Development and Evaluation of a Continuous Coarse (PM10–PM25) Particle Monitor

ABSTRACT

In this paper, we describe the development and laboratory and field evaluation of a continuous coarse (2.5-10 um) particle mass (PM) monitor that can provide reliable measurements of the coarse mass (CM) concentrations in time intervals as short as 5-10 min. The operating principle of the monitor is based on enriching CM concentrations by a factor of ~25 by means of a 2.5-um cut point round nozzle virtual impactor while maintaining fine mass (FM)—that is, the mass of PM_{2 5} at ambient concentrations. The aerosol mixture is subsequently drawn through a standard tapered element oscillating microbalance (TEOM), the response of which is dominated by the contributions of the CM, due to concentration enrichment. Findings from the field study ascertain that a TEOM coupled with a PM₁₀ inlet followed by a 2.5-um cut point round nozzle virtual impactor can be used successfully for continuous CM concentration measurements. The average concentration-enriched CM concentrations measured by the TEOM were 26-27 times higher than those measured by the time-integrated PM₁₀ samplers [the micro-orifice uniform deposit     

An IoT-based waste management system monitored by cloud

Clever solid waste bin is important to create a well-organized and dynamic waste management system. This paper presents the novel way of carrying out an integrated sensing system which automates the solid waste management process. The proposed smart waste bin is based on ultrasonic-level sensor and various gas sensors which automatically sense the hazardous gases and the maximum limit of waste. The approach is unique and uses cloud and mobile app-based monitoring. Two important features of work are it not only checks the maximum waste level of the bin but also checks various stinky gases. The other part of the work is conveying the information to the responsible authority. This unique approach takes the assistance of cloud sever because of its advantages in field of usability, accessibility and disaster recovery. The information can be linked with municipality web server for immediate action. The waste bins are tracked by a unique number which represents its location. The eccentric technique gives all information related to physical condition of a particular bin and can easily reach the corresponding authority. The whole information is interconnected with a cloud-based web-information system at the host server.     

Toxic metals and organochlorine pesticides residue in single herbal drugs used in important ayurvedic formulation – ‘Dashmoola’

Herbal formulations are getting popularity throughout the world and commercialized extensively for various medicinal properties. WHO has emphasized the need for quality assurance of herbal products, including testing of heavy metals and pesticides residues. 'Dashmoola', a popular herbal formulation, with immunomodulator and febrifugal properties, consists of ten single root drugs. In view of WHO guidelines, single herbal drugs used in 'Dashmoola', were collected from different places of India for testing heavy metals and persistent pesticides residue. Although use of roots in 'Dashmoola' is prescribed in original ayurvedic literature but now many pharmacies use stem in place of roots. Therefore, in the present study both roots and stems were selected for estimation of six heavy metals namely arsenic (As), mercury (Hg), lead (Pb), cadmium (Cd), chromium (Cr) and nickel (Ni). Apart from these, the organochlorine pesticides residue viz. different metabolites of DDT, DDE, isomers of HCH and alpha-endosulfan were checked in total 40 samples of single crude drugs. Heavy metals except Hg, were present in most of the samples. In few samples Pb and Cd concentration were beyond the WHO permissible limits. Although alpha-HCH and gamma-HCH were present in almost all the samples, but other pesticides were not detected in these samples. DDT and DDE were found only in two samples.     

Uptake and translocation of metals in Spinacia oleracea L. grown on tannery sludge-amended and contaminated soils: effect on lipid peroxidation, morpho-anatomical changes and antioxidants

The plants of Spinacia oleracea L. grown on contaminated soil (CS) and different amendments of tannery sludge (TS) have shown high accumulation of metals in its edible part. The accumulation of toxic metal (Cr) in the leaves of the plants grown on CS was recorded as 40.67 microgg(-1)dw. However, the leaves of the plants grown on 100% TS have accumulated about two times (70.80 microgg(-1)dw) higher Cr than the 10% TS (31.21 microgg(-1)dw). Among growth parameters, the root length was more affected at 90 d than the shoot length, number of leaves and leaf area. The study of scanning electron micrographs showed 29.31% increase in stomatal length in the leaves of the plants grown on CS as compared to garden soil (GS), which served as control, however it decreased in the plants grown on higher amendments of TS. The decrease in MDA content at initial period of exposure and lower amendment was recorded in the leaves, whereas, significant increase (>10% TS onward) was observed with increase in tannery sludge ratio at 90 d as compared to GS. A coordinated increase in all the studied antioxidants (cysteine, non-protein thiol, ascorbic acid, carotenoid contents) was found up to 75 d of growth. At 90 d, most of the antioxidant decreased as compared to 75 d causing oxidative stress as evidenced by increased level of lipid peroxidation and decreased chlorophyll and protein contents. Maximum increase of 181.43% in MDA content and maximum decrease of 53.69% in total chlorophyll content was recorded in the leaves of the plants grown on 100% TS after 90 d of growth. The plants grown on CS have shown an increase in shoot length, number of leaves, leaf area, photosynthetic pigments and protein contents and in all the studied antioxidants. Thus, these plants are able to combat stress involving defense mechanism, resulting in healthy growth of the plants. The results are well coordinated as there is no change in the MDA content as compared to the plants grown on GS. In view of high Cr accumulation in edible part of S. oleracea grown on CS after irrigation with tap water, it is not advisable to use these plants for edible purposes. Summing up, it is recommended that the level of metals in the edible part should be checked instead of healthy growth as deciding parameter for consumption. It is demonstrated through this study that metal enriched plants have detoxification mechanism and grow well on organic matter enriched contaminated soil.     

