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101.
The adsorption of a synthetic textile dye (Remazol Brilliant Black Reactive) on cocoa pod husk-based activated carbon was investigated in batch process. The adsorbent prepared was characterized by gas adsorption surface analysis (Brunauer Emmett Teller, BET), scanning electron microscopy, and Fourier transform infrared spectroscopy. The effects of initial dye concentration, contact time, solution temperature, and solution pH were evaluated. Equilibrium data were fitted to Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherm models, the first being the best with maximum monolayer coverage of 111?mg?g?1. Kinetic data were fitted into pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich models; the pseudo second-order model provided the best correlation. Maximum adsorption was observed at pH 7. Standard free energy, standard enthalpy, and standard entropy were also calculated. The adsorption interaction was found to be endothermic and spontaneous. Both the mean free energy of adsorption and the activation energy show that the mechanism is by physisorption. 相似文献
102.
Muhammad Nadeem Asghar Aneela Anwar Hafiz Muhammad Abdur Rahman Sammia Shahid Iram Nadeem 《毒物与环境化学》2013,95(8-10):659-676
AbstractThe objective of the present study is to synthesize various metal ions mixed TiO2 nanoparticles using a continuous hydrothermal synthesis pilot reactor for dye-sensitized solar cells (DSCs). In the pilot plant, aqueous solutions of the metal salts are mixed with a flow of supercritical water (450?°C and 24.1?MPa) in a confined jet mixer for continuous synthesis of metal ions-mixed nano-titania. Characterization of the particles was made using Brunauer–Emmett–Teller technique for specific surface area, powder X-ray diffraction analysis and transmission electron microscopy for identification and crystallite size, X-ray photoelectron spectroscopy for surface analysis and infrared spectroscopy for distinct group identification. Following the already existing procedures and using the titanates synthesized, dye-sensitized cells of 1?cm2 area were assembled and their photovoltaic parameters were evaluated under standard test conditions. The power conversion efficiencies (η %) for 40?mol % Zn2+, 5?mol % Zr4+ and 10?mol % Zn4+ titania were obtained to be 4.8, 4.95 and 4.9, respectively. The promising efficiency results from a greener and large-scale production of nano-titania is a step forward towards commercializing DSC technology. 相似文献
103.
Fresh and healthy specimens of Oreochromis niloticus (mean weight 70.5± 1.23 g and mean length, 12.3± 1.5cm) and Clarias gariepinus (mean weight, 41.8±2.3 g and mean length 13.78 ± 1.2 cm) were exposed to heavy metal lead, ranging in concentration from 10 to 18 mg L‐1 for O. niloticus and 20 to 28 mg L‐1 for C. gariepinus respectively. The 96 h LC50 for both the species was computed as 12.45 mg L‐1 (O. niloticus) and 22.65 mg L‐1 (C. gariepinus). The cichlid fish was exposed to sublethal concentration of lead (2, 4 and 6 mgL‐1) and catfish (4, 8 and 12 mgL‐1). The erythrocytes count, haemoglobin concentration, haematocrit and the value of serum glucose increased significantly (P < 0.01), whereas leucocytes count, serum protein and serum triglyceride after intoxication declined in both the species with the same pattern but in different quantity. After 96 h of time a significant depletion of muscle and liver glycogen was noted, being greater in muscle (16.7% in O. niloticus) and in liver (15.9% in C. gariepinus). The response of fish to lead was dose dependent. 相似文献
104.
Malik Nur Khaliesah Abdul Manaf Latifah Abd Jamil Nor Rohaizah Rosli Mohd Hafiz Ash’aari Zulfa Hanan Othman Mohamad Al-Ekhwan 《Journal of Material Cycles and Waste Management》2021,23(4):1289-1302
Journal of Material Cycles and Waste Management - The accumulation of floatable litter load captured in gross pollutant trap (GPT) due to the hydrological runoff has become challenging due to rapid... 相似文献
105.
