Estimation and field measurement of methane emission from waste landfills in Hanoi, Vietnam

A methodology for estimating the methane emissions from waste landfills in Hanoi, Vietnam, as part of a case study on Asian cities, was derived based on a survey of documents and statistics related to waste management, interviews with persons in charge, and field investigations at landfill sites. The waste management system in Hanoi was analyzed to evaluate the methane emissions from waste landfill sites. The quantity of waste deposited into the landfill was evaluated from an investigation of the waste stream. The composition of municipal waste was surveyed in several districts in the Hanoi city area, and the quantities of degradable organic waste that had been deposited into landfill for the past 15 years were estimated. Field surveys on methane emissions from landfills of different ages (0.5, 2, and 8 years) were conducted and their methane emissions were estimated to be 120, 22.5, and 4.38 ml/min/m², respectively. The first-order reaction rate of methane generation was obtained as 0.51/year. Methane emissions from waste landfills were calculated by a first-order decay model using this emission factor and the amount of landfilled degradable waste. The estimates of methane emissions using the model accorded well with the estimates of the field survey. These results revealed that methane emissions from waste landfills estimated by regional-specific and precise information on the waste stream are essential for accurately determining the behavior of methane emissions from waste landfills in the past, present, and future.     

Socialist hydropower governances compared: dams and resettlement as experienced by Dai and Thai societies from the Sino-Vietnamese borderlands

Regional Environmental Change - Research on hydropower development has shown that a diversity of social and environmental impacts of dams is distributed unevenly among various state and corporate...     

长江口潮滩芦苇根表铁膜磁性特征及其环境意义

湿地植物根表铁膜对包括重金属在内的物质迁移转化具有重要作用,其氧化铁组成研究备受重视,但利用环境磁学方法进行表征的研究还未见报道.本文对长江口潮滩植物芦苇根系及周边沉积物进行了磁学分析,并结合沉积物粒度、漫反射光谱等测试,对芦苇根表铁膜的磁性矿物组成进行了系统研究.结果表明,芦苇根表铁膜磁性矿物主要包括磁铁矿和赤铁矿.由于沉积物不同深度氧化还原环境的不同,铁膜磁性矿物组成存在垂向差异.研究柱样24 cm深度以上,由于相对氧化的环境,铁膜磁性矿物除磁铁矿外,还有较多的赤铁矿贡献;24 cm深度以下,因根系处于相对还原的环境,磁性矿物以磁铁矿为主.与沉积物相比,24 cm以上深度铁膜中亚铁磁性矿物含量较低,24 cm深度以下则相反,反映铁膜和沉积物磁性矿物来源不同.本项研究表明,磁性测量方法有助于认识湿地植物根表铁膜的矿物组成,对湿地生物地球化学过程研究具有重要价值.     

Determination of polycyclic aromatic hydrocarbons in dry tea

Twenty-eight different tea samples sold in the United States were evaluated using high-performance liquid chromatography (HPLC) with fluorescence detection (FLD) for their contamination with polycyclic aromatic hydrocarbons (PAHs). Many PAHs exhibit carcinogenic, mutagenic, and teratogenic properties and have been related to several kinds of cancer in man and experimental animals. The presence of PAHs in environmental samples such as water, sediments, and particulate air has been extensively studied, but food samples have received little attention. Eighteen PAHs congeners were analyzed, with percentage recovery higher than 85%. Contamination expressed as the sum of the 18 analyzed PAHs was between 101 and 1337 μg/kg on dry mass and the average contents in all of the 28 examined samples was 300 μg/kg on dry mass. Seven of the congeners were found in all samples with wide ranges of concentrations as follows: fluorene (7–48 μg/kg), anthracene (1–31 μg/kg), pyrene (1–970 μg/kg), benzo(a)anthracene (1–18 μg/kg) chrysene (17–365 μg/kg), benzo(a)pyrene (1–29 μg/kg), and indeno(1,2,3-cd)pyrene (4–119 μg/kg). The two most toxic congeners benzo(a)pyrene and dibenzo(a,h)anthracene were found at high concentrations only in Earl Grey Twinnings, Earl Grey Harney& Sons Fine Teas, and Chai Ultra Spice Black Tea Twinnings. Six PAH congeners are considered as suspected carcinogens (U.S.EPA), formed the basis of the estimation of the toxic equivalent (TEQ), Chai Ultra-Spice Black Tea Twinnings had the highest TEQ (110.9) followed by two grey tea samples, Earl Grey Harney & Sons Fine Tea (57.7) and Earl Grey Twinnings (54.5). Decaffeinated grey teas had the lowest TEQs, decaffeinated Earl Grey Bigelow (9.4) and Green Tea Honey Lemon Decaffeinated Lipton (9.6).     

