A Method for Response Time Measurement of Electrosensitive Protective Devices

A great step toward the improvement of safety at work was made when electrosensitive protective devices (ESPDs) were applied to the protection of press and robot-assisted manufacturing system operators. The way the device is mounted is crucial. The parameters of ESPD mounting that ensure safe distance from the controlled dangerous zone are response time, sensitivity, and the dimensions of the detection zone. The proposed experimental procedure of response time measurement is realized in two steps, with a test piece penetrating the detection zone twice. In the first step, low-speed penetration (at a speed v^m) enables the detection zone border to be localized. In the second step of measurement, the probe is injected at a high speed V^d. The actuator rod position is measured and when it is equal to the value L registered by the earlier measurements, counting time begins as well as the monitoring of the state of the equipment under test (EUT) output relays. After the state changes, time tp is registered. The experimental procedure is realized on a special experimental stand. Because the stand has been constructed for certification purposes, the design satisfies the requirements imposed by Polski Komitet Normalizacyjny (PKN, 1995). The experimental results prove the measurement error to be smaller than ± 0.6 ms.     

Distribution of volatile organohalogen compounds in petrochemical plant water streams

The study assesses halogenated volatile organic compound concentrations in the water and wastewater streams of a petrochemical plant. Water samples were collected at 11 sampling points during 5 sampling campaigns. The samples were collected from the oil dewaxing unit and in the wastewater treatment plant. Dichloromethane and 1,2-dichloroethane were the most frequently determined compounds. Tetrachloroethene was also detected at the wastewater treatment plant inlets. The concentrations of halogenated volatile organic compounds dropped significantly at wastewater discharge points compared to wastewater treatment plant inlets. The application of 1,2-dichloroethane/dichloromethane ratio as a tool to assess evaporation processes is discussed.     

Strategic planning for sustainable tourism development in Poland

The aim of this article is to evaluate selected tourism development strategies in Poland, in the context of strategic planning, stakeholders’ participation, and sustainable development principles. A questionnaire evaluation of strategy (44 questions) was established and based on measurement scales developed and validated by other authors in earlier studies. The five authors of the study rated 37 tourism development strategies in 13 provinces, 11 cities, 5 counties, 6 municipalities, and 2 other areas. Analysis revealed that they implement paradigms of sustainable development of tourism to only a small extent. Definitely higher quality is documented for higher levels of administrative division. The highest rated domains of the tourism development strategy in the examined documents are Strategic Planning Indicators and Implementation, Monitoring, and Evaluation.     

Studies of the effect of simulated acid rain on the ecological equilibrium of the soil system

Introduction to the problem of environmental pollution caused by acid depositions. Presentation of principles of the six-year field experiment with simulated acid rain. Short characteristics of particular parts of the series of papers.     

Variations of arsenic species content in edible Boletus badius growing at polluted sites over four years

The content of arsenic (As) in mushrooms can vary depending on the concentration level of this metalloid in the soil/substrate. The present study evaluated the content of arsenic in Boletus badius fruiting bodies collected from polluted and non-polluted sites in relation to the content of this element in overgrown substrate. It was found that mushrooms from the arsenic-polluted sites contained mean concentrations from 49 to 450 mg As kg^?1 dry matter (d.m.), with the greatest content found for specimens growing in close proximity of sludge deposits (490±20 mg As kg^?1d.m.). The mean content of total arsenic in mushrooms from clean sites ranged from 0.03 to 0.37 mg kg^?1 It was found that B. badius could tolerate arsenic in soil substrate at concentrations of up to 2500 mg kg^?1, at least. In different years of investigation, shifts in particular arsenic forms, as well as a general increase in the accumulation of organic arsenic content, were observed. The results of this study clearly indicate that B. badius should not be collected for culinary purposes from any sites that may be affected by pollution.     

Simultaneous gas chromatographic determination of chlorpyrifos and its impurity sulfotep in liquid pesticide formulations

An analytical method for simultaneous determination of the active substance (chlorpyrifos) and its relevant impurity (sulfotep) in commercial pesticide formulations has been developed and validated. The proposed method entails extraction of the analytes from samples by sonication with acetone and analysis by gas chromatography-flame ionization detection (GC-FID). The proposed method was characterized by satisfactory accuracy and precision. The repeatability expressed as relative standard deviation (RSD) was lower than the acceptable values calculated from the modified Horwitz equation whereas individual recoveries were in the range of 98–102% and 80–120% for chlorpyrifos and sulfotep, respectively. The limit of quantification (LOQ) for the impurity (sulfotep) was 0.003 mg mL^?1 corresponding to the maximum permitted level according to Food and Agricultural Organization of the United Nations (FAO) specifications for the active substance (chlorpyrifos) being 3 g kg^?1 of the chlorpyrifos content found. The main advantage of the proposed method was a considerable reduction in the analysis time since both analytes were determined based on a single injection into the GC-FID. Analysis of real samples of commercial pesticide formulations confirmed fitness-for-purpose of the proposed method.