载体制备方法对贵金属催化剂Ru/ZrO2催化湿式氧化性能的影响

蒸煮处理水合氢氧化锆制备了ZrO2-A;将水合氢氧化锆静置过夜制得ZrO2-B;以此两种载体通过初湿浸渍法制得Ru/ZrO2催化剂.在BET测试中,ZrO2-A载体及其相应催化剂的比表面积远高于ZrO2-B载体及相应催化剂.TPR表明Ru/ZrO2-A中Ru的分散性更好,金属与载体的相互作用更为紧密.以苯酚和乙酸水溶液为模拟废水进行催化剂的评价,结果表明,Ru/ZrO2-A无论是在反应活性还是稳定性上均优于Ru/ZrO2-B.     

A NEW METHOD FOR ESTIMATING FUTURE RESERVOIR STORAGE CAPACITIES1

ABSTRACT: A new method has been developed for estimating future reservoir storage capacities, allowing for sediment deposition and compaction. Reservoir sedimentation surveys for 117 reservoirs, conducted by the Illinois State Water Survey over the past 60 years, were used to determine regional constants K to represent the severity of sediment deposition in the reservoirs. More than half of the 82 water supply reservoirs investigated had records of reservoir sedimentation surveys, and their K values were calculated by using data from those sediment surveys. The average K values of the remaining non-surveyed water supply reservoirs were estimated from the regional distribution of the K values. Other important factors considered in the estimation of future reservoir storage capacities are the trap efficiency of the reservoirs and the variation of density of sediment deposits due to compaction. The model can also be used for analyzing the economics of alternative sites and of design features that can be incorporated in dams for reducing reservoir sedimentation.     

The Effects of Long-Term Grazing Exclosures on Range Plants in the Central Anatolian Region of Turkey

Over the last fifty years, almost half of the steppe rangeland in the Central Anatolian Region of Turkey (CAR) has been converted to cropland without an equivalent reduction in grazing animals. This shift has led to heavy grazing pressure on rangeland vegetation. A study was initiated in June 2003 using 6 multiscale Modified-Whittaker plots to determine differences in plant composition between areas that have not been grazed in 27 years with neighboring grazed plant communities. A total of 113 plant species were identified in the study area with the ungrazed plots containing 32 plants more than the grazed plots. The major species were Astragalus acicularis, Bromus tomentellus, Festuca valesiaca, Genista albida, Globularia orientalis, Poa bulbosa, and Thymus spyleus ssp rosulans. Grazing impacts on forbs were more pronounced than for grasses and shrubs. Based on Jaccard’s index, there was only a 37% similarity of plant species between the two treatments. Our study led to four generalizations about the current grazing regime and long-term exclosures in the steppe rangeland around the study area: (1) exclosures will increase species richness, (2) heavy grazing may have removed some plant species, (3) complete protection from grazing for a prolonged period of time after a long history of grazing disturbance may not lead to an increase in desirable plant species with a concomitant improvement in range condition, and (4) research needs to be conducted to determine how these rangelands can be improved.     

Electrocoagulation of some reactive dyes: a statistical investigation of some electrochemical variables

In this study, the decolorization of strong colored solutions containing the reactive textile dyes by electrocoagulation was investigated. The experiments were statistically designed and carried out according to a 2(4) full factorial design with two replicate and four center points. This design was extended with eight additional axial points. Then, the non-linear regression was applied on the data by using MINITAB software. The variables chosen for this work are mixing rate, cell voltage, electrolysis time and current density. Results showed that the effective variables on decolorization process are cell voltage, electrolysis time and current density. In addition, to determine the effect of dye and electrode type on decolorization, the additional experiments were carried out. It was determined the dye and electrode type are important on the decolorization process.     

膨润土中气溶胶泄漏行为研究

气溶胶泄漏问题是各种放射性实验过程和放射性物质储存、运输过程中普遍存在的问题 ,膨润土和砂则是常用的高放处置回填材料。工作中建立了层剖取样、微波浸提、ICP AES分析的气溶胶泄漏研究方法 ,来评估膨润土和砂对气溶胶的封堵性能。结果表明 :膨润土层的透过率远小于砂层。此外 ,对膨润土和砂 ,透过率与其气体渗透系数有一定的正相关性。     

收口工艺反向模拟技术研究

综述了国内外反向模拟技术 ,介绍了收口工艺特点 ,建立了收口反向模拟技术的理论和系统流程 ,并针对收口工艺提出了反向模拟边界条件确定方法。