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991.
Jie Xia Guanyong Su Xiaowei Zhang Wei Shi John P. Giesy Hongxia Yu 《Environmental science and pollution research international》2014,21(2):1480-1488
Deterioration of the general ecosystem and specifically quality of the water in Tai Lake (Ch: Taihu), the third largest freshwater in China, is of great concern. However, knowledge on status and trends of dioxin-like compounds in Tai Lake was limited. This study investigated AhR-mediated potency and quantified potential aryl hydrocarbon receptor (AhR) agonists in sediments from four regions (Meiliang Bay, Zhushan Lake, Lake Center, Corner of Zhushan Lake, and Meiliang Bay) of Tai Lake by use of the in vitro H4IIE-luc, cell-based, transactivation, reporter gene assay, and instrumental analysis. Concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (Bio-TEQs) in sediments ranged from less than the limit of detection to 114.5 pg/g, dry weight, which indicated that organic extracts of sediments exhibited significant AhR-mediated potencies. Results of the potency balance analysis demonstrated that acid-labile, dioxin-like compounds represented a greater proportion of concentrations of Bio-TEQs in sediments from Tai Lake. Concentrations of 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents calculated as the sum of the product of concentrations of individual congeners and their respective relative potencies (Chem-TEQs) based on polycyclic aromatic hydrocarbons and/or polychlorinated biphenyls represented no more than 10 % of the total concentrations of Bio-TEQs. 相似文献
992.
Carolina Fernández-Ramos Oscar Ballesteros Alberto Zafra-Gómez Francisco Javier Camino-Sánchez Rosario Blanc Alberto Navalón José Luís Vílchez 《Environmental science and pollution research international》2014,21(6):4286-4296
The study describes the environmental monitoring of anionic surfactants―alcohol sulfates (AS) and alcohol ethoxysulfates (AES)—in marine sediments. Concentration values were obtained after pressurised liquid extraction (PLE) and liquid chromatography–tandem mass spectrometry analysis (LC–MS/MS). Samples were collected from a range of wastewater discharge points along the coast of the provinces of Huelva, Málaga, Granada and Almería. Urban, agricultural and industrial wastewaters are discharged at the selected 38 sampling sites. Principal component analysis was carried out in order to evaluate the distribution and behaviour of these compounds in these coastal environments. Evaluation of the data revealed that the behaviour and sources of AS and AES in marine sediments are different, and that the distribution of AES depends on the length of the alkyl chain, while the number of ethoxylated units is not relevant. Additionally, the 38 sampling sites can be grouped into only two types of outfalls according to their AS distribution. The concentration of compounds in sediment samples ranged from 7.52 to 13.50 mg kg?1 for AS, from 3.04 to 10.68 mg kg?1 for AES–C12Ex and from 3.83 to 11.56 mg kg?1 for AES–C14Ex. 相似文献
993.
Effects of environmental parameters on the oxygen consumption of four marine invertebrates: a comparative factorial study 总被引:1,自引:0,他引:1
The oxygen consumption curves of two decapod crustaceans (Palaemon serratus, Penaeus monodon) and two prosobranch molluscs (Trunculariopsis trunculus, Nassarius mutabilis) have been detected in the entire pO2 interval from 0 to 160 mmHg, under different conditions of temperature and salinity. From the experimental curves, physiological
parameters such as the initial oxygen consumption velocity, the Q
10 values and the oxygen independence indices have been measured. The latter parameters have been obtained using normalised
plots which allow their better evaluation. The effects of temperature, salinity and oxygen partial pressure on the oxygen-consumption
features have been studied using a factorial experimental plan which allows measurement of the effects of each experimental
variable as well as the effects of synergistic interactions between different variables.
Received: 27 March 2000 / Accepted: 13 November 2000 相似文献
994.
Critical review of Integrated Water Resources Management: Moving beyond polarised discourse 总被引:1,自引:0,他引:1
Integrated Water Resource Management (IWRM) emerged as a popular concept in the water sector in the 20th century. From a highly techno-centric approach in the past, it has taken a new turn embracing Habermasian communicative rationality as a place-based nexus for multiple actors to consensually and communicatively integrate decisions in a hydrological unit. The 'how to integrate' approach had remarkable appeal worldwide in promoting authentic participation of all stakeholders. However, critics argue that the domain of water resource management is a political process of contestation and negotiation; the emphasis is on complexities, contextuality, power dynamics and the importance of analysing real world situations. They demonstrate 'how integration cannot be achieved' given the power dynamics in social interactions. These apparently contradictory discourses draw on different theoretical paradigms and polarise the discourse on IWRM, without offering constructive alternatives. To this end, this paper offers an option to complement this polarised discourse by examining 'how integration actually does take place' in a strategic context thereby facilitating consensual decisions to integrate water management for a sustainable future. 相似文献
995.
996.
