Study on the optical property and surface morphology of N doped TiO2 film deposited with different N2 flow rates by DCPMS

N doped TiO₂ films were deposited by direct current pulse magnetron sputtering system at room temperature. By using UV-Vis spectrophotometer and atomic force microscope, we studied the influence of N₂ flow rate on the optical property and surface morphology of films. The results indicate that the optical property and surface morphology of N doped TiO₂ film was dominated by the N₂ flow rate. The mean absorbency in visible range of pure TiO₂ films is near to 0%, which means that the pure TiO₂ could hardly display the photocatalytic property in visible range. When N₂ flow rate is 2 sccm, the mean absorbency in visible range of N doped TiO₂ film could reach at 24%. In this case, the film could be used as photocatalyst induced by visible light. While with increasing N₂ flow rate, the mean absorbency in visible range of N doped TiO₂ film decreased abruptly. Especially when N₂ flow rate exceeded 8 sccm, the mean absorbency in visible range of N doped TiO₂ film decreased to about 0%, which is like pure TiO₂ fimls.     

Preparation of MgO/B2O3 coatings by plasma spraying on SUS304 surface and effects of heat-resistant

This study mainly deals with the preparation of MgO/B₂O₃ coatings by plasma spraying on the SUS304 surface and the effects of heat-resistant. The power materials of low thermal conductivity were selected to control the heat divergent performance of high temperature parts. The reticular micro-structure between the cover thermal layer and the substrate was prepared by using the plasma spraying method. The powder mixture of MgO and B₂O₃ were selected as spraying materials and the SUS304 was used as the substrate material. The MgO/B₂O₃ coating was prepared on the surface of the SUS304 to provide better cover thermal performance. The properties of the microstructures and the morphologies were studied by Optical Microscope, Scanning Electron Microscope, Electron Probe Microanalyzer, and X-ray Diffraction. The results showed that the cover thermal performance has been improved.     

Evaluation of leaching characteristic and kinetic study of lithium from lithium aluminum silicate glass-ceramics by NaOH

The behavior and mechanism of Li leaching from lithium aluminum silicate glass-ceramics which can be used as a secondary source of Li using aqueous NaOH solution was investigated. The Li leaching efficiency is increased with increasing concentration of NaOH, specific surface area, and reaction temperature. When leached under optimum conditions, 2 mol/L NaOH, 53 μm particle undersize, 1:10 solid/liquid ratio, 250 r/min stirring speed, 100°C reaction temperature, 12 hr, the Li leaching efficiency was approximately 70%. However, when the leaching experiment was performed for 48 hr, the concentration of Li⁺ ions contained in the leach liquor decreased from 1160 to 236 mg/L. To investigate the origin of this phenomenon, the obtained leach residue was analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. These analyses show that zeolite was formed around the lithium aluminum silicate glass-ceramics, which affected the leaching of by adsorbing Li⁺ ions. In addition, using the shrinking-core model and the Arrhenius equation, the leaching reaction with NaOH was found to depends on the chemical reaction of the two reactants, with a higher than 41.84 kJ/mol of the activation energy.     

锦州市2015年二氧化硫新增量预测

根据《“十二五”主要污染物总量控制规划编制技术指南》提供的公式,预测社会经济发展主要参数,包括GDP、能源消费总量、煤炭消费量等指标。二氧化硫新增量预测以宏观测算方法为主,并按行业测算方法予以校核。宏观测算分为火电行业和非电力行业,结果为1.419万t;分行业预测分为石化、建材（水泥）、有色、冶金和其他行业,结果为1.774万t,两者预测偏差为25%,采用分行业预测结果作为2015年二氧化硫新增量预测。     

石油类污染物对土壤、地下水环境影响模拟分析

某油田利用千化池蒸发处理联合站排放的含油污水,部分干化池存在轻微渗漏,下渗的污水会对地下水产生污染。为掌握污染物在地下水中的迁移转化规律,建立含油废水的一维竖向迁移模型,并利用Hydrus-1D计算程序对地下水中污染物浓度随时间、运移距离衰减的情况进行模拟分析。分析结果对于控制干化池含油废水中石油类污染物对地下水环境的污染具有一定的参考价值。     

