Microbial Removal of Arsenic

Bangladesh is currently the subject of the world's largest mass arsenic poisoning in history. Groundwater throughout Bangladesh and West Bengal is contaminated with naturally occurring arsenic from the alluvial and deltaic sediments that form the region's aquifers. It has been estimated that 75 million people are at risk of developing health effects associated with the ingestion of arsenic. This project focuses on the use of microorganisms such as bacteria and algae to remove arsenic from water. Arsenic in the arsenite form was used in the studies. Experiments were conducted with a common alga and wastewater bacteria. A common green algae Scenedesmus abundans was used for determining arsenic uptake in batch experiments. Results of the experiments indicated that the algae biosorption could be modeled by the conventional Langmuir isotherm model. Algae morphology studies indicated that the algae cells were impacted due to the presence of arsenic as evidenced by clumping or loss of cell clusters. The wastewater bacteria also were capable of high percent of arsenic removal. Results indicate that microbial uptake of arsenic may be a viable method of pretreatment of arsenic contaminated water. However algae and sludge disposal would pose a problem and will have to be dealt with accordingly.     

Implementation of the semi-aerobic landfill system (Fukuoka method) in developing countries: a Malaysia cost analysis

Most of the existing solid waste landfill sites in developing countries are practicing either open dumping or controlled dumping. Proper sanitary landfill concepts are not fully implemented due to technological and financial constraints. Implementation of a fully engineered sanitary landfill is necessary and a more economically feasible landfill design is crucial, particularly for developing countries. This study was carried out by focusing on the economics from the development of a new landfill site within a natural clay area with no cost of synthetic liner up to 10 years after its closure by using the Fukuoka method semi-aerobic landfill system. The findings of the study show that for the development of a 15-ha landfill site in Malaysia with an estimated volume of 2,000,000 m(3), the capital investment required was about US 1,312,895 dollars, or about US 0.84 dollars/tonne of waste. Assuming that the lifespan of the landfill is 20 years, the total cost of operation was about US 11,132,536 dollars or US 7.15 dollars/tonne of waste. The closure cost of the landfill was estimated to be US 1,385,526 dollars or US 0.89 dollars/tonne of waste. Therefore, the total cost required to dispose of a tonne of waste at the semi-aerobic landfill was estimated to be US 8.89 dollars. By considering an average tipping fee of about US 7.89 dollars/tonne of waste in Malaysia in the first year, and an annual increase of 3% to about US 13.84 dollars in year-20, the overall system recorded a positive revenue of US 1,734,749 dollars. This is important information for the effort of privatisation of landfill sites in Malaysia, as well as in other developing countries, in order to secure efficient and effective landfill development and management.     

A review of the role of plastics in energy recovery

This report reviews the major scientific investigations that have been reported world wide over the last ten years on the effect of plastics on the process and emission performance of energy from waste (EFW) facilities. Concentrations of contaminants in air emissions and other process residues measured during tests with added plastics are compared with concentrations during normal operations and with the stringent emission limits stipulated in municipal waste combustor standards and guidelines in Canada, the United States and the European Union. The emission limits in these standards and guidelines are based on the use of the best technology available (Maximum Achievable Control Technology (MACT) standards in North America and Best Available Technology (BAT) standards in Europe) and are amongst the most stringent in the world.     

Diversity in the later Paleogene proboscidean radiation: a small barytheriid from the Oligocene of Dhofar Governorate,Sultanate of Oman

Despite significant recent improvements to our understanding of the early evolution of the Order Proboscidea (elephants and their extinct relatives), geographic sampling of the group’s Paleogene fossil record remains strongly biased, with the first ~30 million years of proboscidean evolution documented solely in near-coastal deposits of northern Africa. The considerable morphological disparity that is observable among the late Eocene and early Oligocene proboscideans of northern Africa suggests that other, as yet unsampled, parts of Afro-Arabia might have served as important centers for the early diversification of major proboscidean clades. Here we describe the oldest taxonomically diagnostic remains of a fossil proboscidean from the Arabian Peninsula, a partial mandible of Omanitherium dhofarensis (new genus and species), from near the base of the early Oligocene Shizar Member of the Ashawq Formation, in the Dhofar Governorate of the Sultanate of Oman. The molars and premolars of Omanitherium are morphologically intermediate between those of Arcanotherium and Barytherium from northern Africa, but its specialized lower incisors are unlike those of other known Paleogene proboscideans in being greatly enlarged, high-crowned, conical, and tusk-like. Omanitherium is consistently placed close to late Eocene Barytherium in our phylogenetic analyses, and we place the new genus in the Family Barytheriidae. Some features of Omanitherium, such as tusk-like lower second incisors, the possible loss of the lower central incisors, an enlarged anterior mental foramen, and inferred elongate mandibular symphysis and diminutive P₂, suggest a possible phylogenetic link with Deinotheriidae, an extinct family of proboscideans whose origins have long been mysterious.     

Lead in particulate deposits and in leaves of roadside plants, Karachi, Pakistan

Lead concentrations were determined for particulates which were deposited during one year on the leaves of roadside plants in Karachi. The particulates were collected from the leaves at a height of one metre. The lead accumulated by the leaves of different species was also measured. A statistically significant correlation was found between the number of passing petrol driven vehicles and the lead concentration in the deposits at different designated sites. However, no significant correlation was found between the concentration in the deposits and the lead accumulated by the leaves. A lead concentration of 30.00±6.6 ppm was recorded as the highest concentration in the particulate deposits, while maximum lead accumulated by the leaves was noted as 3.12±1.09 ppm.     

