Correction to: Trace elements in surface sediments of the Hooghly (Ganges) estuary: distribution and contamination risk assessment

Environmental Geochemistry and Health - Unfortunately, in the original publication of the article, Prof. Yong Sik Ok’s affiliation was incorrectly published. The author’s affiliation is...     

Spatial distribution of organic geochemical record in the core sediments along the prominent zones of Central Kerala,India

The study investigated the origin, quality, composition, and trophic state of sedimentary organic matter (SOM) in core samples collected from three zones (Munambam, Vypin, Chettuva) of Central Kerala, India. The SOM exhibited enhanced levels for carbohydrate (CHO) followed by protein (PRT) and lipid (LPD); and phytopigment in the sediment followed the trend: Pheophytin (Pheo) > Carotenoid (carotend) > Chlorophyll-a (Chl-a) > Chlorophyll-b (Chl-b) > Chlorophyll-c (Chl-c). The low PRT: CHO ratio indicated a large amount of nonliving or aged organic matter in the sedimentary environment. Whereas the low Chl-a: Pheo ratio interprets the abundance of dead plant materials in the sediments. Correlation matrix showed strong association between organic matter and clay fraction of sediment. Furthermore, the strong interrelationships between biochemical components and chloropigments in all the zones suggested that SOM is strictly connected to phytodetritus deposition. Vypin zone near Vallarpadam Container Terminal revealed the presence of high biopolymeric carbon content. Besides, the PRT: CHO > 1 reflected the eutrophic condition at the same site but the low PRT: CHO ratio in the remaining stations displays the oligotrophic nature.     

Severity of motorcycle crashes in Dar es Salaam,Tanzania

Objective: Motorcycles are a common mode of transportation in low- and middle-income countries. Tanzania, in particular, has experienced an increased use of motorcycles in the last decade. In Dar es Salaam, motorcycles provide door-to-door travel and often operate where more conventional services are uneconomical or physically impossible to maneuver. Although motorcycles play a crucial role in improving mobility in the city, they have several safety issues. This study focuses on identifying factors influencing the severity of motorcycle crashes.

Method: A multinomial logit analysis was conducted to identify factors influencing the severity of motorcycle crashes in Dar es Salaam, Tanzania. The severity categories were fatal, severe injury, minor injury, and property damage only (PDO). The analysis was based on a total of 784 motorcycle crashes that occurred from 2013 to 2016.

Results: The following factors were found to increase the probability of a fatality: Speeding, driving under the influence, head-on impact, presence of horizontal curves, reckless riding, off-peak hours, violations, and riding without a helmet. The results indicate that crashes occurring on weekdays, during peak hours, at intersections, involving a rear-end impact, in daylight, on street roads, and under clear weather conditions decrease the probability of a fatality. However, minor injury and PDO crashes were found to be associated with crashes occurring during peak hours, at intersections, and on street roads, as well as failure to yield right-of-way.

Conclusions: Several countermeasures are recommended based on the study findings. The recommended countermeasures focus on the holistic safety improvement strategies constituting the three Es of highway safety, namely, engineering, education, and enforcement.     

Magnitude of anthropogenic phosphorus storage in the agricultural production and the waste management systems at the regional and country scales

Based on a systematic review of 17 recent substance flow analyses of phosphorus (P) at the regional and country scales, this study presents an assessment of the magnitude of anthropogenic P storage in the agricultural production and the waste management systems to identify the potential for minimizing unnecessary P storage to reduce the input of P as mineral fertilizer and the loss of P. The assessment indicates that in case of all (6) P flow analyses at the regional scale, the combined mass of annual P storage in the agricultural production and the waste management systems is greater than 50 % of the mass of annual P inflow as mineral fertilizer in the agricultural production system, while this is close to or more than 100 % in case of half of these analyses. At the country scale, in case of the majority (7 out of 11) of analyses, the combined mass of annual P storage in the agricultural production and the waste management systems has been found to be roughly equivalent or greater than 100 % of the mass of annual P inflow as mineral fertilizer in the agricultural production system, while it ranged from 30 to 60 % in the remaining analyses. A simple scenario analysis has revealed that the annual storage of P in this manner over 100 years could result in the accumulation of a massive amount of P in the agricultural production and the waste management systems at both the regional and country scales. This study suggests that sustainable P management initiatives at the regional and country scales should put more emphasis on minimizing unwanted P storage in the agricultural production and the waste management systems.     

