Environmental performance and spillover effects on productivity: evidence from horticultural firms

This study investigates the effect of environmental investment and related spillover effects on productivity in the agricultural sector by using a panel data of horticultural firms in Andalusia (Southern Spain). The results indicate a positive relationship between firm investment in environmental practices and productivity improvement, also showing the presence of positive environmental spillovers. In a second-stage of analysis, the incidence of environmental factors in firm specific individual technical efficiency is estimated. This analysis also shows the link between environmental knowledge diffusion and horticultural firms' performance.     

Potential application of highly reactive Fe(0)/Fe3O4 composites for the reduction of Cr(VI) environmental contaminants

We describe the use of highly reactive Fe(0)/Fe3O4 composites for the reduction of Cr(VI) species in aqueous medium. The composites were prepared by simple mechanical alloying of metallic iron and magnetite in different proportions, i.e. Fe(0) 25, 50, 75 and 90wt%. While after 3h of reaction pure Fe(0) and pure Fe3O4 showed only a low reduction efficiency of 15% and 25% Cr(VI) conversion, respectively, the composites, in particular Fe(0)(25wt%)/Fe3O4, showed a remarkable activity with ca. 65% Cr(VI) conversion. Kinetic experiments showed a high reaction rate during the first 3h, which subsequently decreased strongly, probably due to a pH increase from 6 to 8. Experiments with composites based on Fe(0)/alpha-Fe2O3, Fe(0)/gamma-Fe2O3 and Fe(0)/FeOOH showed very low activities, suggesting that Fe(oct)2+ in the magnetite structure plays an important role in the reaction. Scanning and high resolution electron microscopies and M?ssbauer spectra (transmission and conversion electron M?ssbauer spectroscopy) indicated that the mechanical alloying process promotes a strong interaction and interface between the metallic and oxide phases, with the Fe(0) particles completely covered by Fe3O4 particles. The high efficiency of the composite Fe(0)/Fe3O4 for Cr(VI) reduction is discussed in terms of a special mechanism where an electron is transferred from Fe(0) to magnetite to reduce Fe(oct)3+ to Fe(oct)2+, which is active for Cr(VI) reduction.     

Farm-level assessment of CO2 and N2O emissions in Lower Saxony and comparison of implementation potentials for mitigation measures in Germany and England

Greenhouse gases (GHG) emissions from agricultural farming practice contribute significantly to European GHG inventories. For example, CO₂ is emitted when grassland is converted to cropland or when peatlands are drained and cultivated. N₂O emissions result from fertilization. Enabling farmers to reduce their GHG emissions requires sufficient information about its pressure–impact relations as well as incentives, such as regulations and funding, that support climate-friendly agricultural management. This paper discusses potentials to improve the supply of information on: farm-specific climate services or impacts, present policy incentives in Germany and England that support climate-friendly farm management and related adaptation requirements. Tools which have been developed for a farm environmental management software (to be added after review because of potential identification) are presented. These tools assess CO₂ emissions from grassland conversion to cropland and peatland cultivation, as well as N₂O emissions from nitrogen fertilization. As input data, the CO₂ tool requires a classification of soil types according to soil organic carbon storage. The input data based on soil profile samples was compared with reference data from the literature. The N₂O tool relies on farm data concerning fertilization. These tools were tested on three farms in order to determine their viability with respect to the availability of required data and the differentiation of results, which determines how well site-specific conservation measures can be identified. Assessing CO₂ retention function of grassland conservation to cropland on the test farms leads to spatially differentiated results (~100 to ~900 potentially mitigated t CO₂ ha^?1). Assessed N₂O emissions varied from 0.41 to 1.1 t CO₂eq. ha^?1 a^?1. The proposed methods support policies that promote a more differentiated funding of climate conservation measures. Conservation measures and areas can be selected so that they will have the greatest mitigation effects. However, even though present policy instruments in Germany and England, such as Cross Compliance and agri-environmental measures, have the potential to reduce agricultural GHG, they do not appear to guide measures effectively or site-specifically. In order to close this gap, agri-environmental measures with the potential to support climate protection should be spatially optimized. Additionally, the wetland restoration measures which are most effective in reducing GHG emissions should be included in funding schemes.     

