流动注射分光光度法测定水中铝的含量

以桑色素作显色剂，采用流动注射分光光度法测定水中铝的含量。在桑色素质量浓度为0．8g／L、聚氧乙烯辛基苯基醚体积分数为1．0％、进样环体积为400μL、检测波长420nm的条件下，采用流动注射分光光度法对水中铝的含量进行测定，本方法的线性范围为2～300μg／L，检出限（信噪比为3）为0．124μg／L，相对标准偏差为2．9％，加标回收率为96．4％～101．8％。     

风暴潮洪水风险图制作研究

在对洪水灾害风险图进行研究和归纳的基础上,根据上海市的地形、沿海提防、洪涝灾害等特点,分析了上海市风暴潮洪水灾害的成因,以及这些因素与洪灾危险程度间的相关关系。借助模糊数学方法,求出危险程度隶属度。在地理信息系统平台上,采用多边形叠置分析和聚类分析等手段,研究洪水灾害危险程度区划的方法,进而绘制成洪水风险图。风险的评估采用了多指标综合评估方法,不仅计算了洪水的自然风险,同时考虑了防洪工程风险的影响。     

我国农业自然灾害与农业政策性保险

在详细分析了我国当前主要农业自然灾害情况的基础上,探讨了通过建立农业政策性保险来应对自然灾害风险的必要性以及我国农业保险目前面临的问题,提出了加大政府支持力度、加快农业保险立法、提高保险意识、加强保险人才培养等方面的政策建议。     

Highly selective capture of phosphate ions from water by a water stable metal-organic framework modified with polyethyleneimine

Environmental Science and Pollution Research - In this work, a series of polyethyleneimine (PEI) impregnated metal-organic framework (UiO-66) with varying PEI loadings were prepared and applied as...     

Growth responses of the newly-discovered Cd-hyperaccumulator Rorippa globosa and its accumulation characteristics of Cd and As under joint stress of Cd and As

Rorippa globosa has been identified as a newly-found Cd-hyperaccumulating species. In the present study, growth responses of Rorippa globosa and its accumulation characteristics of Cd and As were examined under joint stress of Cd and As. The results showed that Cd and As had an antagonistic effect on enhancing the growth of Rorippa globosa plants and Cd uptake and accumulation under the low concentration Cd and As treatments. When the concentration of Cd in the soil was 10 mg/kg and the concentration of As was 50 mg/kg, the highest growing height of the plant was up to 35.9 cm and the dry weight of the shoots was up to 2.2 g/pot, respectively. Meanwhile, the accumulation of Cd in the leaves under the joint stress was higher than that at the same level under single Cd pollution. However, there were synergic adverse effects on plant growth and Cd uptake under the combined pollution from a high concentration of Cd and As. Meanwhile, the accumulation of As in the roots was greater than that in the shoots, the translocation factor (TF) was ?0.3 and the bioaccumulation factor (BF) was ?0.6, thus showing that Rorippa globosa had an excluding effect on As uptake. These results confirmed that Rorippa globosa had a strong tolerant ability to the joint stress of Cd and As, and the potential for phytoremediation of soils contaminated by Cd and As.     

Heavy metals and their source identification in particulate matter (PM2.5) in Isfahan City, Iran

The presence of heavy metals(HMs) in particulate matters(PMs) particularly fine particles such as PM_(2.5) poses potential risk to the health of human being. The purpose of this study was to analyze the contents of HMs in PM_(2.5) in the atmospheric monitoring stations in Isfahan city,Iran, in different seasons between March 2014 and March 2015 and their source identification using principle component analysis(PCA). The samples of PM_(2.5) were taken using a high volume sampler in 7 monitoring stations located throughout the city and industrial zones since March 2014 to March 2015. The HMs content of the samples was measured using ICP-MS.The results showed that the concentrations of As, Cd and Ni were in a range of 23–36, 1–12,and 5–76 ng/m~3 at all the stations which exceeded the US-EPA standards. Furthermore,the concentrations of Cr and Cu reached to 153 and 167 ng/m~3 in some stations which were also higher than the standard levels. Depending on the potential sources of HMs, their concentration in PM_(2.5) through the various seasons was different. PCA illustrated that the different potential sources of HMs in the atmosphere, showing that the most important sources of HMs originated from fossil fuel combustion, abrasion of vehicle tires, industrial activities(e.g., iron and steel industries) and dust storms. Management and control of air pollution of industrial plants and vehicles are suggested for decreasing the risk of the HMs in the region.     

Effective removal of coordinated copper from wastewater using a new dithiocarbamate-type supramolecular heavy metal precipitant

A new dithiocarbamate-type heavy metal precipitant, sodium 1,3,5-hexahydrotriazinedithiocarbamate (HTDC), was prepared and used to remove coordinated copper from wastewater. In the reported dithiocarbamate-type precipitants, HTDC possesses the highest percentage of the effective functional groups. It could effectively precipitate copper to less than 0.5 mg l⁻¹ from both synthetic and actual industrial wastewater containing CuEDTA in the range of pH 3–9. UV–vis spectral investigation and elemental analysis suggested that the precipitate was a kind of coordination supramolecular compound, [Cu₃(HTDC)₂]_n. The toxicity characteristic leaching procedure (TCLP) and semi-dynamic leaching test (SDLT) indicated that the supramolecular precipitate was non-hazardous and stable in weak acid and alkaline conditions. Tests of an anion exchange resin D231 provided a clue to simultaneously remove excess HTDC and residual CuEDTA in practical process of wastewater treatment.     

紫外分光光度法在水中阴离子表面活性剂标准样品研制中的应用

研究了阴离子表面活性剂水溶液的紫外吸收特性，并将研究结果用于阴离子表面活性剂水质标样的稳定性，均匀性和定值工作，简化了操作手续，获得了准确的分析结果。