全文获取类型
收费全文 | 14193篇 |
免费 | 45篇 |
国内免费 | 26篇 |
专业分类
安全科学 | 86篇 |
废物处理 | 1035篇 |
环保管理 | 1560篇 |
综合类 | 1699篇 |
基础理论 | 3958篇 |
环境理论 | 5篇 |
污染及防治 | 3366篇 |
评价与监测 | 1381篇 |
社会与环境 | 1151篇 |
灾害及防治 | 23篇 |
出版年
2023年 | 58篇 |
2022年 | 145篇 |
2021年 | 155篇 |
2020年 | 73篇 |
2019年 | 75篇 |
2018年 | 1565篇 |
2017年 | 1468篇 |
2016年 | 1381篇 |
2015年 | 264篇 |
2014年 | 297篇 |
2013年 | 466篇 |
2012年 | 740篇 |
2011年 | 1599篇 |
2010年 | 893篇 |
2009年 | 750篇 |
2008年 | 1132篇 |
2007年 | 1471篇 |
2006年 | 272篇 |
2005年 | 206篇 |
2004年 | 185篇 |
2003年 | 184篇 |
2002年 | 208篇 |
2001年 | 82篇 |
2000年 | 62篇 |
1999年 | 38篇 |
1998年 | 25篇 |
1997年 | 19篇 |
1996年 | 11篇 |
1995年 | 28篇 |
1994年 | 19篇 |
1993年 | 15篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1989年 | 13篇 |
1984年 | 12篇 |
1983年 | 10篇 |
1966年 | 12篇 |
1965年 | 15篇 |
1964年 | 31篇 |
1963年 | 12篇 |
1962年 | 17篇 |
1961年 | 11篇 |
1960年 | 10篇 |
1959年 | 28篇 |
1958年 | 25篇 |
1957年 | 18篇 |
1956年 | 14篇 |
1955年 | 18篇 |
1954年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 62 毫秒
971.
The total petroleum hydrocarbons (TPH) pollution in regional agricultural soils was investigated. Seventy soil samples collected
from surface layers (0–20 cm) and horizons of five selected pedons in the vicinity of a petrochemical complex in Guangzhou,
China were analyzed, and the vertical variation and spatial variability of TPH were evaluated. The TPH concentration in top
soils around the petrochemical complex ranged from 1,179.3 to 6,354.9 mg kg − 1, with the average of 2,676.6 mg kg − 1. Furthermore, significant differences between land-use types showed that the TPH concentration in top soils was strongly
influenced by accidental spills. Both the TPH trends in pedons and the identified hot-spot areas also showed that the accidental
explosions or burning accidents were mainly responsible for the pollution. The results reported here suggest that the regular
monitoring and inspection shall be conducted for safety and to avoid or minimize the accidents, and the effective measures
should be taken to remediate the contaminated areas and to assure that the important industrialization of Guangzhou area would
not mean human health risks near the petrochemical complex. 相似文献
972.
A differential pulse polarography (DPP) for the simultaneous determination of 2-nitrophenol and 4-nitrophenol was proposed.
It was found that under optimum experimental conditions (pH = 5, scan rate = 5 mV/s, pulse amplitude = −50 mV), 2-nitrophenol
and 4-nitrophenol had well-defined polarographic reduction waves with peak potentials at −317 and −406 mV, respectively. In
the mixture of two compounds overlapping polarographic peaks were observed. In this study, support vector regression (SVR)
was applied to resolve the overlapped polarograms. Furthermore, a comparison was made between the performance of SVR and partial
least square (PLS) on data set. The results demonstrated that SVR is a better well-performing alternative for the analysis
and modeling of DPP data than the commonly applied PLS technique. The proposed method was used for the determination of 2-nitrophenol
and 4-nitrophenol in industrial waste water. 相似文献
973.
Fish scales as indicators of wastewater toxicity from an international water channel Tung Dhab drain
The effect of wastewater exposure on scales and chromatophores of freshwater fish Channa punctatus was studied using wastewater dilutions (60–100%) from an international water channel Tung Dhab drain at an interval of 15
and 30 days. The exposed fish showed significant alterations such as uprooted and damaged lepidonts and dispersal of chromatophores.
