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21.
de Figueiredo DR Ferreira RV Cerqueira M de Melo TC Pereira MJ Castro BB Correia A 《Environmental monitoring and assessment》2012,184(1):471-485
The information on bacterial community composition (BCC) in Portuguese water bodies is very scarce. Cértima River (central
western Portugal) is known to have high levels of pollution, namely organic. In the present work, the BCC from a set of 16
water samples collected from Cértima River Basin and its main tributaries was characterized using 16S rDNA–denaturing gradient
gel electrophoresis, a culture-independent molecular approach. Molecular data were related to environmental parameters through
multivariate analysis to investigate potential impact of water pollution along the river. Principal component analysis using
environmental data showed a water quality gradient from more pristine waters (at the mountain tributaries) to waters with
increasingly eutrophic potential (such as Fermentelos Lake). This gradient was mainly defined by factors such as organic and
inorganic nutrient sources, electrical conductivity, hydrogen carbonate concentration, and pH. Molecular results showed variations
in BCC along Cértima River Basin but in the main river section, a Bacteroidetes phylotype (Flavobacterium sp.) proved to be dominant throughout the river course. Multivariate analysis suggests that spatial variation of BCC along
the Cértima River Basin depended mainly on parameters such as Chl a, total suspended solid (TSS), total organic carbon, electrical conductivity, and HCO
_boxclose^-_{3}^{-} levels. Bacteroidetes phylotypes were all related to higher electrical conductivity and HCO3-_{3}^{-} levels although some of these were also correlated with high SO42-_{4}^{2-} and others with high soluble reactive phosphorus, nitrate, TN, and Kjeld-N levels. The Gammaproteobacteria occurrence was correlated with high SO42-_{4}^{2-} levels. One of the Betaproteobacteria phylotypes showed to correlate with low redox potential (Eh) and high temperature, pH, TSS, and Chl a levels while another one showed a negative correlation with Chl a values. 相似文献
22.
Tim S. Nawrot Nino Kuenzli Jordi Sunyer Tingming Shi Teresa Moreno Mar Viana Joachim Heinrich Bertil Forsberg Frank J. Kelly Muhammad Sughis Benoit Nemery Paul Borm 《Atmospheric environment (Oxford, England : 1994)》2009,43(30):4595-4602
We assessed the extent to which constituents of PM2.5 (transition metals, sodium, chloride) contribute to the ability to generate hydroxyl radicals (OH) in vitro in PM2.5 sampled at 20 locations in 19 European centres participating in the European Community Respiratory Health Survey. PM2.5 samples (n = 716) were collected on filters over one year and the oxidative activity of particle suspensions obtained from these filters was then assessed by measuring their ability to generate OH in the presence of hydrogen peroxide. Associations between OH formation and the studied PM constituents were heterogeneous. The total explained variance ranged from 85% in Norwich to only 6% in Albacete. Among the 20 centres, 15 showed positive correlations between one or more of the measured transition metals (copper, iron, manganese, lead, vanadium and titanium) and OH formation. In 9 of 20 centres OH formation was negatively associated with chloride, and in 3 centres with sodium. Across 19 European cities, elements which explained the largest variations in OH formation were chloride, iron and sodium. 相似文献
23.
Teresa N. Malafi Marlene A. Devine Larry L. Lesher 《Journal of Polymers and the Environment》1994,2(4):219-223
This paper summarizes a study evaluating the acceptance and perceived performance of disposable cutlery made from starch-based biodegradable resins relative to nondegradable polystyrene cutlery. Two hundred forty-three sailors onboard three U.S. Navy vessels ate their lunch using either biodegradable cutlery made with resins manufactured by one of two commercial companies or polystyrene cutlery. The cutlery was rated on several sensory and performance dimensions as well as for overall acceptability. Results indicated that sailors rated both the biodegradable and the polystyrene utensils as easy to hold. There were also no differences in the perceived ease of using each of the spoons. However, compared to the polystyrene utensils, both types of biodegradable utensils were viewed as less sturdy, as having a less attractive color, and as being less acceptable overall. The biodegradable forks and knives were also rated as more difficult to use for piercing and cutting food than the polystyrene ones. In addition, several significant differences emerged between the two types of biodegradable cutlery. The results are discussed in terms of the need for continued consumer testing of products developed from biodegradable polymeric materials. 相似文献
24.
This study was conducted to evaluate the influence of sorbent modification by synthetic, chemical/thermal weathering on the sorptive behavior of polycyclic aromatic hydrocarbons (PAHs). A clean sandy-clay-loam soil was subjected to Soxhlet extraction and PAH sorptive phenomena were evaluated based on quantity and quality changes in soil organic matter (SOM) and clay minerals. Critical changes in sorption capacity were found to depend on the initial PAH concentrations. Above 7 mg/l, weathering increased the PAH in comparison to that of unmodified soil, whereas it decreased when applied below this concentration. Similarly, less PAH was desorbed from the altered soil when PAH was applied above 7 mg/l. Therefore, when PAH was applied below 7 mg/l, quantitative reduction of sorbent amount (i.e., SOM and clay minerals) by soil weathering governed PAH sorptive behavior. However, when the PAH was applied above the critical limit, qualitative modifications in the sorbents facilitated an opposite trend. Sorbent swelling, removal of competing compounds, and possible changes in surface characteristics by Soxhlet extraction, together with increased concentration gradient effects were factors that resulted in dissimilar PAH sorptive phenomena, pivoting at the critical concentration. 相似文献
25.
