核电站FDA安全管理信息流系统模型的构建研究

为了从安全信息的角度完善核电站的事故致因机理，并在实践中加强核电站的安全管理，首先以安全信息为视角，以系统安全行为链为主线，建立核电站FDA安全管理信息流系统模型，该模型由运行操作人员、核电站企业、国家核安全局3条子链和1条必要安全信息主链构成；然后结合模型和核电站具体工作流程，分析得到3个子事故域和1个总事故域，并归纳出核电站安全运行各阶段所需的必要安全信息；最后结合事故域，分析模型在核电站安全管理中的实际应用价值。     

Energy transfer and kinetics in mechanochemistry

Mechanochemistry (MC) exerts extraordinary degradation and decomposition effects on many chlorinated, brominated, and even fluorinated persistent organic pollutants (POPs). However, its application is still limited by inadequate study of its reaction kinetic aspects. In the present work, the ball motion and energy transfer in planetary ball mill are investigated in some detail. Almost all milling parameters are summarised in a single factor—total effective impact energy. Furthermore, the MC kinetic between calcium oxide/Al and hexachlorobenzene is well established and modelled. The results indicate that total effective impact energy and reagent ratio are the two factors sufficient for describing the MC degradation degree of POPs. The reaction rate constant only depends on the chemical properties of reactants, so it could be used as an important index to appraise the quality of MC additives. This model successfully predicts the reaction rate for different operating conditions, indicating that it could be suitably applied for conducting MC reactions in other reactors.

     

膨润土的2种不同柱撑改性方式及其吸附重金属锌离子的比较

考察了钙基膨润土钠化过程中改性剂的用量,矿浆浓度,改性时间等对改性效果的影响,并测试了不同超声反应时间、陈化时间等条件下制备的钠化膨润土的性能,如:膨胀容,膨润值和阳离子交换容量CEC,然后分别以Al13-Cl和Al13-SO4方式嵌入矿物层间域中制备柱撑膨润土,考察和比较了不同陈化时间下2种柱撑膨润土煅烧前后的微观结构,及其对污水中锌离子的吸附去除效果,结果表明,Al13-Cl改性方法制备的柱撑膨润土对锌离子的吸附性能明显优于Al13-SO4柱撑效果。     

电气石对脱氯菌降解三氯乙烯的影响

以电气石作为环境微生物强化介质材料,协同以Dehalococcoides spp.为主体的脱氯混合菌群(简称脱氯菌)对水中的三氯乙烯(TCE)进行降解,探讨了电气石对降解效果的影响。实验结果表明:电气石可调节水溶液的p H使之趋向于中性并提高水溶液的电导率;在脱氯菌接种量为8%、电气石加入量为5.0 g/L的条件下降解20mg/L的TCE,84 h时TCE已全部降解,而未加电气石体系只降解了54.7%;外加电子供体甲醇和外加电气石均可明显提高脱氯菌对TCE的降解速率,且外加电气石的降解效果更好,说明电气石可能在促进微生物生长繁殖的同时也能为其提供合适的电子供体,这对降解地下水中的TCE具有重要意义。     

凤眼莲去除垃圾渗滤液中的COD、NH3-N和TP

在静态水培实验条件下,对不同浓度垃圾渗滤液条件下凤眼莲的生长状况及其净化效果进行了研究。结果表明,在高浓度(COD 3 546.7 mg/L、NH3-N 527.5 mg/L、TP 8.02 mg/L)垃圾渗滤液条件下(HCL)凤眼莲全部被毒害致死,在中浓度(COD 1 233.3 mg/L、NH3-N 182.9 mg/L、TP 2.83 mg/L)垃圾渗滤液条件下(MCL)生长状况差,生物量减少为实验前的32.6%。在低浓度(COD 660.0 mg/L、NH3-N 99.7 mg/L、TP 1.59 mg/L)垃圾渗滤液条件下(LCL)能够正常生长,且对低浓度垃圾渗滤液有较好的净化效果。24 d后COD、NH3-N和TP的去除率分别为85.9%,99.8%和84.8%。COD与NH3-N均达到《生活垃圾填埋场污染控制标准(GB16889-2008)》排放标准,TP达到《地表水环境质量标准(GB 3838-2002)》Ⅳ类排放标准。     

