Assessment of physicochemical characteristics of Ganga Canal water quality in Uttarakhand

Assessment of physicochemical parameters of Ganga Canal water was carried out during 2012–2013 at Haridwar (Uttarakhand) with two different sites, i.e., Bhimgoda Barrage (site 1—control site) and Bahadrabad (site 2—contaminated site), where canal water flows with loads of pollution from highly commercial and industrial areas. During investigation, maximum turbidity (287.72 ± 56.28 JTU), total solids (1167.60 ± 303.90 mg l^?1), free CO₂ (1.88 ± 0.22 mg l^?1), total hardness (60.14 ± 1.13 mg l^?1), pH (7.1 ± 0.13), nitrate (0.048 ± 0.010), nitrite (0.019 ± 0.001), biochemical oxygen demand (2.866 ± 1.098), chemical oxygen demand (6.8 ± 2.61) and phosphate (0.087 ± 0.015), while minimum velocity (1.71 ± 0.19 ms^?1), transparency (0.12 ± 0.08 m) and dissolved oxygen (7.95 ± 0.44 mg l^?1) were recorded in monsoon season at site 2 in comparison with site 1. The mean values of these parameters were compared with WHO and ISI standards and found significant differences (p < 0.05) in the mean values of turbidity, total solids, pH, dissolved oxygen, free CO₂ and total hardness with sampling sites. The turbidity of both the sites 1 and 2 was recorded above the permissible limit. Turbidity of site 2 is much higher than of site 1, so it is counted as more polluted. The values of the studied parameters were more during monsoon season and summer season at site 2 as compared to site 1. The results indicated that most of the physicochemical parameters from Ganga Canal system were within or at periphery in comparison with permissible limit of ISI and WHO for drinking water and therefore may be suitable for domestic purposes, but it requires perceptible consideration due to intense changes in climate and increase in pollution.     

Application of ameliorated wood pulp to recover Cd(II), Pb(II), and Ni(II) from e-waste

In this study, dl-malic acid and hydrogen peroxide were used as leaching agents to remove metals from e-waste (printed-circuit boards) and itaconic acid-grafted poly(vinyl alcohol)-encapsulated wood pulp (IA-g-PVA-en-WP) to uptake metals from leachate with high proficiency [11.63 mg g^?1; 93.03 % for Cd(II), 11.90 mg g^?1; 95.18 % for Pb(II), and 12.14 mg g^?1; 97.08 % for Ni(II)]. Metals were recovered from the loaded biosorbent by desorption studies. The standard analytical techniques, such as elemental analysis, Fourier-transform-infrared spectroscopy, scanning electron microscopy, atomic force microscopy, and thermogravimetric analysis, were used to characterize the recovering agent (biosorbent). At equilibrium, the metal uptake data were fitted to Langmuir and D–R isotherms (R ² > 0.99) significantly, revealing, the homogeneous distribution of active sites on biosorbent’s backbone. The possible mechanism appeared to be ion exchanges of metal ions with H⁺ together with binding over functionalities (COO^?). Dimensionless equilibrium parameter (R _L) showed the favourability of metal uptake at lower concentration, while mean adsorption energy (E) certified the physical binding of metal on functionalities which was further confirmed by sticking probability and activation energy parameters. Reusability studies were also conducted to state the performance of biosorbent.     

Study of ultrasonic assisted cryogenically cooled EDM process using sintered (Cu–TiC) tooltip

In most EDM operations, the maximum contribution in the total operation cost is the tool cost. Electrode wear is a major problem in EDM process. Therefore, in this paper, the process performance of sintered copper (Cu)–titanium carbide (TiC) electrode tip in ultrasonic assisted cryogenically cooled electrical discharge machining (UACEDM) has been studied. The performance parameters studied in this paper are electrode wear ratio (EWR), material removal rate (MRR), surface roughness (SR), out of roundness and surface integrity. The process parameters considered in this study are discharge current, pulse on time, duty cycle and gap voltage. Cermet was fabricated, having copper content of 75% and titanium carbide content of 25%, by mixing, pressing, and sintering. The performance of the newly formed cermet electrode tip is compared with conventional copper electrode tip for UACEDM process and analyzed. It has been observed that EWR and out of roundness decreases when cermet electrode tip is used as compared to conventional tooltip. It has also been observed that MRR and SR increase when cermet tooltip is used. The surface cracks density and crack width on workpiece machined by cermet tooltip have been found to be lesser as compared to the specimen machined by conventional tooltip.     