These observations strongly suggest that fish scales can be successfully employed as indicators of wastewater pollution. 相似文献
974.
Agunbiade FO Olu-Owolabi BI Adebowale KO 《Environmental monitoring and assessment》2012,184(1):89-102
The accumulation patterns of ten metals in tissues of plant, Eichornia crassipes, and fishes, Hydrocynus forskahlii and Oreochromis mossambicus, were modeled with simple fuzzy classification (SFC) to assess toxic effects of anthropogenic activities on the coastal biota.
The plant sample was separated into root, stem, and leaves and the fishes into bones, internal tissues, and muscles. They
were analyzed for As, Cd, Cr, Cu, Ni, Pb, V, Fe, Mn, and Zn after wet oxidation of their dried samples. The results were converted
into membership functions of five accumulation classes and aggregated with SFC. The classification results showed that there
was no metal accumulation in the plant parts while the fishes were classified into low accumulation category. The internal
tissues of the fishes had higher metal accumulation than the other parts. Generally, Fe and Mn had highest concentrations
in the biota but are natural to the area and may not constitute significant risk. Cr had the highest transfer and accumulation
from the coastal water into the aquatic lives and may be indicative of risk prone system being a toxic metal. Metal contaminations
in the zone had not significantly accumulated in the biota making them less prone to risk associated with metal accumulation. 相似文献
975.
C. Borrego J. Valente A. Carvalho E. Sá M. Lopes A.I. Miranda 《Atmospheric environment (Oxford, England : 1994)》2010,44(5):642-651
Wood is commonly used in residential combustion for heating purposes; however, it can be a major source of air pollutants, namely fine particles, volatile organic compounds and carbon monoxide. Since 2004, the PM10 daily limit value has been surpassed in Portugal, and the European Commission has stated that plans and programs must be designed in order to reduce these levels. In Portugal, 18% of PM10 emissions are due to residential wood combustion, which may deeply impact the PM10 levels in the atmosphere. The main aim of this study is to investigate the impact of residential wood combustion on the air quality in Portugal. The air quality modelling system MM5/CHIMERE was applied over Portugal for a winter month, for the following three scenarios: the reference scenario, considering the actual emissions of PM10; scenario 1, where residential wood combustion emissions are not considered; and scenario 2, which takes into account a complete conversion from traditional fireplaces to certified appliances (with a 90% reduction in PM emissions). The residential wood combustion contribution to PM10 air quality concentration values during January 2007 ranges from 0 to 14 μg m?3, with a mean contribution of 10 μg m?3 in the Lisboa area and 6 μg m?3 in the Porto region. Concerning the legislated values, the area where the daily average limit value (50 μg m?3) is exceeded decreases by 46% in the simulation when residential combustion is not considered. The modelling results for scenario 2 are not significantly different from those for scenario 1. In summary, the regulation of the residential wood combustion sector is as an effective way to reduce the PM10 levels in the atmosphere as regards air quality plans and programs. 相似文献
976.
Spatial and seasonal distribution of nitrogen in marsh soils of a typical floodplain wetland in Northeast China 总被引:3,自引:0,他引:3
Bai J Wang Q Deng W Gao H Tao W Xiao R 《Environmental monitoring and assessment》2012,184(3):1253-1263
Horizontal and profile distributions of nitrogen in marsh soils in different seasons were studied in a typical site within
the Erbaifangzi wetland in Northeast China. Results showed that there was higher spatial heterogeneity for nitrate nitrogen
(NO3--_{3}^{-}-N) and ammonium nitrogen (NH4+_{4}^{+}–N), as well as available nitrogen (AN), in surface soils in July compared to that in September. Relative to July, the mean
nitrogen contents in surface soils were slightly higher in September; however, in November, soils contained significantly
lower NO3--_{3}^{-}-N and NH4+_{4}^{+}–N, higher AN, organic nitrogen (Org-N), and total nitrogen (TN). Except for mineral nitrogen, no significant differences
were observed between Org-N and TN contents in September and November. Nitrogen contents generally declined exponentially
with depth along soil profiles in three sampling dates (July, September, and November), except for a significant accumulation
peak of NO3--_{3}^{-}-N at the 20–30 cm depth in September. However, NH4+_{4}^{+}–N contents showed a vertical alternation of “increasing and decreasing” in both July and September, while nearly kept constant
with depth in November. The depth ranking of nitrogen showed the shallowest distribution for AN, followed by Org-N and TN,
while deeper distributions for NO3--_{3}^{-}-N and NH4+_{4}^{+}–N. TN, Org-N, and AN were significantly correlated with soil organic matter and total phosphorus. Soil pH values were significantly
correlated with TN and AN contents in surface soils. Clay contents showed significant correlations with nitrogen contents
except for NO3--_{3}^{-}-N in surface soils and NH4+_{4}^{+}–N in profile soils. However, soil moisture was not significantly correlated with nitrogen contents among all soil samples. 相似文献
977.
