Presence and partitioning properties of the flame retardants pentabromotoluene, pentabromoethylbenzene and hexabromobenzene near suspected source zones in Norway

The brominated flame retardants (BFRs), pentabromotoluene (PBT), pentabromoethylbenzene (PBEB) and hexabromobenzene (HBB), exhibit physical-chemical properties similar to other persistent organic pollutants, and have been in use as flame retardants for several decades. Data on these BFRs in diverse environmental samples can be found in studies from the 1970s and 1980s, as well as in recent years, though very little in the years in between. Due to a lack of data, the cause for the apparent re-emergence of these BFRs in recent studies is unclear, and could reflect changes in production volumes, accumulation of transformation products from BFR precursors, improved analytical techniques or simply a re-emergence in concern. Very little data are available on their environmentally relevant partitioning properties, which could help to explain the occurrence and fate of these BFRs. In this study we analysed for the presence of HBB, PBT, and PBEB in diverse environmental samples from potential Norwegian BFR source zones. Additionally, environmental partitioning properties of these BFRs as well as brominated benzenes were estimated and validated using experimental data for brominated benzenes. Of the three BFRs, HBB was identified in detectable quantities at most source zones, PBEB only near a metal recycling factory, and PBT only in a few additional locations from where PBEB was detected. Data from this study show that HBB is likely widely distributed, as verified both by chemical analysis and estimated properties. Measured HBB levels in wastewater treatment plants indicate that the treatment practices used in the study locations are not effective at lowering HBB levels, perhaps due to association with low density suspended solids (e.g. microplastics).     

Consequences of changed wetness on riverine nitrogen – human impact on retention vs. natural climatic variability

The HBV-N model was used for a scenario analysis of changes in nitrogen retention and transport caused by alterations of wetness due to land drainage, lowering of lakes, building of dams and climatic variability in a river basin in south-central Sweden (1885–1994). In general, dams were situated in locations more favourable for retention, compared to the lowered lakes. Rather modest conversions of water bodies only changed nitrogen transport by about 3%. The 180-times-larger increase of (mainly) tile-drained agricultural land had, according to simulations, increased the nitrogen transport by 17%, due to reduced retention. However, compared to human-induced alteration of the landscape N retention, the choice of 10-year periods of climatological data had the overriding effect on the calculated nitrogen transport. Weather-induced variations resulted in a 13% difference in nitrogen retention between various 10-year periods. When the model was driven by climatological data from the driest 10-year period (1905–1914), the estimated average annual load was only half of that obtained with climatological data from the wettest 10-year period (1975–1984). Electronic Publication     

Sampling and analysis of particulate and gaseous polycyclic aromatic hydrocarbons from coal tar sources in the working environment

A sampling method for polycyclic aromatic hydrocarbons (PAH) in workplace atmospheres using a standard glass fiber filter with a back-up section of Amberlite XAD-2 is described. Filters and XAD are solvent-desorbed and, without further clean-up, the solutions are submitted to high performance liquid chromatographic analysis using fluorimetric detection. Recovery of PAH from XAD-2 was studied, and was found to be in the range 80–100%. The sampling method was evaluated in a coke plant, an aluminium plant and in a creosote impregnating plant. The method described is rapid and sensitive for the determination of the most important workplace PAH, and accounts for both particulate and gaseous PAH.     

The internal barriers of rotation for the 209 polychlorinated biphenyls

The internal barrier of rotation (Erot) was calculated for all 209 polychlorinated biphenyls (PCBs) by using a semi-empirical method, viz. the Austin Model 1 (AMI) Hamiltonian. The difference in total energy between a forced planar state and an optimised twisted structure was defined as Erot. The Erot values were in the range of 8.33 to 483 kj/mol, and were significantly influenced by the number of chlorine atoms inortho position. An additional structural characteristic of the PCBs influencing Erot ofortho substituted congeners was substitution by chlorine atoms in vicinalmeta positions, which is assumed to prevent outward bending ofortho substituents. This so-called buttressing effect contributed with 4 to 31 kj/mol per added chlorine atom. In conclusion, the internal barrier of rotation, calculated for all 209 PCBs, provides an important structure dependent physico-chemical parameter for multivariate modelling of future quantitative structure-activity and structure-property relationships (QSARs/QSPRs).