Net ecosystem CO2 exchange over a larch forest in Hokkaido, Japan

Larch forests are distributed extensively in the east Eurasian continent and are expected to play a significant role in the terrestrial ecosystem carbon cycling process. In view of the fact that studies on carbon exchange for this important biome have been very limited, we have initiated a long-term flux observation in a larch forest ecosystem in Hokkaido in northern Japan since 2000. The net ecosystem CO₂ exchange (NEE) showed large seasonal and diurnal variation. Generally, the larch forest ecosystem released CO₂ in nighttime and assimilated CO₂ in daytime during the growing season from May to October. The ecosystem started to become a net carbon sink in May, reaching a maximum carbon uptake as high as 186 g C m⁻² month⁻¹ in June. With the yellowing, senescing and leaf fall, the ecosystem turned into a carbon source in November. During the non-growing season, the larch forest ecosystem became a net source of CO₂, releasing an average of 16.7 g C m⁻² month⁻¹. Overall, the ecosystem sequestered 141–240 g C m⁻² yr⁻¹ in 2001. The NEE was significantly influenced by environmental factors. Respiration of the ecosystem, for example, was exponentially dependent on air temperature, while photosynthesis was related to the incident PAR in a manner consistent with the Michaelis–Menten model. Although the vapor pressure deficit (VPD) was scarcely higher than 15 hPa, the CO₂ uptake rate was also depressed when VPD surpassed 10 hPa.     

Investigation of saponification for determination of polychlorinated biphenyls in marine sediments

The effects of saponification conditions (temperature and water content of saponifying solution) on the determination of chlorinated biphenyls (CBs) in marine sediments were investigated. Although highly chlorinated biphenyls (nona- to deca-CBs) decomposed during high-temperature saponification, the degree of degradation was reduced by adding water to the ethanolic potassium hydroxide saponifying solution. Room-temperature saponification yielded quantitative recovery of highly chlorinated biphenyl surrogates but low extraction efficiencies of lightly chlorinated biphenyls (mono- to di-CBs). The same samples were analyzed by other extraction techniques, for example, pressurized liquid extraction, and analytical results were compared. The mono- and di-CB concentrations were correlated with the extraction temperatures of various extraction techniques. In particular, the concentrations of some CB congeners (CB11, CB14) were higher with saponification. The low degree of degradation of highly chlorinated biphenyls and the high recovery of lightly chlorinated biphenyls were compatible when room-temperature and high-temperature saponification were combined. Except for the anomalies of CB11 and CB14, the combined method gave satisfactory results for analysis of PCBs.     

Effects of copper chloride on formation of polychlorinated dibenzofurans in model waste incineration in a laboratory-scale fluidized-bed reactor

Combustion experiments in a laboratory-scale fluidized-bed reactor have been performed to clarify the effects of copper chloride as a catalyst on polychlorinated dibenzofurans (PCDFs) formation in municipal waste incineration. We used model wastes with and without copper chloride (CuCl2 x 2H2O) as a catalyst, both of which contained polyvinyl chloride (PVC) as a chlorine source. Combustion temperature was set to 900 degrees C, and the amount of air supplied was twice as much as the theoretical amount. The experimental setup had been carefully planned to ensure avoidance of the influences of previous experiments. Results of these present experiments revealed that copper chloride in the waste increased the amount of PCDFs formed and made the homologue profile shifted towards the highly chlorinated species. Copper chloride contributes to PCDFs formation by promoting chlorination via catalytic reactions, whereby the reaction could be important in that organic matters are chlorinated directly by chlorinated compounds related to Deacon reaction such as copper chloride. It was elucidated that characteristic isomer distribution patterns appeared in case the waste contained copper chloride. It is probable in our experiment with copper chloride that PCDFs are mainly formed via catalytic reactions of copper compounds and carbon.     

Effects of copper chloride on formation of polychlorinated dibenzo-p-dioxins in model waste incineration

Combustion experiments in a laboratory-scale fluidized-bed reactor were conducted to elucidate the effects of copper chloride as a catalyst on polychlorinated dibenzo-p-dioxins (PCDDs) formation in municipal waste incineration. We used model wastes with and without copper chloride (CuCl₂ · 2H₂O), both of which contained polyvinyl chloride as a chlorine source. Combustion temperature was set to 900 °C, and the amount of air supplied was twice the stoichiometric ratio. The experimental setup was carefully planned to suppress the influences of experimental conditions except the waste composition. Results of these experiments showed that copper chloride in the waste increased the amount of PCDDs formed and made the homologue profile to shift towards the highly chlorinated species. Copper chloride contributes to the PCDDs formation by promoting chlorination, whereby the reaction is important in that organic matter is chlorinated directly by copper compounds. Copper chloride did not exert a great influence on the isomer distribution patterns of PCDDs, while there appeared a significant difference in the case of PCDFs. This points out the difference of the major formation mechanisms between PCDDs and PCDFs. PCDDs are less formed by the catalytic reactions from carbon/polycyclic aromatic hydrocarbons than PCDFs in our experimental conditions.     