Suciu NA Ferrari T Ferrari F Trevisan M Capri E 《Environmental science and pollution research international》2012,19(4):1229-1236
Purpose
Many reports on purification of water containing pesticides are based on studies using unformulated active ingredients. However, most commercial formulations contain additives/adjuvants or are manufactured using microencapsulation which may influence the purification process. Therefore, the main objective of this work was to develop and test a pilot scheme for decontaminating water containing pesticides formulated with antifoaming/defoaming agents. 相似文献978.
Chlorinated paraffins (CPs) are straight chain hydrocarbons that are produced as complex mixtures and are used as flame retardants
and paint additives. These mixtures are extremely difficult to characterize using conventional chromatographic methods, as
conventional gas chromatography results in unresolved complex chromatograms that preclude the identification and quantification
of individual congeners or any reasonable assessment of the average carbon chain length. Carbon chain length is an important
parameter for assessing physical properties and the toxicity of these materials. We have modified and improved a previously
published gas chromatography–flame ionization detector method that uses Pd catalyst held in the gas chromatograph injector
to simultaneously dechlorinate the CPs and separate the resulting alkanes. In addition, we have adapted this method to gas
chromatography–mass spectrometry. Dehalogenation of other compounds was also studied with this system to investigate potential
application to other complex halogenated mixtures. 相似文献
979.
Voss KA Pohlman A Viswanathan S Gibson D Purohit J 《Environmental monitoring and assessment》2012,184(3):1603-1616
Environmental agencies across the United States have searched for adequate methods to assess anthropogenic impacts on the
environment. Biological assessments, which compare the taxonomic composition of an aquatic assemblage to relevant biocriteria,
have surfaced as an effective method to assess the ecological integrity of US waterbodies. In this study, bioassessment data
were collected and analyzed in conjunction with physical habitat and chemical stressor data for streams and rivers within
the San Diego basin from 1998 through 2005. Physical stressors such as sediment loading, riparian destruction, and in-stream
habitat homogenization affect many locations in the region. However, physical habitat measures alone were found to frequently
overestimate the biological integrity of streams in the region. Many sites within the San Diego Basin, although unaffected
by physical stressors, continue to exhibit low biological integrity scores. Sites with low biological integrity tend to possess
higher specific conductance and salinity compared to sites with high biological integrity. We suggest that one possible reason
for these differences is the source water used for municipal purposes. 相似文献
980.
Sexual cannibalism can occur before, during or after mating. Relatively few experimental studies have examined why there is
variation in the timing of sexual cannibalism. We examined the latency and number of attacks required for female spiders to
capture male spiders pre- vs. postcopulation. We also examined the effects of female mating status and hunger level on the
occurrence of pre- and postcopulatory cannibalism, which reflects the contribution of both relative capture success and female
motivation to cannibalize males. Precopulatory cannibalism occurred after a shorter interval and required fewer chases and
physical interactions for the female to successfully capture the male than was the case for postcopulatory cannibalism. Virgin
females were more likely to engage in postcopulatory rather than precopulatory cannibalism and mated females vice versa. Those
virgin females that did engage in precopulatory cannibalism had significantly lower body condition than virgin females engaging
in postcopulatory cannibalism. While precopulatory cannibalism occurred more quickly and required fewer attacks by females,
it comes at a potential cost of not mating with males. Hence, females are more likely to engage in precopulatory cannibalism
if they have already mated or, if virgins, if they have low body condition. These results indicate that the decision of when
to cannibalize males is dynamic and depends upon the relative value of a male as a mate versus a meal. 相似文献