A passive sampling device for determining formaldehyde in indoor air

A passive sampling device based on the principle of diffusion has been developed for the determination of formaldehyde in ambient air. The sampler consists of a capped glass tube (with approximate dimensions of 2.4 × 9 cm) containing a glass-fiber filter treated with NaHSO₃. In the field, the device collects a sample by being uncapped for a specified sampling time. After being recapped and returned to the laboratory, the filter is analyzed by the chromotropic acid (CTA) method. Laboratory validation studies were conducted by exposing the sampling devices for 1 week to dry formaldehyde gas generated by passing trioxane vapor over an acid catalyst bed. In these tests, formaldehyde concentrations ranged from 0.05 to 0.80 mL/m³. Reproducibility was excellent, with relative standard deviations averaging 5.4% for five constant concentrations. The lower detection limit was determined to be 3.6 mL/m³ h. In an occupational environment an 8-h sample would be sufficient to detect compliance with the OSHA permissible exposure limit of 3 mL/m³; in a residential environment a 1-week sample would allow detection of 0.025 mL/m³ for indoor air quality audits.     

Effects of head restraint and seat redesign on neck injury risk in rear-end crashes

Automobile insurance claims were examined to determine the rates of neck injuries in rear-end crashes for vehicles with and without redesigned head restraints, redesigned seats, or both. Results indicate that the improved geometric fit of head restraints observed in many newer vehicle models are reducing the risk of whiplash injury substantially among female drivers (about 37% in the Ford Taurus and Mercury Sable), but have very little effect among male drivers. New seat designs, such as active head restraints that move upward and closer to drivers' heads during a rear impact, give added benefit, producing about a 43% reduction in whiplash injury claims (55% reduction among female drivers). Estimated effects of Volvo's Whiplash Injury Prevention System and Toyota's Whiplash Injury Lessening design were based on smaller samples and were not statistically significant.     

Prediction of cervical spine injury risk for the 6-year-old child in frontal crashes

This article presents a series of 49 km/h sled tests using the Hybrid III 6-year-old dummy in a high-back booster, a low-back booster, and a three-point belt. Although a 10-year review at a level I trauma center showed that noncontact cervical spine injuries are rare in correctly restrained booster-age children, dummy neck loads exceeded published injury thresholds in all tests. The dummy underwent extreme neck flexion during the test, causing full-face contact with the dummy's chest. These dummy kinematics were compared to the kinematics of a 12-year-old cadaver tested in a similar impact environment. The cadaver test showed neck flexion, but also significant thoracic spinal flexion which was nonexistent in the dummy. This comparison was expanded using MADYMO simulations in which the thoracic spinal stiffness of the dummy model was decreased to give a more biofidelic kinematic response. We conclude that the stiff thoracic spine of the dummy results in high neck forces and moments that are not representative of the true injury potential.     

Rapidly eroding piñon-juniper woodlands in New Mexico: response to slash treatment

The pi?on (Pinus edulis Engelm.)-juniper [Juniperus monosperma (Engelm.) Sarg.] woodlands of Bandelier National Monument are experiencing accelerated erosion. Earlier studies suggest that causes of these rapidly eroding woodlands are related to an unprecedented rapid transition of ponderosa pine (Pinus ponderosa C. Lawson) savanna to pi?on-juniper woodlands as a result of cumulative historical effects of overgrazing, fire suppression, and severe drought. To study the effectiveness of slash treatment in reducing accelerated erosion, we used sediment check dams to quantify sediment yield from twelve paired microwatersheds (300-1100 m2) within an existing paired water-shed study. Six of the twelve microwatersheds were located in a 41-ha (treatment) watershed with scattered slash treatment, whereas six microwatersheds were located in an adjacent 35-ha untreated (control) watershed. The primary purpose of our research was to quantify the rates of sediment yield between the treated and control microwatersheds. Sediment yield was measured from 15 individual storms during the months of June-September (2000 and 2001). In response to slash treatment, mean seasonal sediment yield for 2000 equaled 2.99 Mg/ha in the control vs. 0.03 Mg/ha in the treatment and 2.07 Mg/ha in the control vs. 0.07 Mg/ha in the treatment in 2001. The practice of slash treatment demonstrates efficacy in reducing erosion in degraded pi?on-juniper woodlands by encouraging herbaceous recovery. Our data show that slash treatment increases total ground cover (slash and herbaceous growth) beyond a potential erosion threshold. Restored pi?on-juniper woodlands, as the result of slash treatment, provide a forest structure similar to pre-grazing and pre-fire suppression conditions and decrease catastrophic fire hazard.     

Evaluation of leachate composition by multivariate data analysis (MVDA)

Landfills generate emissions in the form of gas and leachate. The emissions are often measured within monitoring programmes. It is likely that the requirements of such monitoring programmes can be extended in the future, particularly in light of the increased interest in specific organic substances. Multivariate data analyses (MVDA) have been used to evaluate the possibility of predicting the content of specific organic substances from more common analyses. The results indicate that this is possible for a specific leachate. MVDA can also be used to reduce the number of analyses performed within existing monitoring programmes while retaining information about all the variables formerly included in the programmes.     