In this study, an interval-fuzzy two-stage chance-constrained integer programming (IFTCIP) method is developed for supporting
environmental management under uncertainty. The IFTCIP improves upon the existing interval, fuzzy, and two-stage programming
approaches by allowing uncertainties expressed as probability distributions, fuzzy sets, and discrete intervals to be directly
incorporated within a general mixed integer linear programming framework. It has advantages in uncertainty reflection, policy
investigation, risk assessment, and capacity-expansion analysis in comparison to the other optimization methods. Moreover,
it can help examine the risk of violating system constraints and the associated consequences. The developed method is applied
to the planning for facility expansion and waste-flow allocation within a municipal solid waste management system. Violations
of capacity constraints are allowed under a range of significance levels, which reflects tradeoffs between the system cost
and the constraint-violation risk. The results indicate that reasonable solutions for both binary and continuous variables
have been generated under different risk levels. They are useful for generating desired decision alternatives with minimized
system cost and constraint-violation risk under various environmental, economic, and system-reliability conditions. Generally,
willingness to take a higher risk of constraint violation will guarantee a lower system cost; a strong desire to acquire a
lower risk will run into a higher system cost. 相似文献
997.
Urbanization and its impact on groundwater: a remote sensing and GIS-based assessment approach 总被引:1,自引:0,他引:1
The perils of unplanned urbanization and increasing pressure of human activities on hydro-geomorphologic system often result
in modification of the existing recharge mechanism, which leads to many environmental consequences. In the present research,
an attempt has been made to investigate the applicability of remote sensing and geographical information system (GIS) in dealing
with spatial and temporal variability of dynamic phenomena, like urbanization and its impact on groundwater. This paper covers
primarily, quantitative and qualitative impacts of urban growth on the behavior of aquifer in Ajmer city (India). Urban growth
of the Ajmer city in last 17 years has been estimated from the satellite images. Database related to urbanization and groundwater
has been created in GIS. Groundwater recharge has been computed using a water balance approach known as Water Level Fluctuation
Methodology. Recharge estimation methodology has been implemented in GIS to introduce the spatial variability of hydro-geological
characteristics. Further, temporal and spatial variations in groundwater quality and quantity have been correlated with urban
growth using overlay analysis in GIS. The study reveals a general decline in water table and quality with urbanization. Further,
remote sensing and GIS technologies have been found useful in assessment of spatial and temporal phenomena of urbanization
and its impact on groundwater system. 相似文献
998.
A retrospective study on severity analysis of Indian coal mines accidents for 100 years was done considering fatal and serious accidents and the resulting causalities. The impact of recommendations based on safety conferences and committees over the years was studied. An event evaluation algorithm (EEA) was developed for this purpose. The hazard rate functions and cumulative risk functions for major hazards in Indian coal mines were developed. The study evaluated the status of safety level as well as the scope of improvement for Indian coal mines safety. 相似文献
999.
This paper presents an investigation of the mineralogy and pore water chemistry of a boiler ash sampled from a municipal solid waste fluidized-bed incinerator, subject to 18 months of dynamic leaching in a large percolation column experiment. A particular focus is on the redox behaviour of Cr(VI) in relation to metal aluminium Al0, as chromium may represent an environmental or health hazard. The leaching behaviour and interaction between Cr(VI) and Al0 are interpreted on the basis of mineralogical evolutions observed over the 18-month period and of saturation indices calculated with the geochemical code PhreeqC and reviewed thermodynamic data. Results of mineralogical analyses show in particular the alteration of mineral phases during leaching (e.g. quartz and metal aluminium grains), while geochemical calculations suggest equilibria of percolating fluids with respect to specific mineral phases (e.g. monohydrocalcite and aluminium hydroxide). The combination of leaching data on a large scale and mineralogical analyses document the coupled leaching behaviour of aluminium and chromium, with chromium appearing in the pore fluids in its hexavalent and mobile state once metal aluminium is no longer available for chromium reduction. 相似文献
1000.
H. Barndõk M. Peláez C. Han W. E. Platten III P. Campo D. Hermosilla A. Blanco D. D. Dionysiou 《Environmental science and pollution research international》2013,20(6):3582-3591
This study reports the synthesis and characterization of composite nitrogen and fluorine co-doped titanium dioxide (NF-TiO2) for the removal of contaminants of concern in wastewater under visible and solar light. Monodisperse anatase TiO2 nanoparticles of different sizes and Evonik P25 were assembled to immobilized NF-TiO2 by direct incorporation into the sol–gel or by the layer-by-layer technique. The composite films were characterized with X-ray diffraction, high-resolution transmission electron microscopy, environmental scanning electron microscopy, and porosimetry analysis. The photocatalytic degradation of atrazine, carbamazepine, and caffeine was evaluated in a synthetic water solution and in an effluent from a hybrid biological concentrator reactor (BCR). Minor aggregation and improved distribution of monodisperse titania particles was obtained with NF-TiO2-monodisperse (10 and 50 nm) from the layer-by-layer technique than with NF-TiO2?+?monodisperse TiO2 (300 nm) directly incorporated into the sol. The photocatalysts synthesized with the layer-by-layer method achieved significantly higher degradation rates in contrast with NF-TiO2-monodisperse titania (300 nm) and slightly faster values when compared with NF-TiO2-P25. Using NF-TiO2 layer-by-layer with monodisperse TiO2 (50 nm) under solar light irradiation, the respective degradation rates in synthetic water and BCR effluent were 14.6 and 9.5?×?10?3?min?1 for caffeine, 12.5 and 9.0?×?10?3?min?1 for carbamazepine, and 10.9 and 5.8?×?10?3?min?1 for atrazine. These results suggest that the layer-by-layer technique is a promising method for the synthesis of composite TiO2-based films compared to the direct addition of nanoparticles into the sol. 相似文献