Do transportation taxes promote pro-environmental behaviour? An empirical investigation

The transportation sector is a crucial driver of energy intensity and environmental degradation. Therefore, we aim to explore the nexus of transportation taxes, energy intensity, and CO₂ emissions for the BICS economies. The econometric approaches, CS-ARDL and PMG-ARDL, have been employed to compute the estimates. The long-run estimates of the green transportation tax variable are negatively significant in both energy intensity and CO₂ emissions models irrespective of the estimation technique. These findings imply that green transportation taxes help reduce energy intensity and CO₂ emissions in BICS economies. Conversely, in the short-run, the effects of transportation taxes on energy intensity and CO₂ emissions are mixed and inconclusive. Hence, transportation taxes are necessary to keep the polluters under control not only from the transport sector but also serve as a deterrent for other sectors as well.

     

Spatio-temporal analysis of climatic variables in the western part of Bangladesh

Monitoring and detecting trends of climatic variables like rainfall and temperature are essential for agricultural developments in the context of climate change. The present study has detected trends in annual and cropping seasonal rainfall and temperature data for the period of 1961–2011 using Mann–Kendall (MK) test, Spearman’s rho (SR) test and modified Mann–Kendall test that has been applied to the significant lag-1 serial correlated time series data, and slope has been estimated using Sen’s Slope estimator for twelve meteorological stations located in the western part of Bangladesh covering about 41 % of the country. Almost 71 % trends explored by MK test in annual rainfall are statistically insignificant, and SR test also complies it. The spatial distribution of rainfall trend shows insignificant positive trends in major part of the area. Significant positive trends both by MK test and by SR test at 95 % confidence levels are observed at rates of 8.56, 11.15 and 13.66 mm/year at Dinajpur, Rangpur and Khepupara stations, respectively, and the Kharif season rainfall of these stations also shows significant increasing trends except Dinajpur. On the other hand, significant decreasing trends in annual rainfall are found at Bhola (?11.67 mm/year) and Rajshahi (?5.951 mm/year) stations and decreasing trends in rainfall dominated the Pre-Kharif season over the area. But, 83.33 % of the stations show rising trends in annual mean temperature with significant positive trends (as observed by both MK test and SR test) at Rangpur, Bogra, Faridpur, Jessore and Bhola stations where the rate of changes vary from 0.013 °C/year at Faridpur to 0.08 °C/year at Bhola. Most of the trends in Rabi and Pre-Kharif seasons of mean temperatures are not statistically significant. However, all stations except Barisal show significant rising trends in temperature in Kharif season. To cope with this changing pattern of rainfall and temperature, effective adaptation strategies should be taken to keep up the agricultural production that is related to livelihood of the most people and to ensure the country’s food security.     

Catalase and ascorbate peroxidase—representative H<Subscript>2</Subscript>O<Subscript>2</Subscript>-detoxifying heme enzymes in plants

Plants have to counteract unavoidable stress-caused anomalies such as oxidative stress to sustain their lives and serve heterotrophic organisms including humans. Among major enzymatic antioxidants, catalase (CAT; EC 1.11.1.6) and ascorbate peroxidase (APX; EC 1.11.1.11) are representative heme enzymes meant for metabolizing stress-provoked reactive oxygen species (ROS; such as H₂O₂) and controlling their potential impacts on cellular metabolism and functions. CAT mainly occurs in peroxisomes and catalyzes the dismutation reaction without requiring any reductant; whereas, APX has a higher affinity for H₂O₂ and utilizes ascorbate (AsA) as specific electron donor for the reduction of H₂O₂ into H₂O in organelles including chloroplasts, cytosol, mitochondria, and peroxisomes. Literature is extensive on the glutathione-associated H₂O₂-metabolizing systems in plants. However, discussion is meager or scattered in the literature available on the biochemical and genomic characterization as well as techniques for the assays of CAT and APX and their modulation in plants under abiotic stresses. This paper aims (a) to introduce oxidative stress-causative factors and highlights their relationship with abiotic stresses in plants; (b) to overview structure, occurrence, and significance of CAT and APX in plants; (c) to summarize the principles of current technologies used to assay CAT and APX in plants; (d) to appraise available literature on the modulation of CAT and APX in plants under major abiotic stresses; and finally, (e) to consider a brief cross-talk on the CAT and APX, and this also highlights the aspects unexplored so far.     

Molybdenum (Mo) increases endogenous phenolics,proline and photosynthetic pigments and the phytoremediation potential of the industrially important plant Ricinus communis L. for removal of cadmium from contaminated soil

Cadmium (Cd) in agricultural soil negatively affects crops yield and compromises food safety. Remediation of polluted soil is necessary for the re-establishment of sustainable agriculture and to prevent hazards to human health and environmental pollution. Phytoremediation is a promising technology for decontamination of polluted soil. The present study investigated the effect of molybdenum (Mo) (0.5, 1.0 and 2.0 ppm) on endogenous production of total phenolics and free proline, plant biomass and photosynthetic pigments in Ricinus communis plants grown in Cd (25, 50 and 100 ppm) contaminated soils and the potential for Cd phytoextraction. Mo was applied via seed soaking, soil addition and foliar spray. Foliar sprays significantly increased plant biomass, Cd accumulation and bioconcentration. Phenolic concentrations showed significantly positive correlations with Cd accumulation in roots (R ² = 0.793, 0.807 and 0.739) and leaves (R ² = 0.707, 721 and 0.866). Similarly, proline was significantly positively correlated with Cd accumulation in roots (R ² = 0.668, 0.694 and 0.673) and leaves (R ² = 0.831, 0.964 and 0.930). Foliar application was found to be the most effective way to deliver Mo in terms of increase in plant growth, Cd accumulation and production of phenolics and proline.