煤制取天然气全生命周期评价分析

利用全生命周期评价(LCA)方法,对某日产1 200万m3煤制天然气(SNG)项目进行分析,计算出每生产1 000 m3天然气需消耗2 435.71 kg标煤,34.44 kg油和0.62 kg天然气,总资源耗竭系数26.34 mPR90,总环境影响潜值为1.96 PET2010。此项目整个生命周期对全球变暖的影响最大,对粉尘的影响最小,说明SNG项目对局地性的环境影响相对全球性和区域性较小。     

Tuning the primary selective nanochannels of MOF thin-film nanocomposite nanofiltration membranes for efficient removal of hydrophobic endocrine disrupting compounds

• PA layer properties tune the primary nanochannels in MIL-101(Cr) TFN NF membranes. • The dense PA layer induced transition of primary nanochannels of TFN NF membranes. • Nanochannels around MOF contributed to the improved flux with a loose PA structure. • Nanochannels in MOFs dominated the separation performance with a dense PA structure. Metal organic framework (MOF) incorporated thin-film nanocomposite (TFN) membranes have the potential to enhance the removal of endocrine disrupting compounds (EDCs). In MOF-TFN membranes, water transport nanochannels include (i) pores of polyamide layer, (ii) pores in MOFs and (iii) channels around MOFs (polyamide-MOF interface). However, information on how to tune the nanochannels to enhance EDCs rejection is scarce, impeding the refinement of TFN membranes toward efficient removal of EDCs. In this study, by changing the polyamide properties, the water transport nanochannels could be confined primarily in pores of MOFs when the polyamide layer became dense. Interestingly, the improved rejection of EDCs was dependent on the water transport channels of the TFN membrane. At low monomer concentration (i.e., loose polyamide structure), the hydrophilic nanochannels of MIL-101(Cr) in the polyamide layer could not dominate the membrane separation performance, and hence the extent of improvement in EDCs rejection was relatively low. In contrast, at high monomer concentration (i.e., dense polyamide structure), the hydrophilic nanochannels of MIL-101(Cr) were responsible for the selective removal of hydrophobic EDCs, demonstrating that the manipulation of water transport nanochannels in the TFN membrane could successfully overcome the permeability and EDCs rejection trade-off. Our results highlight the potential of tuning primary selective nanochannels of MOF-TFN membranes for the efficient removal of EDCs.     

基于“美丽海湾”建设的“三线一单”编制实践--以儋州市环新英湾地区为例

编制“三线一单”(生态保护红线、环境质量底线、资源利用上线和生态环境准入清单)是深入打好污染防治攻坚战的基础。以儋州市为研究对象,衔接“美丽海湾”建设需求,从“三水”(水环境、水生态、水资源)协同角度提出解决儋州市重点海湾环新英湾地区突出生态环境问题的生态分区管控方案,重点讨论了基于陆海统筹原则的环新英湾地区“三线一单”编制重点和特色,提出了针对性的生态环境保护的对策建议,探索了一套符合沿海地区特色的生态环境要素分区管控方案编制方法,为其他沿海城市“三线一单”划定提供借鉴。     

脱贫山区农户生计转型的低碳效应研究：以陇南山区为例

明确脱贫山区农户生计转型的低碳效应对实现乡村绿色发展、建设低碳乡村至关重要。基于陇南山区农户的入户调查数据，利用碳排放清单法分析了2014—2019年农户的生计转型路径及其低碳效应。结果表明：（1）陇南山区农户的生计策略分为传统农业主导型、经济作物主导型、务工主导型、经商主导型和综合型；2014—2019年有26.97%的农户生计策略发生了转型，最主要的转型方式是由综合型转向务工主导型；（2）因人均生活碳排放增加量高于人均生产碳排放减少量，陇南山区农户的人均家庭碳排放呈增加趋势；（3）农户生计转型路径中，由经济作物主导型转向传统农业主导型的人均家庭碳排放降幅最大，为41.45%，综合型转向传统农业主导型的增幅最大，达208.86%。