Observed chemical characteristics of long-range transported particles at a marine background site in Korea

Deokjeok Island is located off the west coast of the Korean Peninsula and is a suitable place to monitor the long-range transport of air pollutants from the Asian continent. In addition to pollutants, Asian dust particles are also transported to the island during long-range transport events. Episodic transport of dust and secondary particles was observed during intensive measurements in the spring (March 31-April 11) and fall (October 13-26) of 2009. In this study, the chemical characteristics of long-range-transported particles were investigated based on highly time-resolved ionic measurements with a particle-into-liquid system coupled with an online ion chromatograph (PILS-IC) that simultaneously measures concentrations of cations (Li+, Na , NH4+, K+, Ca2+, Mg2+) and anions (F-, C1-, NO3-, SO42-). The aerosol optical thickness (AOT) distribution retrieved by the modified Bremen Aerosol Retrieval (M-BAER) algorithm from moderate resolution imaging spectroradiometer (MODIS) satellite data confirmed the presence of a thick aerosol plume coming from the Asian continent towards the Korean peninsula. Seven distinctive events involving the long-range transport (LRT) of aerosols were identified and studied, the chemical components of which were strongly related to sector sources. Enrichment of acidic secondary aerosols on mineral dust particles, and even of sea-salt components, during transport was observed in this study. Backward trajectory, chemical analyses, and satellite aerosol retrievals identified two distinct events: a distinctively high [Ca2++Mg2]/[Na+] ratio (>2.0), which was indicative of a preprocessed mineral dust transport event, and a low [Ca2++Mg2+]/[Na+] ratio (<2.0), which was indicative of severe aging of sea-salt components on the processed dust particles. Particulate C1- was depleted by up to 85% in spring and 50% in the fall. A consistent fraction of carbonate replacement (FCR) averaged 0.53 in spring and 0.55 in the fall. Supporting evidences of C1- enrichment on the marine boundary layer prior to a dust front were also found. Supplemental materials are available for this article. Go to the publisher's online edition of the Journal of the Air & Waste Management Association for sector and air mass classifications of clean and LRT cases.     

Occurrence of perfluorooctanoate and perfluorooctanesulfonate in the Korean water system: implication to water intake exposure

Perfluorinated compounds (PFCs) measured in surface running waters indicated the existence of different emission sources in eight main city basins. The tap water reflected the contamination pattern and levels in their corresponding source water basins. The daily intakes through tap water consumption ranged from <0.01 to 0.73 ng kg⁻¹ d⁻¹ for perfluorooctanoate (PFOA) and <0.01 to 0.08 ng kg⁻¹ d⁻¹ for perfluorooctanesulfonate (PFOS). Tap water intake-derived exposure accounted for 8.6%-101% (for PFOA) and while <10% (for PFOS) of total daily exposure, which was estimated from Korean serum concentrations using a pharmacokinetic model. Our findings indicate that tap water intake could be an important contributor to PFOA exposure in Korean populations; accordingly, additional efforts are necessary to improve the removal efficiency of perfluorinated compounds (PFCs) in the water purification process. However, more fundamentally the aim would be to reduce the discharge of PFCs from potential sources within the basin.     

Environmental impact minimization of a total wastewater treatment network system from a life cycle perspective

Synthesis of distributed wastewater treatment plants (WTPs) has focused on cost reduction, but never on the reduction of environmental impacts. A mathematical optimization model was developed in this study to synthesize existing distributed and terminal WTPs into an environmentally friendly total wastewater treatment network system (TWTNS) from a life cycle perspective. Life cycle assessment (LCA) was performed to evaluate the environmental impacts of principal contributors in a TWTNS. The LCA results were integrated into the objective function of the model. The mass balances were formulated from the superstructure model, and the constraints were formulated to reflect real wastewater treatment situations in industrial plants. A case study validated the model and demonstrated the effect of the objective function on the configuration and environmental performance of a TWTNS. This model can be used to minimize environmental impacts of a TWTNS in retrofitting existing WTPs in line with cleaner production and sustainable development.     

Exploring insideness in urban children’s sense of place

This study, informed by phenomenology and ethnography, explores urban children’s relationship with their urban environment: In what ways do urban children exhibit “insideness” in their sense of place? This study proposes “insideness” as a conceptual construct to understand urban children’s sense of place in its ecological and dynamic nature. Employing qualitative research methods, the study explores place stories of urban children who live in low-income, immigrant neighborhoods in New York City. The study finds that as children cultivate their sense of place, they construct “insideness” in their sense of place including 1) environmental understanding (i.e., contextualized, comprehensive, and critical understanding of a place), 2) environmental competence (i.e., knowing how to navigate and engage in a place), and 3) diverse, strong affective relationships with a place. Using “insideness” as a conceptual tool, this study discusses children’s emplaced understanding and active and dialogical positionality in the development of their sense of place.     

Effects of anions on the kinetics and reactivity of nanoscale Pd/Fe in trichlorobenzene dechlorination

Influences of anionic co-solutes on dechlorination of 1,2,4-trichlorobenzene (124TCB) by the nanoscale Pd/Fe particles were investigated in batch experiments in the presence of an anionic solute such as nitrate, nitrite, perchlorate, phosphate, carbonate, silica, sulfate, sulfite, or sulfide. Based on the extent of inhibitory effects on the 124TCB dechlorination, the anions can be ranked in the order of: control≈sulfate≈silica相似文献