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991.
以日光灯和金属卤化物灯为主要光源,以Fe(Ⅲ)/丙酮酸钠体系光化学过程中产生的Fe(Ⅱ)和·OH为主要检测对象,探讨了Fe(Ⅲ)/丙酮酸钠体系光解过程中生成的Fe(Ⅱ)和·OH的浓度变化.结果表明,Fe(Ⅲ)/丙酮酸钠体系的光解过程不仅能产生Fe(Ⅱ)和·OH;在丙酮酸钠过量的情况下,光解过程还存在着Fe(Ⅲ)/Fe (Ⅱ)的循环;Fe(Ⅱ)浓度和·OH累积浓度均在pH 3.00时最大;体系的光化学过程中会伴随pH的升高;初始Fe(Ⅲ)浓度和初始丙酮酸钠浓度的提高都有利于Fe(Ⅱ)浓度和·OH累积浓度的提高. 相似文献
992.
Jinping Zhang Bingtuo Guo Zhihong Ding 《Environmental monitoring and assessment》2013,185(10):8749-8757
The empirical mode decomposition method is applied to analyze fluctuating periods and local features of the annual drought index and the drought index in the irrigation and non-irrigation periods from 1956 to 2010 in the Yinchuan irrigation district. In order to understand the uncertainty between these variables, the set pair analysis method is used to present the identity, discrepancy, and contrary of the drought index with multi-time scales. The results reveal that the annual drought index and the drought index in the irrigation and non-irrigation periods have a complex relationship which may be related to El Niño, the air–sea intersection, and the long period of solar activity. The drought index in the irrigation and non-irrigation periods presents mainly the contrary and the discrepancy; the fluctuating shapes of the annual drought index and drought index in the irrigation period are the same on their different period levels. The original annual drought index and its intrinsic mode function components have a certain connection degree; they mainly present the discrepancy. 相似文献
993.
Dahai Yan Qiong Ding Kåre Helge Karstensen Christian J. Engelsen Li Li 《Journal of the Air & Waste Management Association (1995)》2013,63(8):1002-1010
The aim of this study was to evaluate the behavior of Hg, As, and Se in cement production. Two types of cement plants were studied, including the vertical shaft kiln (VSK) and preheater–precalciner kiln (PPK) processes. Determination of Hg, As, and Se in the main material and gas streams were performed. It was found that recycling of particulate matter captured by an air pollution control device caused a significant enrichment of Hg and As inside both processes. The total quantity of Hg entering the process and the quantity emitted to the atmosphere were found to be 10–109 and 6.3–38 mg, respectively, per ton of clinker produced. The average Hg emission was calculated to be around 41% of the total mercury input. The emissions found complied with the European Union (EU) limit and exceeded partly the U.S. limit. Furthermore, it was found that oxidized mercury was the dominant species in the PPK process, whereas the reduced form was dominant in the VSK process, due to the oxidizing and reducing gas conditions, respectively. Regarding the distribution of As and Se, the major amounts were bound to the solid materials, that is, cement clinker and particulate matter. Based on cement production data in China in 2013, the annual emissions of Hg and As were estimated to be in the range of 8.6–52 and 4.1–9.5 tons, respectively.Implications: There are fairly limited studies on Hg, As, and Se measurements from cement manufacturing facilities in China, and even more limited studies on the behavior in vertical shaft kilns. The needs for increased emission reduction efforts in energy-intensive industries are globally recognized, and an improved understanding of the processes ongoing in a cement kilns system is decisive. Since the processes are complex and almost impossible to recreate in the laboratory, field measurements are indeed important. The findings in the present study were solely based on field measurements and the data are considered to be valuable for the further development of emission reduction technology. 相似文献
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采用革取、分离工艺从生产聚醚多元醇(PPG)的滤渣中回收PPG 和KH2PO4.实验结果表明:用于生产聚氨酯(PU)泡沫包装块和高回弹泡沫制品的PPG 的滤渣适宜采用该工艺回收;本实验最佳工艺条件为KH2 PO4结晶母液与滤渣质量比为2.0,革取温度80 ~ 90 C,革取时间60 ~ 90 min,静置温度80 ~ ... 相似文献
996.
石化企业环境管理体系能源管理探讨 总被引:1,自引:0,他引:1
分析了石化企业环境管理体系运行中的能源管理现状,结合环境管理体系与能源管理体系关系,依托能源管理体系的思路和方法,对环境管理体系中的能源管理进行了探讨. 相似文献
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Lead and cadmium uptake was investigated for common deciduous street trees in Beijing in this study. Species having Cd accumulation included Populus tomentosa, Sophora japonica and Catalpa speciosa. P. tomentosa had the highest ratios between leaf and soil Cd (0.848), followed by S. japonica (0.536), C. speciosa (0.493), Paulownia tomentosa (0.453) and Juglans regia (0.415). Pb levels were high in leaves of C. speciosa, J. regia and Pa. tomentosa. S. japonica had the highest ratio between leaf Pb and soil Pb (0.146), followed by Pa. tomentosa (0.143), Ginko biloba (0.103) and C. speciosa (0.095). A predictive foliar metal accumulation index (MAI) was developed and C. speciosa was calculated to have the highest MAI value (53.8). This suggests that C. speciosa would be a good choice for planting in areas of Beijing where soil contamination with Cd and Pb may be a problem. 相似文献
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