Agricultural Land Use Effects on Sediment Loading and Fish Assemblages in Two Minnesota (USA) Watersheds

We examined the relationship between water quality and fish communities within two agricultural areas using a computer simulation model. Our analyses focused on a coolwater stream, Wells Creek in southeastern Minnesota, and a warmwater stream, the Chippewa River in western Minnesota. We used the Agricultural Drainage and Pesticide Transport (ADAPT) model in relation to land use to calculate instream suspended sediment concentrations using estimates of sediment delivery, runoff, baseflow and streambank erosion, and quantified the effects of suspended sediment exposure on fish communities. We predicted the effects of agricultural practices on stream fish communities under several possible land use scenarios, with reference to current conditions. Land use changes led to reductions in sediment loading of up to 84% in Wells Creek and 49% in the Chippewa River. The reduction in sediment loading across scenarios may be directly related to a reduction in runoff by about 35% in both study areas. We found a 98% decrease in lethal concentrations of suspended sediment on fish in Wells Creek with an increase in conservation tillage, riparian buffers, and permanent vegetative cover. However, the effects of suspended sediment did not significantly decrease in the Chippewa River. This difference between study areas was likely due to differences in tolerance to suspended sediment between coolwater and warmwater fish communities and differences in topography, runoff and bank erosion between the two streams. The Minnesota Cooperative Fish and Wildlife Research Unit is jointly sponsored by the US Geological Survey, the University of Minnesota, the Minnesota Department of Natural Resources, and the Wildlife Management Institute.     

Assessing Biological Integrity Using Freshwater Fish and Decapod Habitat Selection Functions

Comparison between the number of taxa observed and the number expected in the absence of human impact is an easily understood and ecologically meaningful measure of biological integrity. This approach has been successfully applied to the assessment of the biological quality of flowing water sites using macroinvertebrates with the river invertebrate and classification system (RIVPACS) and its derivatives. In this paper, we develop a method similar to the RIVPACS predictive model approach to assess biological integrity at flowing-water sites using freshwater fish and decapod assemblages. We extend the RIVPACS approach by avoiding the biotic classification step and model each of the individual species separately. These assemblages were sampled at 118 least impacted (reference) sites in the Auckland region, New Zealand. Individual discriminant models based on the presence or absence of the 12 most common fish and decapod species were developed. Using the models, predictions were made using environmental measures at new sites to yield the probability of the capture of each of the 12 species, and these were combined to predict the assemblage expected at sites. The expected assemblage was compared to that observed using an observed over expected ratio (O/E). The models were evaluated using a number of internal tests including jackknifing, data partitioning, and the degree to which O/E values differed between reference sites and a set of sites perceived to be impaired by human impacts.     

An Evaluation of Vernal Pool Creation Projects in New England: Project Documentation from 1991–2000

Vernal pools are vulnerable to loss through development and agricultural and forestry practices owing to their isolation from open water bodies and their small size. Some vernal pool-dependent species are already listed in New England as Endangered, Threatened, or Species of Special Concern. Vernal pool creation is becoming more common in compensatory mitigation as open water ponds, in general, may be easier to create than wooded wetlands. However, research on vernal pool creation is limited. A recent National Research Council study (2001) cites vernal pools as challenging to recreate. We reviewed documentation on 15 vernal pool creation projects in New England that were required by federal regulatory action. Our purpose was to determine whether vernal pool creation for compensatory mitigation in New England replaced key vernal pool functions by assessing project goals and documentation (including mitigation plans, pool design criteria, monitoring protocols, and performance standards). Our results indicate that creation attempts often fail to replicate lost pool functions. Pool design specifications are often based on conjecture rather than on reference wetlands or created pools that function successfully. Project monitoring lacks consistency and reliability, and record keeping by regulatory agencies is inadequate. Strengthening of protection of isolated wetlands in general, and standardization across all aspects of vernal pool creation, is needed to ensure success and to promote conservation of the long-term landscape functions of vernal pools.     

Development of a purpose built landfill system for the control of methane emissions from municipal solid waste

In the present paper, a new system of purpose built landfill (PBLF) has been proposed for the control of methane emissions from municipal solid waste (MSW), by considering all favourable conditions for improved methane generation in tropical climates. Based on certain theoretical considerations multivariate functional models (MFMs) are developed to estimate methane mitigation and energy generating potential of the proposed system. Comparison was made between the existing waste management system and proposed PBLF system. It has been found that the proposed methodology not only controlled methane emissions to the atmosphere but also could yield considerable energy in terms of landfill gas (LFG). Economic feasibility of the proposed system has been tested by comparing unit cost of waste disposal in conventional as well as PBLF systems. In a case study of MSW management in Mumbai (INDIA), it was found that the unit cost of waste disposal with PBLF system is seven times lesser than that of the conventional waste management system. The proposed system showed promising energy generation potential with production of methane worth of Rs. 244 millions/y ($5.2 million/y). Thus, the new waste management methodology could give an adaptable solution for the conflict between development, environmental degradation and natural resources depletion.     

Implications of fluoride--an endless uncertainty

Fluorosis has become pandemic and it has assumed global status in the public health point of view. The paper deals with the health issues pertaining to fluorosis with special emphasis in the Indian context. It explains the equivocal evidences of fluoride-related problems and discusses the control measures of fluorosis. In general, it reveals how fluoride is useful at very low concentrations and at the same time brings forth manifestation of clinical abnormalities at higher concentrations that are the basis of the principles of toxicology.