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11.
A.A.L. Oiffer J.F. Barker F.M. Gervais K.U. Mayer C.J. Ptacek D.L. Rudolph 《Journal of contaminant hydrology》2009,108(3-4):89-106
An anaerobic plume of process-affected groundwater was characterized in a shallow sand aquifer adjacent to an oil sands tailings impoundment. Based on biological oxygen demand measurements, the reductive capacity of the plume is considered minimal. Major dissolved components associated with the plume include HCO3, Na, Cl, SO4, and naphthenic acids (NAs). Quantitative and qualitative NA analyses were performed on groundwater samples to investigate NA fate and transport in the subsurface. Despite subsurface residence times exceeding 20 years, significant attenuation of NAs by biodegradation was not observed based on screening techniques developed at the time of the investigation. Relative to conservative tracers (i.e., Cl), overall NA attenuation in the subsurface is limited, which is consistent with batch sorption and microcosm studies performed by other authors. Insignificant biological oxygen demand and low concentrations of dissolved As (< 10 µg L− 1) in the plume suggest that the potential for secondary trace metal release, specifically As, via reductive dissolution reactions driven by ingress of process-affected water is minimal. It is also possible that readily leachable As is not present in significant quantities within the sediments of the study area. Thus, for similar plumes of process-affected groundwater in shallow sand aquifers which may occur as oil sands mining expands, a reasonable expectation is for NA persistence, but minimal trace metal mobilization. 相似文献
12.
Male corn earworm moths, Helicoverpa zea (Boddie), were captured in conical Texas pheromone traps (cone traps) and bucket traps baited with four different commercial lures manufactured by three different manufacturers. Because significant numbers were captured in bucket traps baited with some of the lures, and none with others, the volatile emissions from all of the lures were sampled and analyzed by gas chromatographic methods. The numbers of males captured in two types of trap were compared with bait emissions in an endeavor to define a more effective lure for bucket traps. The lure from one manufacturer captured the same numbers of males in both trap types; one captured more in bucket traps than in cone traps, and another captured only a small number in bucket traps. The emission rate of all active compounds from each of the different lures was approximately linear for the duration of the assays. A gas-liquid chromatographic peak associated with a third compound, (Z)-9-tetradecenal, which reduces behavioral responses, was observed in the emissions from all lures evaluated. The effectiveness of the Hercon (Emmigsville, PA) lure in capturing males in both types of trap was associated with a lower emission of (Z)-11-hexadecenal, (Z)-9-hexadecenal and (Z)-9-tetradecenal than from the other lures. 相似文献
13.
John W. Hanna Steven F. Philipp Gary W. Mullins 《Journal of the American Water Resources Association》1978,14(1):179-189
Abstract: Opportunities for the development of an amalgam of park and leisure-oriented commercial establishments in urban-core waterfont settings exist in many U.S. cities. Public awareness of the need to enhance the environmental quality of these waterfont areas has resulted in a demand for planning and implementation action. However, the lack of understanding of urban political systems has been an inhibiting factor in the development of this park/ business concept. The major factors that influence the decision-making process leading to the development of urban-core waterfronts for park/business use are identified inthis paper. Understanding this decision-making process can aid project implementation and avoid waste of planning effort in time, dollars, and productivity. 相似文献
14.
Abstract Male corn earworm moths, Helicoverpa zea (Boddie), were captured in conical Texas pheromone traps (cone traps) and bucket traps baited with four different commercial lures manufactured by three different manufacturers. Because significant numbers were captured in bucket traps baited with some of the lures, and none with others, the volatile emissions from all of the lures were sampled and analyzed by gas Chromatographic methods. The numbers of males captured in two types of trap were compared with bait emissions in an endeavor to define a more effective lure for bucket traps. The lure from one manufacturer captured the same numbers of males in both trap types; one captured more in bucket traps than in cone traps, and another captured only a small number in bucket traps. The emission rate of all active compounds from each of the different lures was approximately linear for the duration of the assays. A gas‐liquid Chromatographic peak associated with a third compound, (Z)‐9‐tetradecenal, which reduces behavioral responses, was observed in the emissions from all lures evaluated. The effectiveness of the Hercon (Emmigsville, PA) lure in capturing males in both types of trap was associated with a lower emission of (Z)‐l 1‐hexadecenal, (Z)‐9‐hexadecenal and (Z)‐9‐tetradecenal than from the other lures. 相似文献
15.
Steffi Mayer Philipp Klaritsch Scott Petersen Elisa Done Inga Sandaite Holger Till Filip Claus Jan A. Deprest 《黑龙江环境通报》2011,31(11):1086-1096
16.
K. Håkan Olsén J. Torbjörn Järvi Ian Mayer Erik Petersson Frederieke Kroon 《Chemoecology》1998,8(1):9-17
Summary. In the present experiment the behaviour and endocrine status of males of the brown trout, Salmo trutta L., (Salmoniformes: Salmonidae) were studied when males were kept in a stream tank with a nest digging female. Groups of
mature adult males and precocious intact or anosmic male parr were placed with the nesting female so that the group resembled
a natural spawning situation with big anadromous fish acting as dominant males and precocious parr acting as “sneakers”. A
control experiment was also run with only males without a female present. In intact parr there were significant positive correlations
between the per cent of the total observation time spent with a female, milt volume, and plasma concentration of 17α, 20β-dihydroxy-4-pregnen-3-one.