我国电力工业的发展前景与展望

介绍了我国电力工业的发展现状，着重分析了电力工业发展中存在的诸多问题。从可持续发展的角度出发，我国电力工业在严格控制火力发电的同时，应该重点发展火力发电，适度发展核电技术，重视可再生能源的开发利用以及大力发展发布式能源冷热电联产技术。     

致突变的致癌剂和非致癌剂在引发DNA股间交联上的显著差别

借碱洗脱法证明：具有致突变能力的致癌剂1，2－二溴乙烷和肼在经过代谢活化后，均剂理相关地引起L1210细胞中DNA的股间交联。相反，动物致癌试验表现阴性的突变剂溴乙烷，以及通过各种致癌动物试验均显示阴性的传统常用致突变剂羟胺，在代谢活化以后的同样条件下均不能引起L1210细胞中DNA的股间交联。这证明了双区理论的致癌观点，即致癌剂必须是双官能烷化剂，其同时引起互补碱对的交联将引起癌变。相反，股内单一碱基的变异则可能引起致突变作用。并用APCI／SIM（大气压化学电离／选择离子质谱）证明：1，2－二溴乙烷与DNA碱基对的模型反应，与致突实验一致主要引起G－C对的交联和发生G－C→A－T突变。     

Solid recovery rate of food waste recycling in South Korea

Source-separated collection system of household food waste has been implemented national wide in South Korea. Food waste recycling rate that means conversion rate to recycle is over 90 % in present. However, over the value of 90 %, we need to enhance the efficiency of food waste recycling process. We analyzed material flow of 24 food waste recycling facilities and calculated solid recovery rate to key-process. We found that 3–13 % of the solids from food waste outflows with foreign materials and 27–33 % of the solids outflow with wastewater. As a result, solid recovery rates are 65.3, 60.9, and 56.3 % in wet feed facility, dry feed facility, and composting facility, respectively. Alternative ways to recovery solid from wastewater or collection tools to exclude plastic bags, salt, and moisture content are required to make food waste recycling more efficient.     

Identification of Enteric Viruses in Foods from Mexico City

Foodborne viruses are a common and, probably, the most under-recognized cause of outbreaks of gastroenteritis. Among the main foods involved in the transmission of human enteric viruses are mollusks, and fruits and vegetables irrigated with wastewater and/or washed with non-potable water or contaminated by contact with surfaces or hands of the infected personnel during its preparation. In this study, 134 food samples were analyzed for the detection of Norovirus, Rotavirus, and Hepatitis A virus (HAV) by amplification of conserved regions of these viruses. From the 134 analyzed samples, 14 were positive for HAV, 6 for Norovirus, and 11 for Rotavirus. This is the first report in Mexico where emphasis is given to the presence of HAV and Norovirus on perishable foods and food from fisheries, as well as Rotavirus on frozen vegetables, confirming the role of vegetables and bivalve mollusks as transmitting vehicles of enteric viruses.     

Synthesis of surface sulfated BiWO with enhanced photocatalytic performance

Sulfated BiWO (SBiWO) was synthesized by an impregnation method to enhance the visible-light-driven photoactivities of BiWO (BiWO). The characterization results verified that sulfate anion mainly anchored on the catalyst surface greatly extended the visible-light-responsive range without destroying the crystal lattice. Moreover, the SBiWO-based photoactivities were evaluated with the removal of Malachite Green (MG) under UV-Vis irradiation emitted from two microwave-powered electrodeless discharge lamps (MPEDL_-2) and under visible light (λ > 420 nm). The results demonstrated that the kinetic constant was increased 2.25 times, varying from 0.1478 (BiWO) to 0.3328 min^-1 (SBiWO-1). Similar results were also obtained for the visible light-driven reaction. Furthermore, radical scavengers such as t-butanol restricted the visible-light induced degradation of MG over BiWO and SBiWO-1. This indicated that the sulfating process increased the generation of reactive oxygen species, which was further verified by molecular probe with salicylic acid. Thus, more blue-shifting at λ = 618 nm was observed over SBiWO. On the basis of the above results, the photocatalytic mechanism over the sulfated catalyst was also discussed.