Nanotechnology in cosmetics: a boon or bane?

Recent advances in the field of nanotechnology enabled the manufacturing of elaborated nanometer-sized particles for various biomedical applications. The cosmetic industry is one of the most enthusiastic early adopters of nanotechnology which routinely uses nano-scale ingredients. However, in the absence of mandatory product labeling, it is difficult to estimate the number of cosmetics, sunscreens and personal care products containing nanoparticles that are now commercially available. The increased capacity of nanoparticles to penetrate skin and gain access to human cells is a double-edged sword as it may be useful for medical purposes, but might also result in far greater uptake of substances that exert adverse health effects. Since nanomaterials represent a large group of structurally, physically, and chemically variable substances, specific toxicological studies are required for each product prior to commercialization. This review aims to delineate the most investigated applications, risk and safety considerations, and regulation of nanotechnology in the field of cosmetics.     

Chromium toxicity and tolerance in plants

Chromium (Cr) is the second most common metal contaminant in ground water, soil, and sediments due to its wide industrial application, hence posing a serious environmental concern. Among various valence states, Cr(III) and Cr(VI) are the most stable forms. Cr(VI) is the most persistent in the soil and is highly toxic for biota. Since Cr is a non-essential element for plants, there is no uptake mechanism; Cr is taken up along essential elements such as sulfate through sulfate transporters. Cr accumulation in plants causes high toxicity in terms of reduction in growth and biomass accumulation, and Cr induces structural alterations. Cr interferes with photosynthetic and respiration processes, and water and minerals uptake mechanism. Various enzymatic activities related to starch and nitrogen metabolism are decreased by Cr toxicity either by direct interference with the enzymes or through the production of reactive oxygen species. Cr causes oxidative damage by destruction of membrane lipids and DNA damage. Cr may even cause the death of plant species. Few plant species are able to accumulate high amount of Cr without being damaged. Such Cr-tolerant, hyperaccumulator plants are exploited for their bioremediation property. The present review discusses Cr availability in the environment, Cr transfer to biota, toxicity issues, effect on germination and plant growth, morphological and ultrastructural aberrations, biochemical and physiological alterations, effect on metabolic processes, Cr-induced alterations at the molecular level, Cr hyperaccumulation and Cr detoxification mechanism, and the role of arbuscular mycorrhizae in Cr toxicity, in plants.     

Safety performance evaluation of cable median barriers on freeways in Florida

Objective: This article aims to evaluate the safety performance of cable median barriers on freeways in Florida.

Method: The safety performance evaluation was based on the percentages of barrier and median crossovers by vehicle type, crash severity, and cable median barrier type (Trinity Cable Safety System [CASS] and Gibraltar system). Twenty-three locations with cable median barriers totaling about 101 miles were identified. Police reports of 6,524 crashes from years 2005–2010 at these locations were reviewed to verify and obtain detailed crash information. A total of 549 crashes were determined to be barrier related (i.e., crashes involving vehicles hitting the cable median barrier) and were reviewed in further detail to identify crossover crashes and the manner in which the vehicles crossed the barriers; that is, by either overriding, underriding, or penetrating the barriers.

Results: Overall, 2.6% of vehicles that hit the cable median barrier crossed the median and traversed into the opposite travel lane. Overall, 98.1% of cars and 95.5% of light trucks that hit the barrier were prevented from crossing the median. In other words, 1.9% of cars and 4.5% of light trucks that hit the barrier had crossed the median and encroached on the opposite travel lanes. There is no significant difference in the performance of cable median barrier for cars versus light trucks in terms of crossover crashes. In terms of severity, overrides were more severe compared to underrides and penetrations. The statistics showed that the CASS and Gibraltar systems performed similarly in terms of crossover crashes. However, the Gibraltar system experienced a higher proportion of penetrations compared to the CASS system. The CASS system resulted in a slightly higher percentage of moderate and minor injury crashes compared to the Gibraltar system.