Anosmic parr had significantly lower volumes of strippable milt and gonadal steroid hormone levels compared with intact parr.
However, no differences were found in the control experiment. Significantly fewer anosmic parr attended and courted the nesting
female and those anosmic fish that attended the female had significantly lower plasma levels of gonadal hormones. Intact parr
also displayed a greater number of agonistic acts against other parr without any difference in fighting ability. No differences
in aggression occured in the control experiment. In adult males together with a female, post-experimental gonadal steroid
hormone levels were higher than pre-experimental levels. Positive correlations between aggression and androgen hormone levels
were observed in adult males. No differences in plasma hormone levels were observed between adult males and intact precocious
males. The results show that olfactory occlusion results in low steroid hormone levels and milt volumes in precocious males
placed in a spawning situation. The courting behaviour was also affected by anosmia. Odours from the nesting female may have
caused the enhanced plasma hormone levels and stimulated the males to attend the female.
Received 15 May 1997; accepted 29 June 1997. 相似文献
17.
Mayer T Bennie D Rosa F Rekas G Palabrica V Schachtschneider J 《Environmental pollution (Barking, Essex : 1987)》2007,147(3):683-690
Occurrence and fate of alkylphenols (APs), known endocrine disruptors, were investigated in a Great Lakes coastal wetland, Cootes Paradise, ON. The wetland, which receives discharges from a Wastewater Treatment Plant (WTP) and several Combined Sewer Overflows (CSOs), is an important spawning ground for fish and crucial habitat for other fauna. Elevated concentrations of nonylphenol ethoxylates (NPEs) and their degradation product nonylphenol (NP) were found in water and sediment samples near the sources. Since transfer of APs through the food chain is of concern, we compared their concentrations in invertebrates from clean and contaminated sites. The results reveal transfer of alkylphenolics from sediments to biota and their accumulation in the invertebrate tissue, particularly the highly hydrophobic 4-NP, whose concentrations ranged from 1.9 to 6.3 microg g(-1). To our knowledge, this is the first study to evaluate AP concentrations in tissue of benthic invertebrates under real environmental conditions. 相似文献
18.
Identification of key parameters controlling dissolved oxygen migration and attenuation in fractured crystalline rocks 总被引:1,自引:0,他引:1
In the crystalline rocks of the Canadian Shield, geochemical conditions are currently reducing at depths of 500-1000 m. However, during future glacial periods, altered hydrologic conditions could potentially result in enhanced recharge of glacial melt water containing a relatively high concentration of dissolved oxygen (O2). It is therefore of interest to investigate the physical and geochemical processes, including naturally-occurring redox reactions, that may control O2 ingress. In this study, the reactive transport code MIN3P is used in combination with 2k factorial analyses to identify the most important parameters controlling oxygen migration and attenuation in fractured crystalline rocks. Scenarios considered are based on simplified conceptual models that include a single vertical fracture, or a fracture zone, contained within a rock matrix that extends from the ground surface to a depth of 500 m. Consistent with field observations, Fe(II)-bearing minerals are present in the fractures (i.e. chlorite) and the rock matrix (biotite and small quantities of pyrite). For the parameter ranges investigated, results indicate that for the single fracture case, the most influential factors controlling dissolved O2 ingress are flow velocity in the fracture, fracture aperture, and the biotite reaction rate in the rock matrix. The most important parameters for the fracture zone simulations are flow velocity in the individual fractures, pO2 in the recharge water, biotite reaction rate, and to a lesser degree the abundance and reactivity of chlorite in the fracture zone, and the fracture zone width. These parameters should therefore receive increased consideration during site characterization, and in the formulation of site-specific models intended to predict O2 behavior in crystalline rocks. 相似文献
19.
20.
Melanie D. Harrison Andrew J. Miller Peter M. Groffman Paul M. Mayer Sujay S. Kaushal 《Journal of the American Water Resources Association》2014,50(6):1365-1382
Although wetlands are known to be sinks for nitrogen (N) and phosphorus (P), their function in urban watersheds remains unclear. We analyzed water and nitrate (NO3?) and phosphate (PO43?) dynamics during precipitation events in two oxbow wetlands that were created during geomorphic stream restoration in Baltimore County, Maryland that varied in the nature and extent of connectivity to the adjacent stream. Oxbow 1 (Ox1) received 1.6‐4.2% and Oxbow 2 (Ox2) received 4.2‐7.4% of cumulative streamflow during storm events from subsurface seepage (Ox1) and surface flow (Ox2). The retention time of incoming stormwater ranged from 0.2 to 6.7 days in Ox1 and 1.8 to 4.3 days in Ox2. Retention rates in the wetlands ranged from 0.25 to 2.74 g N/m2/day in Ox1 and 0.29 to 1.94 g N/m2/day in Ox2. Percent retention of the NO3?‐N load that entered the wetlands during the storm events ranged from 64 to 87% and 23 to 26%, in Ox1 and Ox2, respectively. During all four storm events, Ox1 and Ox2 were a small net source of dissolved PO43? to the adjacent stream (i.e., more P exited than entered the wetland), releasing P at a rate of 0.23‐20.83 mg P/m2/day and 3.43‐24.84 mg P/m2/day, respectively. N and P removal efficiency of the oxbows were regulated by hydrologic connectivity, hydraulic loading, and retention time. Incidental oxbow wetlands have potential to receive urban stream and storm flow and to be significant N sinks, but they may be sources of P in urban watersheds. 相似文献