Geodiversity Assessment of Paraná State (Brazil): An Innovative Approach

Geodiversity is considered as the natural range of geological, geomorphological, and soil features, including their assemblages, relationships, properties, interpretations, and systems. A method developed for the quantitative assessment of geodiversity was applied to Paraná, a Brazilian state with an area of about 200,000 km². The method is based on the overlay of a grid over different maps at scales ranging from 1/500,000 to 1/650,000, with the final Geodiversity Index the sum of five partial indexes calculated on a 25 × 25 km grid. The partial indexes represent the main components of geodiversity, including geology (stratigraphy and lithology), geomorphology, paleontology, and soils. The fifth partial index covers mineral occurrences of geodiversity, such precious stones and metals, energy and industrial minerals, mineral waters, and springs. The Geodiversity Index takes the form of an isoline map that can be used as a tool in land-use planning, particularly in identifying priority areas for conservation, management, and use of natural resources at the state level.     

On the environmental,economic and safety optimization of distributed treatment systems for industrial effluents discharged to watersheds

This paper presents a general mathematical programming model for the synthesis of distributed treatment systems for industrial effluents discharged to watersheds. In addition to addressing the economic and environmental concerns of the design, the paper introduces safety as an additional objective. A multi-objective optimization formulation is developed to simultaneously address and reconcile the various objectives. Material flow analysis (MFA) is used to track the flows and concentrations throughout the watershed system while accounting for the different sources (industrial, sanitary, agricultural, precipitation, etc.), extractions (agricultural, filtration, evaporation, etc.), and physical, biological, and chemical phenomena occurring within the watershed. Additionally, the formulation allows the installation of treatment systems for the industrial effluents. The economic, environmental, and safety aspects of these treatment units are incorporated. A case study with different scenarios for the Balsas watershed in Mexico is considered to show the applicability of the proposed approach.     

A new practical approach to risk management for underground mining project in Quebec

The mining industry worldwide is currently experiencing an economic boom that is contributing to economic recovery and social progress in many countries. For this to continue, the mining industry must meet several challenges associated with the start-up of new projects. In a highly complex and uncertain environment, rigorous management of risks remains indispensable in order to repel threats to the success of mining.In this article, a new practical approach to risk management in mining projects is presented. This approach is based on a novel concept called “hazard concentration” and on the multi-criteria analysis method known as the Analytic Hierarchy Process (AHP). The aim of the study is to extend the use of this approach to goldmines throughout Quebec. The work is part of a larger research project of which the aim is to propose a method suitable for managing practically all risks inherent in mining projects.This study shows the importance of taking occupational health and safety (OHS) into account in all operational activities of the mine. All project risks identified by the team can be evaluated. An adaptable database cataloguing about 250 potential hazards in an underground goldmine was constructed. In spite of limitations, the results obtained in this study are potentially applicable throughout the Quebec mining sector.     

Surface orange patinas on the limestone of the Batalha Monastery (Portugal): characterization and decay patterns

Environmental Science and Pollution Research - Samples of orange patinas found on a limestone window tracery and an ornament of the Batalha Monastery have been investigated by X-ray...     

Characterization of black crusts developed on historic stones with diverse mineralogy under different air quality environments

Environmental Science and Pollution Research - Black crusts (BCs) are one of the most critical alteration forms found on stones belonging to architectural heritage. Since they could be considered...     

Challenges of TiO2 heterogeneous photocatalysis on cytostatic compounds degradation: state of the art

Environmental Science and Pollution Research - The following work provides a perspective on the degradation of cytostatic pollutants through TiO2 heterogeneous photocatalysis. Cytostatic drugs are...     

Ecotoxicity of binary mixtures of ILs and inorganic salts of electrochemical interest

Environmental Science and Pollution Research - The applicability of ionic liquids (ILs) has increased over the last years, and even new opportunities are becoming a reality, i.e. mixtures of pure...