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排序方式: 共有302条查询结果,搜索用时 281 毫秒
81.
Blanca M. Dominguez-Martinez Hector E. Martínez-Flores Jose De J. Berrios Caio G. Otoni Delilah F. Wood Gonzalo Velazquez 《Journal of Polymers and the Environment》2017,25(3):683-691
This study aimed to develop and characterize biodegradable films containing mucilage, chitosan and polyvinyl alcohol (PVA) in different concentrations. The films were prepared by casting on glass plates using glycerol as plasticizer. Mechanical properties, water vapor and oxygen barrier, as well as the interaction with water, were measured. The compatibility of the film-forming components and the uniformity of the films were determined by zeta potential and SEM, respectively. The glycerol and mucilage allowed obtaining more hydrophilic films. The barrier properties of the films made from 100 % chitosan were similar to composed films containing PVA up to 40 %. The results of this study suggest that the interaction between chitosan and mucilage could increase water vapor permeability. The films prepared from either 100 % chitosan or PVA showed a more hydrophobic behavior as compared to the composed films. The films were homogenous since no boundary or separation of components was observed, indicating a good compatibility of the components in the films. 相似文献
82.
Gredilla Ainara Fdez-Ortiz de Vallejuelo Silvia Gomez-Nubla Leticia Carrero Jose Antonio de Leão Felipe B. Madariaga Juan Manuel Silva Luis F. O. 《Environmental science and pollution research international》2017,24(31):24333-24345
Environmental Science and Pollution Research - In city playgrounds, there is a potential risk of harming children’s health by contamination coming from anthropogenic activities. With the aim... 相似文献
83.
Stefan Gelcich Camila Vargas Maria Jose Carreras Juan Carlos Castilla C. Josh Donlan 《Ambio》2017,46(2):184-189
Biodiversity offsets are becoming increasingly common across a portfolio of settings: national policy, voluntary programs, international lending, and corporate business structures. Given the diversity of ecological, political, and socio-economic systems where offsets may be applied, place-based information is likely to be most useful in designing and implementing offset programs, along with guiding principles that assure best practice. We reviewed the research on biodiversity offsets to explore gaps and needs. While the peer-reviewed literature on offsets is growing rapidly, it is heavily dominated by ecological theory, wetland ecosystems, and U.S.-based research. Given that majority of offset policies and programs are occurring in middle- and low-income countries, the research gaps we identified present a number of risks. They also present an opportunity to create regionally based learning platforms focused on pilot projects and institutional capacity building. Scientific research should diversify, both topically and geographically, in order to support the successful design, implementation, and monitoring of biodiversity offset programs. 相似文献
84.
Gema Pliego Patricia Garcia-Muñoz Juan A. Zazo Jose A. Casas J.J. Rodriguez 《Environmental science and pollution research international》2016,23(23):23449-23455
The effect of irradiation with visible light-emitting diode (LED) light on the efficiency of Fenton oxidation is investigated using phenol as the target compound (100 mg/L). The H2O2 dose and temperature are tested as operating variables with the aim of minimizing consumption of the reagents. At 50 °C, 10 mg/L Fe2+, and 60 % of the stoichiometric H2O2 amount, phenol was completely oxidized into CO2, H2O, and short chain organic acids, with oxalic acid completely degraded. Up to 95 % mineralization was achieved. This high efficiency can be attributed to the effect of LED radiation on the quinones/Fe2+/Fe3+/H2O2 cycle, which significantly increases the reaction rate, as well as on the photodecomposition of the iron complexes formed along the oxidation process, which also enhanced mineralization. 相似文献
85.
Jose A. Manzanilla-Cano Manuel H. Barcelo-Quintal Tania I. Coral-Martinez 《Journal of environmental science and health. Part. B》2013,48(7):546-552
Photochemical degradation of methylparathion (O,O,-dimethyl O-4 nitrophenylphosphorothioate) in the presence of humic acid between pH 2 and 7 was monitored by differential pulse polarography. Humic acid was not electro-active under the experimental conditions used in this study. Only the pesticide and its main degradation product at pH 2 exhibited polarographic signals. Photolysis of methylparathion in acid media was sensitized by humic acid since the pesticide did not degrade in the absence of this compound. Methylparathion degradation in the presence of humic acid was observed at each of the studied pHs. The reaction was first-order with rate constant values ranging from 2 × 10?3 to 6.3 × 10?3 min?1. 相似文献
86.
