Chemical degradation of chlorophenols with Fenton's reagent (Fe + H2O2)

Aqueous solutions of Fenton's reagent (Fe²⁺ + H₂O₂) have been used to effect the total decomposition of the chlorophenols: 2-chlorophenol, 3-chlorophenol, 4-chlorophenol, 3,4-dichlorophenol and 2,4,5-trichlorophenol. The mineralization of these chlorinated aromatic substrates to CO₂ and free Cl⁻ has been studied as a function of [Fe²⁺] and [HClO₄]. Increasing the concentration of Fe²⁺ enhances the decomposition process, while an increase in the concentration of HClO₄, inhibits the reaction. The presence of Fe³⁺ alone (without any Fe²⁺) with H₂O₂ has no effect on the degradation of the chlorophenols. In all cases, the stoichiometric quantity of free Cl⁻ was obtained at the completion of the decomposition reaction; but the rates of disappaearance of the chlorophenol and of the formation of the Cl⁻ are not similar. This suggests that some chlorinated aliphatic species may be formed as possible intemediates.     

Bayesian Ecological Regression with Latent Factors: Atmospheric Pollutants Emissions and Mortality for Lung Cancer

In this work we propose a Bayesian ecological analysis in which a latent variable summarizes data on emissions of atmospheric pollutants. We specified a hierarchical Bayesian model with spatially structured and unstructured random terms with a nested latent factor model. This can be considered a combination of the convolution spatial model of Besag et al. (1991) and an ecological regression analysis in which a latent variable plays the role of the covariate. The unified approach allows to proper account for the uncertainty in the latent score estimation in the regression analysis. The Bayesian Latent Factor model is used to summarize the information on environmental pressure derived from three stressors: Carbon Monoxide, Nitrogen Oxides and Inhalable Particles. We found evidence of positive correlation between Lung cancer mortality and environmental pressure indicators, in males, Tuscany (Italy), 1995–1999. Environmental pressure seems to be restricted to fourteen municipalities (top 5% of the Latent Factor distribution). The model identified two areas with high point source emissions.     

A new practical aid to regional hydrogeologic planning: The runoff coefficient map

The principal aim of this research is to solve problems of water-budget estimation in particularly indeterminate conditions, of the kind that are frequently encountered in the field, in which absence or insufficiency of hydrographic instrumentation prevents the adequate evaluation of runoff.To do this we have developed techniques that are based on the method of Kennessey (1930), in which the runoff coefficient of a watershed in estimated using three physiographic variables (slope angle, permeability, and vegetation cover) and a parameter that defines the climatic conditions of the local area. Our comparison of the Kennessey method with instrumental records from a wide variety of instrumented drainage basins in central Italy shows that the method provides reliable estimates of runoff. Our analysis also indicates the best criteria for its application, as shown by the examples and results presented in this article.This research enables us to present a new application of the method, namely the runoff coefficient map, which, in addition to its specific usefulness for the evaluation of runoff, has three advantages. First, it supplies a more realistic vision of the local distribution of runoff/rainfall ratios; second, it allows one to overcome the spatial constraints imposed by the narrow frame of reference represented by the watershed; and third, it makes an important contribution to the solution of other hydrogeological problems, such as the evaluation of the amount of water required for adequate recharge of the intake areas of deep aquifers or the maintenance of geothermal processes.Hence we propose this mapping technique as a valuable practical aid to regional hydrogeologic planning.     

PM<Subscript>10</Subscript> source apportionment in the surroundings of the San Vicente del Raspeig cement plant complex in southeastern Spain

Introduction  

The concentrations of trace metals, ionic species, and carbonaceous components in PM₁₀ (particulate matter with aerodynamic diameters smaller than 10 μm) were measured from samples collected near an industrial complex, primarily composed of cement plants, in southeastern Spain, from September 2005 to August 2006.     

Enrichment of organic pollutants in the sea surface microlayer (SML) at Terra Nova Bay, Antarctica: influence of SML on superficial snow composition

Concentrations of dissolved and particle-associated n-alkanes, phthalates and polycyclic aromatic hydrocarbons (PAHs) were measured in sea surface microlayer (SML) and sub-surface water (SSL) samples collected in the coastal area of Terra Nova Bay, Antarctica, during the Austral spring 1998/1999. SML concentrations of the selected organic compounds were higher than SSL values and the enrichment factors were greater in the particulate phase than in the dissolved phase. During the same campaign, "fresh" snow samples, collected at different altitudes (from sea level up to 2670 m) near the coast on Mt Melbourne, immediately after a snowy event, were analysed in order to provide more information on air/sea exchange processes. The same classes of organic compounds found in sea water were also present in "fresh" snow samples. The surfactant fluorescent organic matter (SFOM), adsorbed on the microdrop aerosol surface, could be considered the main constituent of the enrichment and the carrier at higher altitudes of organic compounds. In fact, hydrocarbons (n-alkanes and PAHs), which are not surfactants like phthalates, could interact with SFOM and follow the same fate.     