The Chinese steel industry

The Chinese steel industry achieved even growth in the 1980s and China is now the world's fourth largest steel producing country. Two factors that have played important roles in this development of the Chinese steel industry are the reform of the system or the strengthening of enterprise autonomy accompanying market reform, and the introduction of advanced technology from Western countries as a continuing policy since the 1970s. The Chinese steel industry still lags far behind those of other steel producing countries in terms of equipment and production technology, however. The present situation and problems of the Chinese steel industry in the 1990s are discussed here, together with a review of its development in the 1980s.     

Effects of water depth and litter accumulation on morpho-ecological adaptations of Eleocharis sphacelata

The morpho-ecological adaptations of Eleocharis sphacelata in response to water depth and the sequential effects of resultant differences in deep water conditions on the long term population dynamics were investigated based on the observations carried out in three stable homogeneous populations in Goulburn and Ourimbah, New South Wales, Australia from August 2003 to May 2005. The deep water populations attained a higher harvestable shoot biomass and a lower rhizome biomass with increased growth in root structure thus significantly enhancing the nutrient uptake rates leading to a higher accumulation of shoot bound macronutrients. However, the accretion of excessive amounts of autogenous shoot litter coupled with slower decomposition rates under anaerobic conditions in the two deep water populations led to higher nutrient enrichment in sediments and overlying water column causing subsequent eutrophication with signs of growth inhibition including typical stress symptoms like stunted growth and chlorotic shoots. The shallow water population that intermittently experienced alternative inundation-drawdown pattern depicted an unaffected continuation of seasonal growth affirming that strict water regime management practices coupled with timely mowing or the removal of accumulating litter are necessary to ensure long-term survival of healthy E. sphacelata stands when it is used in applications where deep water conditions prevail.     

Environmental management of pesticidal POPs in China: past, present and future

China, the largest developing country in the world, has been undergoing rapid economic growth in the past two decades. Synchronously, large quantities of persistent organic chlorinated pesticides have been used in agriculture and non-agriculture areas. Accompanying with incomplete management framework, the improper use and disposal of pesticides have caused serious pollution problems. In this study, we discussed: (1) ten persistent organochlorine pesticides in terms of historical production, consumption and number of manufacturers, import and export; (2) the current management framework of pesticidal persistent organic pollutants (POPs) with respect to legal system and government administrative system; (3) the existing problems in the management of pesticidal POPs; and proposed recommendations for countermeasures. Based on the available information, it can be concluded that records on the historical production and consumption quantities of pesticidal POPs are incomplete which makes a difficulty in the management. Although China has come a long way in developing a modern legal system, the current system is still considered weak and inefficient; and many challenges are ahead. The government administrative system has also been reformed and improved, but over-lapping jurisdictions still exist and are ineffective in managing pesticidal POPs program. To address these existing problems in pesticidal POPs management, it was suggested that more investigations should be conducted to collect information on pollution sources of pesticidal POPs, to evaluate their environmental risks, to identify new alternative chemicals and to complete management framework of pesticidal POPs in China. Furthermore, the public should be encouraged to participate in managing hazardous pesticidal POPs in China, and international cooperation and communication should be established and strengthened imperatively as well.     

Mass balance of anti-influenza drugs discharged into the Yodo River system,Japan, under an influenza outbreak

In February 2011, at the peak of an influenza outbreak, we performed a comprehensive analysis of the mass balances of four anti-influenza drugs—oseltamivir (OS), oseltamivir carboxylate (OC), amantadine (AMN), and zanamivir (ZAN)—in the urban area of the Yodo River system. This area includes three main river catchments (the Katsura, Uji, and Kidzu Rivers) and is home to 12 million people, about 10% of Japan’s population. Water was sampled at six main rivers and 13 tributary sites and eight sewage treatment plants (STPs). We concluded that the STP effluents were the major sources of the anti-influenza drug load in the Yodo River system (68–94% of total mass fluxes). Extended measurement throughout the Yodo River system further showed only small fluctuations of the ratio of OS to OC from 0.2 to 0.3, suggesting that OS and its metabolite are environmentally stable. The results also clearly showed the importance of reducing the levels of anti-influenza drugs in the water environment by reducing their emission at STPs.