Influence of lake morphology on water quality

Lakes are seriously affected due to urban pollution. The study of the morphological features of a lake system helps to identify its environmental status. The objective of the present study is to analyse the influence of morphometry on water quality in a lake (Akkulam-Veli Lake, Thiruvananthapuram, Kerala). The morphological features namely mean depth, surface area, volume, shoreline length, shoreline development and index of basin permanence have been evaluated. Correlation analysis has been conducted to determine the relationship between morphological features and water quality. Regression analysis has been conducted to find out the extent of influence of morphometric features on water quality. The study revealed that the lake is less affected by wind-induced wave action due to various reasons. The depth and volume have significant role in the water quality. The nitrogen fixation of blue green algae can be observed from the morphological features. The morphology has greater role in the water quality of a lake system.     

Trophic state index of a lake system using IRS (P6-LISS III) satellite imagery

Water pollution has now become a major threat to the existence of living beings and water quality monitoring is an effective step towards the restoration of water quality. Lakes are versatile ecosystems and their eutrophication is a serious problem. Carlson Trophic State Index (CTSI) provides an insight into the trophic condition of a lake. CTSI has been modified for the study area and is used in this study. Satellite imagery analysis now plays a prominent role in the quick assessment of water quality in a vast area. This study is an attempt to assess the trophic state index based on secchi disk depth and chlorophyll a of a lake system (Akkulam?CVeli lake, Kerala, India) using Indian Remote Sensing (IRS) P6 LISS III imagery. Field data were collected on the date of the overpass of the satellite. Multiple regression equation is found to yield superior results than the simple regression equations using spectral ratios and radiance from the individual bands, for the prediction of trophic state index from satellite imagery. The trophic state index based on secchi disk depth, derived from the satellite imagery, provides an accurate prediction of the trophic status of the lake. IRS P6-LISS III imagery can be effectively used for the assessment of the trophic condition of a lake system.     

Size distribution and source identification of total suspended particulate matter and associated heavy metals in the urban atmosphere of Delhi

A study of the atmospheric particulate size distribution of total suspended particulate matter (TSPM) and associated heavy metal concentrations has been carried out for the city of Delhi. Urban particles were collected using a five-stage impactor at six sites in three different seasons, viz. winter, summer and monsoon in the year 2001. Five samples from each site in each season were collected. Each sample (filter paper) was extracted with a mixture of nitric acid, hydrochloric acid and hydrofluoric acid. The acid solutions of the samples were analysed in five-particle fractions by atomic absorption spectrometry (AAS). The impactor stage fractionation of particles shows that a major portion of TSPM concentration is in the form of PM0.7 (i.e. <0.7microm). Similarly, the most of the metal mass viz. Mn, Cr, Cd, Pb, Ni, and Fe are also concentrated in the PM0.7 mode. The only exceptions are size distributions pertaining to Cu and Ca. Though, Cu is more in PM0.7 mode, its presence in size intervals 5.4-1.6microm and 1.6-0.7microm is also significant, whilst in case of Ca there is no definite pattern in its distribution with size of particles. The average PM10.9 (i.e. <10.9microm) concentrations are approximately 90.2%+/-4.5%, 81.4%+/-1.4% and 86.4%+/-9.6% of TSPM for winter, summer and monsoon seasons, respectively. Source apportionment reveals that there are two sources of TSPM and PM10.9, while three and four sources were observed for PM1.6 (i.e. <1.6microm) and PM0.7, respectively. Results of regression analyses show definite correlations between PM10.9 and other fine size fractions, suggesting PM10.9 may adequately act as a surrogate for both PM1.6 and PM0.7, while PM1.6 may adequately act as a surrogate for PM0.7.     

Studies on the protein binding mechanism of p-aninodiphenylamine: A hair dye constituent

p-Aminodiphenylamine (p-ADPA) has got a binding capacity with tissue proteins. Aspartic and glutamic acids are presumably the responsible units in the protein chain involved in this binding with p-ADPA. p-ADPA is changed into a quinone structure after atmospheric oxidation in Krebs-Ringer-Bicarbonate buffer, pH 7.4 in the presence of trace metal ions. This oxidised form of p-ADPA binds with aspartic acid at pH 7.4 and temperature 40° in 2 hrs. The derivative thus formed absorbs at 450 nm instead of 430 nm.     

Free radical biology in neurological manifestations: mechanisms to therapeutics interventions

Environmental Science and Pollution Research - Recent advancements and growing attention about free radicals (ROS) and redox signaling enable the scientific fraternity to consider their involvement...