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871.
TianTian Xiong Camille Dumat Antoine Pierart Muhammad Shahid Yuan Kang Ning Li Georges Bertoni Christophe Laplanche 《Environmental geochemistry and health》2016,38(6):1283-1301
The quality of cultivated consumed vegetables in relation to environmental pollution is a crucial issue for urban and peri-urban areas, which host the majority of people at the global scale. In order to evaluate the fate of metals in urban soil–plant–atmosphere systems and their consequences on human exposure, a field study was conducted at two different sites near a waste incinerator (site A) and a highway (site B). Metal concentrations were measured in the soil, settled atmospheric particulate matter (PM) and vegetables. A risk assessment was performed using both total and bioaccessible metal concentrations in vegetables. Total metal concentrations in PM were (mg kg?1): (site A) 417 Cr, 354 Cu, 931 Zn, 6.3 Cd and 168 Pb; (site B) 145 Cr, 444 Cu, 3289 Zn, 2.9 Cd and 396 Pb. Several total soil Cd and Pb concentrations exceeded China’s Environmental Quality Standards. At both sites, there was significant metal enrichment from the atmosphere to the leafy vegetables (correlation between Pb concentrations in PM and leaves: r = 0.52, p < 0.05) which depended on the plant species. Total Cr, Cd and Pb concentrations in vegetables were therefore above or just under the maximum limit levels for foodstuffs according to Chinese and European Commission regulations. High metal bioaccessibility in the vegetables (60–79 %, with maximum value for Cd) was also observed. The bioaccessible hazard index was only above 1 for site B, due to moderate Pb and Cd pollution from the highway. In contrast, site A was considered as relatively safe for urban agriculture. 相似文献
872.
Jiwan SINGH Yoon-Young CHANG Jae-Kyu YANG Seon-Hong KANG Janardhan Reddy KODURU 《Frontiers of Environmental Science & Engineering》2016,10(4):9
Phenol removal by n/m Fe in the presence of H2O2 was highly effective.
Increasing the amounts of n/m Fe and H2O2?increased the phenol removal rate.
Phenol removal was decreased with an increase in the concentration of phenol.
The natural pH (6.9) of the solution was highly effective for phenol removal.
The pseudo-first-order kinetics was best fitted for the degradation of phenol.
The study investigates the magnetic separation of Fe from automobile shredder residue (ASR) (<0.25 mm) and its application for phenol degradation in water. The magnetically separated Fe was subjected to an ultrasonically assisted acid treatment, and the degradation of phenol in an aqueous solution using nano/micro-size Fe (n/m Fe) was investigated in an effort to evaluate the possibility of utilizing n/m Fe to remove phenol from wastewater. The prepared n/m Fe was analyzed by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The effects of the dosages of n/mFe, pH, concentration of phenol and amount of H2O2 on phenol removal were evaluated. The results confirm that the phenol degradation rate was improved with an increase in the dosages of n/mFe and H2O2; however, the rate is reduced when the phenol concentration is higher. The degradation of phenol by n/mFe followed the pseudo-first-order kinetics. The value of the reaction rate constant (k) was increased as the amounts of n/m Fe and H2O2 increased. Conversely, the value of k was reduced when the concentration of phenol was increased. The probable mechanism behind the degradation of phenol by n/m Fe is the oxidation of phenol through hydroxyl radicals which are produced during the reaction between H2O2 and n/m Fe. 相似文献
873.
Water-dissolved oxygen was supplied into anaerobic aquifer , which oxidized Fe(II), Mn(II) and trivalent arsenic and changed
them into undissolved solid matter through hydrolysis, precipitation, co-precipitation and adsorption processes. The experiment
was carried out on the column imitated a bore core of anaerobic aquifer with water phase containing Fe(II), Mn(II), As(III)
concentration of 45.12 mg/L, 14.52 mg/L, 219.4 μg/L, respectively and other ions similarly composition in groundwater. After
6 days of air supply, concentration of iron reduced to 0.38 mg/L, manganese to 0.4 mg/L, arsenic to 9.8 μg/L (equivalent 99.16%
of iron, 97.25% of manganese and 95.53% of arsenic fixed), and for other ions, the concentration changed almost according
to general principles. Ion phosphate and silicate strongly influenced on arsenic removal but supported iron and manganese
precipitation from water phase. Based on the experimental results, new model of groundwater exploitation was proposed. 相似文献
874.
875.
