeling study of the effect of CO and H2 on the urea DeNO(x) process in a 150kW laboratory reactor

An experimental and modeling investigation has been performed to study the effect of process additives, H2 and CO on NO(x) removal from flue gases by a selective non-catalytic reduction process using urea as a reducing agent. Experiments were performed with a flow reactor in which flue gas was generated by the combustion of propane in air at 3% excess oxygen and the desired levels of initial NO(x) (500ppm) were achieved by doping the flame with ammonia. Experiments were performed throughout the temperature range of interest, i.e. from 850 to 1200 degrees C for investigation of the effects of the process additives on the performance of aqueous urea DeNO(x). Subsequently, computational kinetic modeling with SENKIN code was performed to analyze the performance of urea providing a direct comparison of modeling prediction with experimental measurements. With CO addition, a downwards shift of 215 degrees C in the peak reduction temperature from 1125 to 910 degrees C was observed during the experimentation while the kinetic modeling suggests it to be 150 degrees C, i.e. from 1020 to 870 degrees C. The addition of H2 impairs the peak NO(x) reduction but suggests a low temperature application of the process. A downward shift of 250 degrees C in the peak reduction temperature, from 1020 to 770 degrees C, was observed during kinetic modeling studies. The kinetic modeling shows a good qualitative agreement with the experimental observations and reveals additional information about the process.     

Towards a sustainable economy? Socio-technical transitions in the green building sector

Making the transition to a green economy is a major policy driver in the UK and other countries. Entrepreneurs are suggested as being at the forefront of this transition and as a driving force for sustainability. These “green entrepreneurs” may represent a new type of entrepreneurial behaviour combining economic, environmental and social aims. In this paper, we present empirical work conducted with green entrepreneurs in the UK green building sector. Buildings have significant impacts on the environment, both in terms of materials and post-construction energy demands. Drawing on sustainability transitions theory, we examine the role of green entrepreneurs in affecting change and suggest that green building niches are less consensual than previously theorised. In theorising green entrepreneurs, we also point to the need to consider them within wider networks of activity rather than as lone actors and the implications this has for policy.     

Metals of the bottom muds in Townsville Harbor, Australia

Samples of Townsville Harbor bottom mud were acid leached (0.3 m HCl) to measure bioavailability of Cd, Co, Cu, Fe, Mn, Ni, Pb, Sn and Zn. Three of seven samples showed enrichment factors relative to average soil of 25-30 for Cd, 5-71 for Cu, 21-81 for Pb, and 13-37 for Zn. The other four samples were only high in Cd, Pb, and Zn by an enrichment factor of 2-7. Considering that this harbor is in the middle of the environmentally sensitive Great Barrier Reef area, the disposal of the dredged harbor muds poses a special problem.     

On course for a sustainable future? European environmental policy and local economic development

Local authorities are increasingly faced with demands and pressures to become much more responsive to environmental issues. International agreements and national legislation all put an emphasis on the local level as the most appropriate scale for action and on local authorities as the most appropriate bodies to take such action. One area of local authority competence where environmental issues have made a limited impact to date is in economic development. Yet the concept of sustainable development which forms the basis of national and European legislation and policy necessitates the integration of economic development with the environment. In this paper the main features of European policy with regard to the environment are outlined and the implications for European funding of local authority economic development strategies are examined.     

BENTHIC INVERTEBRATE RESPONSE TO POLLUTION ABATEMENT: STRUCTURAL CHANGES AND FUNCTIONAL IMPLICATIONS1

We examined changes in certain structural and functional aspects of the benthic invertebrate community in the Penobscot River, Maine, between 1974 and 1981. During this period, two pulp and paper manufacturers and three municipalities spent an estimated $33 million to reduce point source effluents harmful to aquatic life. We developed a biotic index based on objectively derived pollution tolerance values for resident taxa. Analysis of the benthic invertebrate community indicated that substantial improvement in water quality had resulted from pollution abatement. We established a four-group water quality classification scheme based on biotic index ranges, and showed that every site that was not in the best water quality classification in 1974 improved its classification to a better water quality group in 1981, and that the sites in the best group did not change. Relative abundances of functional feeding groups also changed, as were predicted by the river continuum theory. The effluents had acted as a “reset mechanism” that shifted polluted areas from autotrophic to more heterotrophic conditions. The direction of the shift was reversed in response to abatement efforts. Functional analyses of energy dynamics could lead to a more ecologically sound classification of water quality.     

Experimental assessment of ecological and phenotypic factors affecting male mating success and polyandry in northern watersnakes, Nerodia sipedon

To resolve conflicting field observations regarding the action of sexual selection, we used breeding experiments and paternity analysis of the 927 resulting offspring to assess how male size, condition, tail length, genetic similarity to the female, and variation in operational sex ratio (OSR) affected male reproductive success and the incidence of polyandry in northern watersnakes (Nerodia sipedon). Only size affected male mating success. Large males were more successful, but only when male size varied substantially and competition among males was intense (i.e., male-biased OSR). The conditional nature of the size advantage may explain why studies of free-living watersnakes have produced inconsistent results regarding the relationship between male size and mating success. Size differences between males did not affect the proportion of offspring each male sired within multiply sired litters. We found positive size-assortative mating, but only when the OSR was female biased, suggesting that smaller males had improved access to females when competition among males was reduced, but that competition with larger males still restricted mating opportunities of small males to less preferred, smaller females. Most litters (58%) were multiply sired and larger females were more likely to produce multiply sired litters, similar to free-living watersnakes. There was no association between the incidence of multiple paternity and OSR, however, suggesting that polyandry is not simply a function of opportunity, with females passively waiting for males to court them.     

Book reviews

Toward Sustainable Communities: resources for citizens and their governments. Mark Roseland with Maureen Cureton & Heather Wornell, 1998, Gabriola Island, New Society Publishers, ISBN 0 86571 374 X, $18.95

First Mover Advantage by Eco-efficiency: local incentives for environment and employment.. C. Erdmunger & S. Schreckenberger, 1998, Freiburg, ICLEI, DM30

Agendas for Sustainability: environment and development into the twenty-first century. Mary Macdonald, 1998, London, Routledge, ISBN 0 415 15491X, £55.00 (hbk)

Women, Population and Global Crisis: a political-economic analysis. Asoka Bandarage, 1997, London, Zed Books, ISBN 1 85649 428 4, £15.95 (pbk)

Spirit of the Environment: religion, value, and environmental concern. David Cooper & Joy Palmer (Eds), 1998, London, Routledge, ISBN 0 4151 4202 4, £12.99 (pbk)

Environmental Transition in Nordic and Baltic Countries. Hans Aage (Ed.), 1998, (New Horizons in Environmental Economics). Cheltenham, UK and Northampton, MA, USA, Edward Elgar, ISBN 1 85898 629 X

Sustainability Indicators: measuring the immeasurable. Simon Bell & Stephen Morse, 1999, London, Earthscan Publications, 175 pp. ISBN 1 85383 498 X, LE14.95 (pbk)

The Economics of Road Transport Regulation. Erik Verhoef, Cheltenham, Edward Elgar 1996, 265 pp. ISBN 1 85898 364 9, £55.00

The Water Crisis. Julie Stauffer, London, Earthscan, 1998, ISBN 185383 436X, £12.95 (pbk)