26.
The survival of autochthonous fungi in soil treated with 1mM aqueous solution of glyphosate was investigated. Significant differences in the total number of fungi in the studied objects were observed, and additionally significant qualitative changes were encountered. The dominating group of fungi belonged to genus Fusarium: Fusarium solani H30, Fusarium solani H50 and Fusarium oxysporum H80. Interactions between the isolated strains of fungi and varying concentrations of glyphosate were determined. The studied strains possessed high tolerance against the applied doses of glyphosate (0.5-2.0 mM). In the presence of glyphosate (as a sole source of phosphorus) applied in concentrations of 1.0-1.5 mM the increase in dry mass of the tested fungi was highly significant. In the presence of glyphosate the phenotypic changes of studied strains were observed as was shown as the presence of colorants being indicators of such changes. Thus, their color and intensity depended on the age, pH and species present in the culture. The degradation of glyphosate by studied fungi was determined by means of TLC. Two types of compounds were formed. One of them (Rf=0.21-0.35) contained free amino group but was not either glycine nor AMPA. Survival of Fusarium in soil environment is potentially dangerous. 相似文献
27.
28.
GOAL, SCOPE AND BACKGROUND: Pentachlorophenol (PCP) is the second highest volume pesticide used in the United States. It is a mutagenic compound whose exposure poses significant health effects, One of the most desirable, environmentally friendly treatment methods is bioremediation. For soil-based contamination, the effectiveness of bioremediation will also be affected by the presence of an active indigenous population, sorption of the contaminant onto the soil, and environmental parameters. METHODS: Two pure strains and their mixed culture were used to evaluate PCP biodegradation in two different field soils, Columbia (CO) and New Mexico (NM). Biostimulation of the indigenous microbes was evaluated by adding nutrients. The efficiency of adding bacteria strains (bioaugmentation) for degrading PCP was determined with Arthrobacter sp., Flavobacterium sp. and a 50:50 mixture of the two bacteria strains. RESULTS: In CO soil, only 24%, 12% and 25% of the initial PCP concentration were degraded by Flavobacterium sp., Arthrobacter sp. and mixed culture, respectively. Arthrobacter sp. was used in NM soil with two initial concentrations and achieved degradation efficiencies of 57% and 61% for 361 and 95 mg kg- concentrations, respectively. Discussion. Analysis via statistical methods showed that the bacteria had different efficiencies on PCP degradation in each soil. 2 CONCLUSIONS: All bacteria catalyzed a higher PCP degradation when present in NM soil. Second, Flavobacterium sp. degraded more PCP than Arthrobacter sp. in CO soil. The mixed culture achieved the highest degradation efficiency regardless of the initial concentration or soil origin. RECOMMENDATIONS AND PERSPECTIVES: The effect of the soil properties, such as the soil organic matter (SOM) on PCP biodegradation should be investigated. Future work can also investigate the effect of aging time on biodegradation. 相似文献
29.
Diego Iribarren Almudena Hospido María Teresa Moreira Gumersindo Feijoo 《Environmental Science & Policy》2010,13(6):509-521
The increasing demand for environmental information on the global warming impact of products requires a solid methodological framework which guarantees comparability and communicability. The publicly available specification PAS 2050 combines approaches to a variety of greenhouse gas specific assessment issues to deliver a globally applicable product Carbon Footprinting (CF) method, which is expected to be widely accepted. Specifically, this paper aims to demonstrate the implementation of a CF scheme for a common canned mussel product according to PAS 2050 guidelines. A final value of 4.35 kg CO2e per triple pack of round cans of mussels was calculated. Furthermore, this CF study led to identify primary packaging (can production) and mussel shell management as the main activities where efforts should focus for climate change mitigation. Throughout this case study, CF opportunities and drawbacks are discussed. The whole text tries to provide a starting point for both mussel processors and policy makers to benefit from the potential advantages of a responsible use of this increasingly popular tool. 相似文献
30.
Diego Iribarren Maria Teresa Moreira Gumersindo Feijoo 《Journal of Cleaner Production》2010,18(2):101-111
Mussels as a commercial product involve a range of activities which can be included within four different sub-sectors: culture, dispatch centres, canning factories and, finally, cooking plants. This paper deals with the environmental evaluation of the whole mussel sector from a Life Cycle Assessment approach. The use of exhaustive inventories led to the subsequent environmental characterization of the mussel sector in terms of the contribution observed for each of the sub-sectors. In this sense, the sub-sector associated with dispatch centres presented the largest contributions to the potential environmental impacts, clearly ahead of mussel farming. Furthermore, the sub-sectors of mussel cooking plants and canning factories showed a much lower contribution to the potential environmental impacts. Several improvement potentials were identified from the characterization results, stressing the minimization of the electric energy consumption in dispatch centres. A comparative LCA was performed in order to contrast the environmental performance of the three main commercial mussel products: fresh mussels, canned mussels and frozen mussels. The analysis showed that fresh mussels have the least favourable environmental profile. 相似文献