Conclusions: Cable median barriers are successful in preventing median crossover crashes; 97.4% of the cable median barrier crashes were prevented from crossing over the median. Of all of the vehicles that hit the barrier, 83.6% were either redirected or contained by the cable barrier system. Barrier crossover crashes were found to be more severe compared to barrier noncrossover crashes. In addition, overrides were found to be more severe compared to underrides and penetrations.     

Predicting adsorptive removal of chlorophenol from aqueous solution using artificial intelligence based modeling approaches

The research aims to develop artificial intelligence (AI)-based model to predict the adsorptive removal of 2-chlorophenol (CP) in aqueous solution by coconut shell carbon (CSC) using four operational variables (pH of solution, adsorbate concentration, temperature, and contact time), and to investigate their effects on the adsorption process. Accordingly, based on a factorial design, 640 batch experiments were conducted. Nonlinearities in experimental data were checked using Brock–Dechert–Scheimkman (BDS) statistics. Five nonlinear models were constructed to predict the adsorptive removal of CP in aqueous solution by CSC using four variables as input. Performances of the constructed models were evaluated and compared using statistical criteria. BDS statistics revealed strong nonlinearity in experimental data. Performance of all the models constructed here was satisfactory. Radial basis function network (RBFN) and multilayer perceptron network (MLPN) models performed better than generalized regression neural network, support vector machines, and gene expression programming models. Sensitivity analysis revealed that the contact time had highest effect on adsorption followed by the solution pH, temperature, and CP concentration. The study concluded that all the models constructed here were capable of capturing the nonlinearity in data. A better generalization and predictive performance of RBFN and MLPN models suggested that these can be used to predict the adsorption of CP in aqueous solution using CSC.     

Applying Fuzzy logic and the point count system to select landfill sites

The treatment of solid waste is currently one of the major environmental problems facing municipalities. Thousands of tonnes of waste are generated each day, requiring a large area for disposal purposes. It is difficult to find suitable areas for the construction of such sanitary landfills as numerous criteria must be met, and landfill sites vary considerably in terms of their sophistication. The selection criteria for landfill sites should be as simple as possible, and with this in mind, we have evaluated a large number of random cases for the suitability of the site for landfill purposes using the recently advocated fuzzy approach. Using the fuzzy classification, we have attempted to develop a simple classification which uses only certain point values for available attributes. A normalized average of such attributes based on the proposed classifier is further evaluated using additionally generated random data sets. The results appear to be encouraging and indicate that the present classifier can be used as a substitute for the fuzzy-based ranking of landfill sites.     

Occurrence of pharmaceuticals in urban wastewater of north Indian cities and risk assessment

Six pharmaceuticals of different categories, such as nonsteroidal anti-inflammatory drugs (ibuprofen, ketoprofen, naproxen, diclofenac), anti-epileptic (carbamazepine), and anti-microbial (trimethoprim), were investigated in wastewater of the urban areas of Ghaziabad and Lucknow, India. Samples were concentrated by solid phase extraction (SPE) and determined by high-performance liquid chromatography (HPLC) methods. The SPE-HPLC method was validated according to the International Conference on Harmonization guidelines. All the six drugs were detected in wastewater of Ghaziabad, whereas naproxen was not detected in Lucknow wastewater. Results suggest that levels of these detected drugs were relatively higher in Ghaziabad as compared to those in Lucknow, and diclofenac was the most frequently detected drug in both the study areas. Detection of these drugs in wastewater reflects the importance of wastewater inputs as a source of pharmaceuticals. In terms of the regional distribution of compounds in wastewater of two cities, higher spatial variations (coefficient of variation 112.90–459.44 %) were found in the Lucknow wastewater due to poor water exchange ability. In contrast, lower spatial variation (162.38–303.77 %) was observed in Ghaziabad. Statistical analysis results suggest that both data were highly skewed, and populations in two study areas were significantly different (p?NSAIDs) posed high (RQ >1) risk to all the test species. The present study would contribute to the formulation of guidelines for regulation of such emerging pharmaceutical contaminants in the environment.