Residual congener pattern of dioxins in human breast milk in southern Vietnam

This study evaluated residual congener patterns of dioxin/furan (=PCDD/DF) related to tactical herbicides aerially sprayed over the regions of southern Vietnam through Operation Ranch Hand. The study focused on Cam Chinh (CC) commune, Quang Tri province (an area sprayed with tactical herbicides), and the Cam Phuc (CP) commune, Ha Tinh province (a non-sprayed area). Breast milk samples for analysis were collected in September 2002 and July 2003 from lactating primiparous and multiparous mothers born after the war (<31 years old). We found the levels of each congener in the CC commune were higher than in the CP commune, and determined specificity in the PCDD/DF congener pattern in CC commune samples by cluster analysis. The congener pattern is characterized by higher (the hexa-, the hepta-, and the octa-) chlorinated PCDD/DFs; this appears to be the same profile as that presented by pentachlorophenol (PCP), rather than 2,4,5-trichlorophenoxy acid (2,4,5-T) contaminated with 2,3,7,8-TCDD. A GC/MS study in the 1970s detected the chlorophenols 2,4-di and 2,4,6-trichlorophenol in some Agent Orange samples, which contained, like PCP, a wide variety of PCDD/DF congeners. In this context, it may be expected that certain tactical herbicides contaminated with various chlorophenol impurities, have a unique congener pattern when compared with pure 2,4,5-T formulations.     

Contamination by perfluorinated compounds in water near waste recycling and disposal sites in Vietnam

There are very few reports on the contamination by perfluorinated chemicals (PFCs) in the environment of developing countries, especially regarding their emission from waste recycling and disposal sites. This is the first study on the occurrence of a wide range of PFCs (17 compounds) in ambient water in Vietnam, including samples collected from a municipal dumping site (MD), an e-waste recycling site (ER), a battery recycling site (BR) and a rural control site. The highest PFC concentration was found in a leachate sample from MD (360 ng/L). The PFC concentrations in ER and BR (mean, 57 and 16 ng/L, respectively) were also significantly higher than those detected in the rural control site (mean, 9.4 ng/L), suggesting that municipal solid waste and waste electrical and electronic equipment are potential contamination sources of PFCs in Vietnam. In general, the most abundant PFCs were perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluoroundecanoic acid (PFUDA; <1.4–100, <1.2–100, and <0.5–20 ng/L, respectively). Interestingly, there were specific PFC profiles: perfluoroheptanoic acid and perfluorohexanoic acid (88 and 77 ng/L, respectively) were almost as abundant as PFOA in MD leachate (100 ng/L), whereas PFNA was prevalent in ER and BR (mean, 17 and 6.2 ng/L, respectively) and PFUDA was the most abundant in municipal wastewater (mean, 5.6 ng/L), indicating differences in PFC contents in different waste materials.     