Pius Lee Youhua Tang Daiwen Kang Jeff McQueen Marina Tsidulko Ho-Chun Huang Sarah Lu Mary Hart Hsin-Mu Lin Shaocai Yu Geoff DiMego Ivanka Stajner Paula Davidson 《Environmental Fluid Mechanics》2009,9(1):23-42
Discrepancies in grid structure, dynamics and physics packages in the offline coupled NWS/NCEP NAM meteorological model with
the U.S. Environmental Protection Agency Community Multiscale Air Quality (CMAQ) model can give rise to inconsistencies. This
study investigates the use of three vertical mixing schemes to drive chemistry tracers in the National Air Quality Forecast
Capability (NAQFC). The three schemes evaluated in this study represent various degrees of coupling to improve the commonality
in turbulence parameterization between the meteorological and chemistry models. The methods tested include: (1) using NAM
predicted TKE-based planetary boundary height, h, as the prime parameter to derive CMAQ vertical diffusivity; (2) using the NAM mixed layer depth to determine h and then proceeding as in (1); and (3) using NAM predicted vertical diffusivity directly to parameterize turbulence mixing
within CMAQ. A two week period with elevated surface O3 concentrations during the summer 2006 has been selected to test these schemes in a sensitivity study. The study results are
verified and evaluated using the EPA AIRNow monitoring network and other ozonesonde data. The third method is preferred a
priori as it represents the tightest coupling option studied in this work for turbulent mixing processes between the meteorological
and air quality models. It was found to accurately reproduce the upper bounds of turbulent mixing and provide the best agreement
between predicted h and ozonesonde observed relative humidity profile inferred h for sites investigated in this study. However, this did not translate into the best agreement in surface O3 concentrations. Overall verification results during the test period of two weeks in August 2006, did not show superiority
of this method over the other 2 methods in all regions of the continental U.S. Further efforts in model improvement for the
parameterizations of turbulent mixing and other surface O3 forecast related processes are warranted. 相似文献
876.
Youhua Tang Pius Lee Marina Tsidulko Ho-Chun Huang Jeffery T. McQueen Geoffrey J. DiMego Louisa K. Emmons Robert B. Pierce Anne M. Thompson Hsin-Mu Lin Daiwen Kang Daniel Tong Shaocai Yu Rohit Mathur Jonathan E. Pleim Tanya L. Otte George Pouliot Jeffrey O. Young Kenneth L. Schere Paula M. Davidson Ivanka Stajner 《Environmental Fluid Mechanics》2009,9(1):43-58
A sensitivity study is performed to examine the impact of lateral boundary conditions (LBCs) on the NOAA-EPA operational Air
Quality Forecast Guidance over continental USA. We examined six LBCS: the fixed profile LBC, three global LBCs, and two ozonesonde
LBCs for summer 2006. The simulated results from these six runs are compared to IONS ozonesonde and surface ozone measurements
from August 1 to 5, 2006. The choice of LBCs can affect the ozone prediction throughout the domain, and mainly influence the
predictions in upper altitude or near inflow boundaries, such as the US west coast and the northern border. Statistical results
shows that the use of global model predictions for LBCs could improve the correlation coefficients of surface ozone prediction
over the US west coast, but could also increase the ozone mean bias in most regions of the domain depending on global models.
In this study, the use of the MOZART (Model for Ozone And Related chemical Tracers) prediction for CMAQ (Community Multiscale
Air Quality) LBC shows a better surface ozone prediction than that with fixed LBC, especially over the US west coast. The
LBCs derived from ozonesonde measurements yielded better O3 correlations in the upper troposphere. 相似文献
877.
The Fenton's system is applied to the destruction of perchloroethylene (PCE) present as a dense non-aqueous phase liquid (DNAPL) in soil slurry systems; the initial concentration of PCE was 45 times higher than its aqueous solubility. Studies were conducted in two matrices: Ottawa sand and soil from Warsaw, IN. In Ottawa sand, a 60-62% decrease in PCE concentration was observed, and Cl(-) recovery was 47-58%, whereas in Warsaw soil, a 44-49% decrease in PCE concentration and a Cl(-) recovery of 40-42% were observed after the addition of 600 mM H(2)O(2) and 10 mM dissolved iron. Significantly enhanced destruction resulted during application of N-(2-hydroxyethyl) iminodiacetic acid (HEIDA) to Warsaw soil. For example, in the absence of HEIDA in Warsaw soil, 36% PCE loss and 33% Cl(-) release were observed at 600 mM H(2)O(2) and 5 mM Fe(III), while 74% PCE loss and 63% Cl(-) release were achieved at 600 mM H(2)O(2) and 5 mM Fe(III)-HEIDA. For both soils, the catalytic activities of Fe(II) and Fe(III) were nearly equivalent. These findings clearly demonstrate that system design can be optimized with regard to process variables in Fenton's treatment of DNAPL in soils. 相似文献
878.