Methanesulphonic acid (MSA) stratigraphy from a Talos Dome ice core as a tool in depicting sea ice changes and southern atmospheric circulation over the previous 140 years

Firn core methanesulphonic acid (MSA) stratigraphy from Talos Dome (East Antarctica) was compared with anomalies of the satellite-measured sea ice extent (1973–1995) in the Ross Sea and Wilkes Land oceanic sector. In spite of the sparseness of sea ice data, the MSA maxima fit with many positive sea ice anomalies in the Ross Sea. This evidence suggests that marine biogenic activity enhanced by large sea ice cover is an important, but not exclusive, factor in controlling MSA concentration in snow precipitation at Talos Dome. Other than source intensity, differences in regional atmospheric transport mechanisms affect the arrival of MSA-rich aerosol at Talos Dome. To clarify the role of transport processes in bringing biogenic aerosol to Talos Dome, a spectral analysis was applied to the MSA, SOI (South Oscillation Index), and SAM (Southern Annular Mode) record. Synchronicity or phase shift between the chemical signature and atmospheric circulation modes were tested. The variations in the MSA profile have a periodicity of 6.9, 4.9, 3.5, and 2.9 years. The 6.9 and 2.9 year periodicities show a strong positive correlation and are synchronous with corresponding SOI periodicity. This variability could be related to an increase in MSA source intensity (by dimethylsulphide from phytoplanktonic activity) linked to the sea ice extent in the Ross Sea area, but also to an increased strength in transport processes. Both of these factors are correlated with La Niña events (SOI positive values). Furthermore, SAM positive values are related to an increased sea ice extent in the Ross Sea sector and show two main periodicities 3.3 and 3.8 years. These periodicities determine the MSA variability at 3.5 years. However, the effect of intensification of the polar vortex and the consequent reduction in transport process intensity, which reduce the delivery of air masses enriched in MSA from oceanic areas to Talos Dome, make the effect of the SAM on the MSA concentration at Talos Dome less active than the SOI. In this way, snow deposition at the Talos Dome records larger MSA concentration by the combined effects of increased source emissions and more efficient transport processes. The MSA record from Talos Dome can therefore be considered a reliable proxy of sea ice extent when the effect of changes in transport processes in this region of Antarctica is considered. Over the previous 140 years, these conditions occur with a periodicity of 6.9 years.     

Maternal metabolomic profiling and congenital heart disease risk in offspring: A systematic review of observational studies

Aetiological understanding and screening methods for congenital heart disease (CHD) are limited. Maternal metabolomic assessment offers the potential to identify risk factors and biomarkers. We performed a systematic review (PROSPERO CRD42022308452) investigating the association between fetal/childhood CHD and endogenous maternal metabolites. Ovid-MEDLINE, Ovid-EMBASE and Cochrane Library were searched between inception and 06/09/2022. Case control studies included analysing maternal blood or urine metabolites in pregnancy or postpartum where there was foetal/childhood CHD. Risk of bias assessment utilised the Scottish Intercollegiate Guidelines Network methodology checklist and narrative synthesis was performed. A total of 134 records were screened with eight eligible studies (n = 3242 pregnancies, n = 842 CHD-affected offspring). Five studies performed metabolomic analysis in pregnancy. Metabolites distinguishing case and control groups spanned lipid, glucose and amino-acid pathways, with the development of sensitive risk prediction models. No single metabolite consistently distinguished cases and controls across studies. Three studies performed targeted analysis postnatally with altered lipid and amino acid metabolites and raised homocysteine and markers of oxidative stress identified in cases. Included studies reported small sample sizes, analysing different biosamples at variable time points using differing techniques. At present, there is not enough evidence to confidently associate maternal metabolomic profiles with offspring CHD risk. However, several identified pathways warrant further investigation.     

Biochemical composition and trophic strategies of the amphipod Eurythenes gryllus at hadal depths (Atacama Trench,South Pacific)

Amphipods Eurythenes gryllus were collected at 7800?m depth in the Atacama Trench (South Pacific) for studying their biochemical composition (in terms of proteins, lipids and carbohydrates and fatty acid content) and to gather information on bioenergetic strategies and trophic habits of organisms living in this extreme environment. The effect of long-term formalin storage on the biochemical determinations was also determined. Proteins were the dominant biochemical class of organic compounds (39–53%D.W.), whereas carbohydrates accounted for a very small fraction (1–2%D.W.). Lipid concentrations of E. gryllus accounted for 7–18%D.W. and were much lower than those reported for other deep-sea amphipods. These differences are likely to be more dependent upon food availability in the Atacama Trench rather than upon temperature. Lipid composition of E. gryllus revealed the dominance of monounsaturated fatty acids with polyunsaturated fatty acids accounting for a very small fraction, suggesting that hadal amphipods are higher dependent upon lipid reserves than amphipods inhabiting at shallow depths. The ratio of C18:1Δ⁹ to C18:1Δ¹¹ was >11 confirming the necrophagous trophic habits of this hadal amphipod.