Effects of population and population pressure on forest resources and their conservation: a modeling study

In this paper, a nonlinear mathematical model is proposed and analyzed to study the depletion of forest resources caused by population and the corresponding population pressure. It is assumed that the cumulative density of forest resources and the density of populations follow logistic models with prey–predator type nonlinear interaction terms. It is considered that the carrying capacity of forest resources decreases by population pressure, the main focus of this paper. A conservation model is also proposed to control the population pressure by providing some economic incentives to people, the amount of which is assumed to be proportional to the population pressure. The model is analyzed by using stability theory of differential equations and numerical simulation. The model analysis shows that as the density of population or population pressure increases, the cumulative density of forest resources decreases, and the resources may become extinct if the population pressure becomes too large. It is also noted that by controlling the population pressure, using some economic incentives, the density of forest resources can be maintained at an equilibrium level, which is population density dependent. The simulation analysis of the model confirms analytical results.     

Decreasing reliance on mineral nitrogen--yet more food

Higher crop production normally demands higher nutrient application rates and consequently increased mineral nitrogen use. With food demand for 2030 estimated around 2800 mill. tonnes (t) yr-1, the corresponding mineral N consumption figure is 96 mill. t (78 mill. t yr-1 in 1995/1997). Global-level mineral N losses to the environment from mineral fertilizer use are currently 36 mill. t yr-1, worth USD 11,700 mill. and with adverse environmental impacts. However, innovative fertilizer-use efficiency (FUE) technologies enable increased production with a less than a proportionate increase in mineral-N use. Moreover, nitrogen-nutrient supplies can be augmented through improvements in agricultural production systems and in the exploitation of alternative sources such as biological nitrogen fixation (BNF). By 2030, with adequate policy, technology transfer, research and investment support, the on-farm adoption of BNF and FUE technologies could generate savings of 10 mill. t yr-1 of mineral N, worth USD 3300 mill.     

Organochlorine residues in water from the Mahala water reservoir, Jaipur, India

Residues of p,p'-DDE, p,p'-DDT alpha-, beta-, gamma-isomers of HCH, aldrin and heptachlor in water, from four different sites of the Mahala water reservoir were monitored periodically from September 1985 to October 1987. All the samples contained the above residues in varying concentrations. Isomers of HCH predominated and were followed in relative dominance by aldrin, total DDT and heptachlor residues, p,p'-DDE and p,p'-DDD constituted the major fraction of total p,p'-DDT. Monthly total organochlorine residue levels in water ranged between 1.07 and 81.23 microg litre-1. The variation is attributed to the run-off or subsoil water movement from the catchment area.     

Collective action: an alternative institutional arrangement for reducing water pollution in an industrial estate in India

This study explores the possibility of collective action as an alternative option for reducing water pollution for a cluster of small-scale industries. A case study of the Nandesari Industrial Estate in Gujarat, India, demonstrates the roles played by different agents, such as affected parties, polluters, non-governmental organizations, regulators and the court. The study empirically estimates the 'benefits' and 'costs' of water pollution abatement for a cluster of 250 small-scale industries at Nandesari, and uses these estimates for a social cost-benefit analysis. Benefits are estimated using the contingent valuation method, with a 'willingness to accept' format for the rural areas, and a 'willingness to pay' format for the urban area of the nearby Vadodara city. The article considers costs of command and control, market-based solutions and the option of common effluent treatment as alternative scenarios. It discusses how collective action and joint abatement at a common effluent treatment plant (CETP) by the 250 industries efficiently comply with the State Pollution Control Board norms, which had not been possible for the factories acting individually over the last 20 years. Finally, a detailed social cost-benefit analysis has been undertaken to estimate the net present social benefits with and without CETP. The cost-benefit analysis shows the economic advantage and social desirability of 'collective action' (joint treatment with CETP institutional arrangement) for water pollution abatement with respect to all possible scenarios comprising shadow prices of investment, foreign exchange, unskilled labour and equity considerations.