在实验室条件下,研究了Shewanella oneidensis MR-1对磺胺甲噁唑(Sulfamethoxazole,SMX)的降解特性以及低分子有机酸强化Fe(Ⅲ)还原介导的S.oneidensis MR-1对SMX的降解.结果表明,S.oneidensis MR-1对不同浓度SMX的降解能力与体系中的有机酸和Fe(Ⅲ)密切相关.低浓度SMX对其生长影响不大,高浓度时细菌生长则受到抑制,进而抑制SMX的降解率.当低分子有机酸单独加入体系后,S.oneidensis MR-1对SMX的最大降解率为58.5%;Fe(Ⅲ)单独加入体系后,S.oneidensis MR-1对SMX的最大降解率为67.6%.此外,当柠檬酸和Fe(OH)3同时加入体系后,S.oneidensis MR-1对SMX生物降解和铁还原作用促进效果最显著,培养5 d后SMX降解率为90.3%.最后,采用液相色谱-质谱联用仪(LC-MS)对SMX的降解中间产物进行了分析,推测SMX的可能降解途径是由S-N键断裂引起的.本研究以期为地下水污染场地修复提供理论依据. 相似文献
879.
Kang XIAO Ying XU Shuai LIANG Ting LEI Jianyu SUN Xianghua WEN Hongxun ZHANG Chunsheng CHEN Xia HUANG 《Frontiers of Environmental Science & Engineering》2014,8(6):805-819
China has been the forerunner of large-scale membrane bioreactor (MBR) application. Since the first large-scale MBR (≥ 10 000 m^3·d^-1) was put into operation in 2006, the engineering implementation of MBR in China has attained tremendous development. This paper outlines the commercial application of MBR since 2006 and provides a variety of engineering statistical data, covering the fields of municipal wastewater, industrial wastewater, and polluted surface water treatment. The total treatment capacity of MBRs reached 1× 10^6 m^3·d^-1 in 2010, and has currently exceeded 4.5 × 10^6 m^3·d^-1 with -75% of which pertaining to municipal wastewater treatment. The anaerobic/anoxic/aerobie-MBR and its derivative processes have been the most popular in the large-scale municipal application, with the process features and typical ranges of parameters also presented in this paper. For the treatment of various types of industrial wastewater, the configurations of the MBR-based processes are delineated with representative engineering cases. In view of the significance of the cost issue, statistics of capital and operating costs are also provided, including cost structure and energy composition. With continuous stimulation from the environmental stress, political propulsion, and market demand in China, the total treatment capacity is expected to reach 7.5 × 10^6 m^3·d^-1 by 2015 and a further expansion of the market is foreseeable in the next five years. However, MBR application is facing several challenges, such as the relatively high energy consumption. Judging MBR features and seeking suitable application areas should be of importance for the long-term development of this technology. 相似文献
880.
John Ibhagbemien Anetor Hideki Wanibuchi Min Wei Anna Kakehsshi Jin Seok Kang 《毒物与环境化学》2013,95(7):1339-1351
There is a dearth of data on the initiation activity of dimethylarsinic acid (DMA (V)), a major metabolite of the ubiquitous environmental and occupational carcinogen and toxicant, arsenic (As). The initiation activity of DMA (V) was investigated on rat hepatocarcinogenesis with liver being a major target organ for As-induced carcinogenicity. A total of 50 rats at 10 weeks old were randomly divided in a nine-week medium-term bioassay into four groups. Groups 1 and 2 received 200 ppm of DMA (V) in drinking water for four weeks while groups 3 and 4 drank only tap water until the sixth week when groups 1 and 3 were given 0.01% 2-acetylaminofluorene (2-AAF) in their diet for two weeks in the promotion stage. All animals were subjected to two-third partial hepatectomy (PH) at the seventh week. Quantitative analysis of glutathione S-transferase placental form (GST-P) positive foci in liver, a pre-neoplastic marker of rat hepatocarcinogenesis, demonstrated higher numbers in group 1 (DMA (V) + 2-AAF) than 3 (2-AAF alone) at foci consisting of two–four cells and 15 or a greater number of cells. The numbers of GST-P positive foci consisting of five–nine cells were significantly higher in group 1 than 3. Foci consisting of 10–14 cells were also higher but not significantly different. The GST-P positive foci were apparently similar in groups 2 and 4. Expression of total GST-P positive foci was significantly higher in group 1 compared to 2, 3 or 4. The proliferating cell nuclear antigen (PCNA) test performed to clarify the apparent trend of GST-P data revealed significantly higher PCNA index in group 1. Data indicate weak initiation potential of DMA (V) and for the first time appear to provide evidence for initiation activity in DMA (V)-induced hepatocarcinogenesis in rats. 相似文献