Kinetics of the reactions of soot surface-bound polycyclic aromatic hydrocarbons with the OH radicals

The kinetics of the heterogeneous reaction of OH radicals with 15 polycyclic aromatic hydrocarbons (PAHs) present in laboratory generated simulated kerosene combustion soot was studied at T = 290 K in a low pressure discharge-flow reactor combined with an electron-impact mass spectrometer. The kinetics of soot-bound PAH consumption in reaction with OH were monitored using off-line HPLC measurements of their concentrations in soot samples as a function of time of exposure to OH. Concentration of OH radicals in the gas phase was measured by mass spectrometry. The first-order rate constants measured for the individual PAH at T = 290 K ranged from 0.02 to 0.04 s^?1 and were found to be independent of the OH concentration ([OH] = (0.34–2.5) × 10¹² molecule cm^?3) and of the molecular structure of the PAH. In addition, the uptake coefficient of OH on soot surface and the diffusion coefficient of OH in He were measured to be 0.19 ± 0.03 (calculated with geometric surface area) and (615 ± 80) Torr cm² s^?1, respectively. Comparison of the results on the PAH + OH reaction to those from previous studies carried out on different carbonaceous substrates, indicates probable dependence of the heterogeneous reactivity of PAH toward OH on the substrate nature. Rapid reaction with OH can be an important potential pathway of the atmospheric degradation of non-volatile PAH present mainly in the particulate phase in the atmosphere.     

Tsunami mitigation by coastal vegetation considering the effect of tree breaking

Damage to vegetation by tsunami moment and reduction of potential tsunami force are discussed based on a numerical simulation. A numerical model based on two-dimensional nonlinear long-wave equations that include drag forces and turbulence-induced shear force due to the presence of vegetation was developed to estimate tree breaking. The numerical model was then applied to a coastal forest where two dominant tropical vegetation species, Pandanus odoratissimus and Casuarina equisetifolia, were considered. The threshold water depth for tree breaking increased with increasing forest width, and the analysis was consistent with the field investigation results that the critical tsunami water depth for breaking is around 80% of the tree height for P. odoratissimus. C. equisetifolia is stronger than P. odoratissimus against tsunami action, but P. odoratissimus can reduce a greater tsunami force than C. equisetifolia due to its complex of aerial root structures. Even if breakage occurs, P. odoratissimus still has high potential to reduce the tsunami force due to its dense aerial root structures. Previous numerical models that do not include the breaking phenomena may overestimate the vegetation effect for reducing tsunami force. The combination of P. odoratissimus and C. equisetifolia is recommended as a vegetation bioshield to protect coastal areas from tsunami hazards.     

Effects of cadmium and chlordane on cellular apoptosis in ecotoxicological test species

Cadmium and chlordane are compounds chosen for a preliminary study on the impact of environmental contaminants on apoptosis in different representative species. These two potentially toxic substances decrease in vitro apoptosis of Daphnia magna cells. This appears to be related to the chemical concentrations and the time exposure. Cadmium was also directly introduced to the cell culture medium of Syrian hamster embryos (SHE) or indirectly via daphnids, which had firstly consumed algae contaminated with cadmium. A very sharp transfer of cadmium toxicity from algae to daphnids is noted and an inhibition of the apoptosis in SHE cells can be observed.     

Persistence of white spot syndrome virus in shrimp ponds and surrounding areas after an outbreak

White Spot Syndrome Virus (WSSV) is the major and most serious pathogen in shrimp aquaculture industries. By using a sensitive PCR-based detection technique followed by sequencing multiple PCR products for confirmation, we address to the question of whether WSSV can persist in shrimp ponds and surrounding areas after an outbreak. The seawater samples were taken from two shrimp ponds and surrounding canals in a coastal area in northern Vietnam, Quang Ninh Province where the shrimps cultured in the two ponds had been killed due to a WSSV outbreak in April 2001 and the ponds were thereafter abandoned. A total of 480 seawater samples (30 samples each for July and December of 2001 and 2002) were subjected to WSSV genome detection. Although the detection rates of WSSV genome were generally gradually declined in seawater environments of both diseased shrimp ponds and surrounding canals, WSSV was still detected with rates of more than 10% in the diseased ponds and lower in surrounding canals in December 2002, 20 months after the WSSV outbreak.