Ana de Santiago-Martín Inmaculada Valverde-Asenjo Jose R. Quintana Antonio Vázquez Antonio L. Lafuente Concepción González-Huecas 《Environmental science and pollution research international》2013,20(9):6392-6405
A set of periurban calcareous agricultural Mediterranean soils was spiked with a mixture of Cd, Cu, Pb and Zn at two levels within the limit values proposed by current European legislation, incubated for up to 12 months, and subjected to various one-step extraction procedures to estimate mobile (neutral salts) and potentially mobile metal fractions (complexing and acidic extraction methods). The results obtained were used to study metal extractability patterns according to the soil characteristics. The analytical data were coupled with mineralogical investigations and speciation modelling using the Visual Minteq model. The formation of soluble metal-complexes in the complexing extracts (predicted by the Visual Minteq calculations) led to the highest extraction efficiency with complexing extractants. Metal extractability patterns were related to both content and composition of carbonate, organic matter, Fe oxide and clay fractions. Potentially mobile metal fractions were mainly affected by the finest soil fractions (recalcitrant organic matter, active lime and clay minerals). In the case of Pb, scarce correlations between extractable Pb and soil constituents were obtained which was attributed to high Pb retention due to the formation of 4PbCO3·3PbO (corroborated by X-ray diffraction). In summary, the high metal proportion extracted with complexing agents highlighted the high but finite capacity to store potentially mobilizable metals and the possible vulnerability of these soils against environmental impact from metal accumulation. 相似文献
87.
Céline Dupont Francesca Romana Grati Kwong Wai Choy Sylvie Jaillard Jérôme Toutain Marie-Laure Maurin Jose Antonio Martínez-Conejero Claire Beneteau Aurélie Coussement Denise Molina-Gomes Nina Horelli-Kuitunen Azzedine Aboura Anne-Claude Tabet Justine Besseau-Ayasse Bettina Bessieres-Grattagliano Giuseppe Simoni Gustavo Ayala Brigitte Benzacken François Vialard 《黑龙江环境通报》2015,35(1):35-43
88.
Gomez-Eyles JL Collins CD Hodson ME 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):918-923
Validating chemical methods to predict bioavailable fractions of polycyclic aromatic hydrocarbons (PAHs) by comparison with accumulation bioassays is problematic. Concentrations accumulated in soil organisms not only depend on the bioavailable fraction but also on contaminant properties. A historically contaminated soil was freshly spiked with deuterated PAHs (dPAHs). dPAHs have a similar fate to their respective undeuterated analogues, so chemical methods that give good indications of bioavailability should extract the fresh more readily available dPAHs and historic more recalcitrant PAHs in similar proportions to those in which they are accumulated in the tissues of test organisms. Cyclodextrin and butanol extractions predicted the bioavailable fraction for earthworms (Eisenia fetida) and plants (Lolium multiflorum) better than the exhaustive extraction. The PAHs accumulated by earthworms had a larger dPAH:PAH ratio than that predicted by chemical methods. The isotope ratio method described here provides an effective way of evaluating other chemical methods to predict bioavailability. 相似文献
89.
90.
Air-vegetation transfer of PCDD/PCDFs: an assessment of field data and implications for modeling 总被引:1,自引:0,他引:1
Schuhmacher M Jones KC Domingo JL 《Environmental pollution (Barking, Essex : 1987)》2006,142(1):143-150
This study was designed to evaluate soil and air (gas and particle) transfer of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) to vegetation in residential and industrial areas. In a first part, soil-vegetation transfer was assessed. The levels of PCDD/Fs in 120 soil and 120 herbage samples collected from 1996 to 2002 in an industrial area of Montcada (Barcelona, Spain), near a municipal solid waste incinerator (MSWI), were determined. Some additional individual samples were also evaluated. It was concluded that high soil concentrations, which are not at steady state with the air layer above it, show a tendency for PCDD/Fs to escape via volatilization. In a second part of the study, air-vegetation transfer was examined. PCDD/F concentrations from 24 herbage samples were used, while PCDD/F concentrations were also measured in seven high-volume air samples and seven passive air-vapor samples. Scavenging coefficients (m3 air "sampled"/g grass d.m.) ranged from 1.9 to 11.3 m3/g. A good trend with K(OA) was observed for PCDDs (R=0.82), while it was lower for PCDFs (R=0.55). The current results corroborate that PCDD/F concentrations in vegetation are associated with atmospheric deposition. For the highest substituted PCDD/F congeners, the air-particle uptake from plants is the principal pathway. In regions impacted by combustion emission sources, PCDD/F gas-particle partitioning is influenced by a higher concentration of particles in the air. Particles and associated particle-bound PCDD/Fs would sorb to leaf surfaces, and are subject to removal via wash off. However, in areas where emissions to air are not very notable, vapor absorption would be the principal source of vegetation pollution. The results of this investigation can have a potential interest in risk assessment studies and environmental fate models. 相似文献