Amanchi NR Hussain MM 《Journal of environmental biology / Academy of Environmental Biology, India》2010,31(5):603-607
Experiments were conducted to evaluate the toxic effects ofmonocrotophos in ciliate models Paramecium caudatum and Oxytricha fallax. In acute toxicity studies higherconcentrations of monocrotophos caused marked increase in mobility of cells exhibiting rocking movements within two mins of exposure but were decreased after 30 mins. LC50 value by mortality curve for 3 hr acute toxicity test of Oxytricha fallax and Paramecium caudatum was found 307.744 +/- 33.27 mg l(-1) and 332.284 +/- 57.52 mg l(-1) respectively. Oxytricha fallax was found sensitive than Paramecium caudatum to monocrotophos. In acute exposure cells showed deformities such as swelling, oval shaped deformity and in higher concentrations shortening of longitudinal axis with blackening of cytoplasm occurred. The length of paramecia was reduced prominently. Similarly enlargement of contractile vacuole and stress egestion of food vacuoles was also observed. The morphological studies showed the changes in shape, size, colour and width of Paramecia and Oxytricha. Frequencies of macronuclear aberrations were significant showing deformities such as rod shaped, elongation, fragmentation, diffusion and total absence of nucleus and were concentration dependent. The data provided in the present study on interaction of pesticides with nuclear structure can be of immense value because most of these pesticides have been reported to have carcinogenic, mutagenic and teratogenic properties. 相似文献
106.
Ahsan Haseeb Ayub Mahnoor Irfan Hafiz Muhammad Saleem Muhammad Anjum Irfan Haider Ihtisham Asif Awais Abbas Syed Qamar ul Hulassan Syed Shams 《Environmental science and pollution research international》2023,30(6):14580-14591
Environmental Science and Pollution Research - Fluvoxamine, a selective serotonin re uptake inhibitor, is used to treat depression. The aim of present study was to evaluate fluvoxamine in acute... 相似文献
107.
Kusin Faradiella Mohd Hasan Sharifah Nur Munirah Syed Molahid Verma Loretta M. Yusuff Ferdaus Mohamat Jusop Shamsuddin 《Environmental science and pollution research international》2023,30(9):22188-22210
Environmental Science and Pollution Research - Mining waste that is rich in iron-, calcium- and magnesium-bearing minerals can be a potential feedstock for sequestering CO2 by mineral carbonation.... 相似文献
108.
Meraj Alam Khan Ayaz Mahmood Dar Mohd Arsalan 《Journal of Polymers and the Environment》2017,25(3):717-727
A series of organic–inorganic conducting nano polymer-matrix composite cation-exchanger have been synthesized via sol–gel method and characterized through FTIR, XRD, TGA-DTA, SEM, and TEM studies. The structural studies confirm the semi-crystalline nature of the material but the morphology of the exchanger gets changed after incorporation of inorganic moiety. The particle size of the nano-composite was found to be 19.2 nm. The observed band gap for the different samples was found to be in the range of 3.70–4.61 eV which shows that nano-composite material covers semiconducting range but the resistivity of samples is highly dependent on the percentage of inorganic part in the composite. Further the oxidative degradation of the polymer backbone begins after the removal of trapped water successively followed by dopant and low molecular weight oligomers. During the antimicrobial screening, the nano-composite was found to be active against different strains of bacteria and fungi. Gel electrophoresis and molecular docking studies were carried out to check the interaction and mechanism of inhibition of microbial growth, respectively by studying the effect of the nano-composite with DNA-Topoisomerase-1. 相似文献
109.
Mohd Reza Esa Anthony Halog Lucia Rigamonti 《Journal of Material Cycles and Waste Management》2017,19(3):1144-1154
Construction and demolition (C&D) waste is a pressing issue not only in Malaysia, but it is also a worldwide concern including the developed countries as well. C&D waste should be managed throughout the construction cycle. The concept of circular economy (CE) is an emerging notion that has the potential to be utilized as waste minimization approach. This paper aims to assess the potentials of incorporating the CE concept as an approach to minimizing C&D wastes, by developing a CE-based theoretical framework for C&D waste management in Malaysia. In line with this objective, a systematic review has been conducted to determine how CE can be operationalised as a strategy to minimize wastes, while considering it as a key factor for mitigating the environmental impacts. Based on the literature review, a CE-based theoretical framework has been proposed using Malaysia as a case study. The framework has been developed following a three-layer approach namely micro-, meso-, and macro-levels. Waste minimization strategies have been identified for each level taking into account the main stages in the construction industry, i.e., planning, designing, procurement, construction, and demolition. The different stakeholders involved at each stage and their interactions in the stages have also been identified. 相似文献
110.
Ariffin Muhammad Afif Wan Mahmood Wan Mohd Faizal Harun Zambri Mohamed Ramizi 《Journal of Material Cycles and Waste Management》2017,19(3):1244-1252
Journal of Material Cycles and Waste Management - This paper focuses on the performance of oil palm empty fruit bunch (EFB) gasification using a medium-scale downdraft gasifier for power... 相似文献