MODELING METALS TRANSPORT AND SEDIMENT/WATER INTERACTIONS IN A MINING IMPACTED MOUNTAIN STREAM1

ABSTRACT: The U.S. Environmental Protection Agency (USEPA) Water Quality Analysis Simulation Program (WASP5) was used to model the transport and sediment/water interactions of metals under low flow, steady state conditions in Tenmile Creek, a mountain stream supplying drinking water to the City of Helena, Montana, impacted by numerous abandoned hard rock mines. The model was calibrated for base flow using data collected by USEPA and validated using data from the U.S. Geological Survey (USGS) for higher flows. It was used to assess metals loadings and losses, exceedances of Montana State water quality standards, metals interactions in stream water and bed sediment, uncertainty in fate and transport processes and model parameters, and effectiveness of remedial alternatives that include leaving contaminated sediment in the stream. Results indicated that during base flow, adits and point sources contribute significant metals loadings to the stream, but that shallow ground water and bed sediment also contribute metals in some key locations. Losses from the water column occur in some areas, primarily due to adsorption and precipitation onto bed sediments. Some uncertainty exists in the metal partition coefficients associated with sediment, significance of precipitation reactions, and in the specific locations of unidentified sources and losses of metals. Standards exceedances are widespread throughout the stream, but the model showed that remediation of point sources and mine waste near water courses can help improve water quality. Model results also indicate, however, that alteration of the water supply scheme and increasing base flow will probably be required to meet all water quality standards.     

Assessment of Nonpoint Source Pollution from Inactive Mines Using a Watershed-Based Approach

/ A watershed-based approach for screening-level assessment of nonpoint source pollution from inactive and abandoned metal mines was developed and illustrated. The methodology was designed to use limited stream discharge and chemical data from synoptic surveys to derive key information required for targeting impaired waterbodies and critical source areas for detailed investigation and remediation. The approach was formulated based on the required attributes of an assessment methodology, information goals for targeting, attributes of data that are typical of basins with inactive mines, and data analysis methods that were useful for the case study. The methodology is presented as steps in a framework including evaluation of existing data/information and identification of data gaps; definition of assessment information goals for targeting and monitoring design; data collection, management, and analysis; and information reporting and use for targeting. Information generated includes the type and extent of and critical conditions for water-quality impairment, concentrations in and loadings to streams, differences between concentrations in and loadings to streams, and risks of exceeding target concentrations and loadings. Data from the Cement Creek Basin, located in the San Juan Mountains of southwestern Colorado, USA, were used to help develop and illustrate application of the methodology. The required information was derived for Cement Creek and used for preliminary targeting of locations for detailed investigation and remediation. Application of the approach to Cement Creek was successful in terms of cost-effective generation of information and use for targeting.KEY WORDS: Water quality assessment; Nonpoint source pollution; Inactive mines; Watershed     

SEC-ICP-MS studies for elements binding to different molecular weight fractions of humic substances in compost extract obtained from urban solid waste

In this work, the speciation of elements in compost was studied with emphasis on their binding to humic substances. In order to assess the distribution of As, Cd, Co, Cr, Cu, Mn, Mo, Ni, Pb, U, Th and Zn among molecular weight fractions of humic substances, the compost extract (extracted by 0.1 mol l(-1) sodium pyrophosphate) was analyzed by size exclusion chromatography coupled on-line with UV-Vis spectrophotometric and ICP-MS detection. Similar chromatograms were obtained for standard humic acid (Fluka) and for compost extract (254 nm, 400 nm) and three size fractions were operationally defined that corresponded to the apparent molecular weight ranges > 15 kDa, 1-15 kDa and < 1 kDa. The percentage of total element content in compost that was leached to the extract ranged from 30% up to 100% for different elements. The elution profiles of Co, Cr, Cu, Ni and Pb (ICP-MS) followed that of humic substances, while for other elements the bulk elution peak matched the retention time observed for the element in the absence of compost extract. Spiking experiments were carried out to confirm elements' binding and to estimate the affinity of individual elements for humic substances derived from compost. The results obtained indicated the following order of decreasing affinity: Cu > Ni > Co > Pb > Cd > (Cr, U, Th) > (As, Mn, Mo, Zn). After standard addition, further binding of Cu, Ni and Co with the two molecular weight fractions of humic substances was observed, indicating that humic substances derived from compost were not saturated with these elements.     

Comparative Analysis of New Zealand and US Approaches for Agricultural Nonpoint Source Pollution Management

The role of the central government in New Zealand is generally limited to research and policy development, and regional councils are responsible for most monitoring and management of the problem. The role of the federal government in the United States includes research and monitoring, policy development, and regulation. States also have a significant management role. Both countries rely on voluntary approaches for NPS pollution management. Very few national water quality standards exist in New Zealand, whereas standards are widely used in the United States. Loading estimates and modeling are often used in the United States, but not in New Zealand. A wide range of best management practices (BMPs) are used in the United States, including buffer strips and constructed/engineered wetlands. Buffer strips and riparian management have been emphasized and used widely in New Zealand. Many approaches are common to both countries, but management of the problem has only been partly successful. The primary barriers are the inadequacy of the voluntary approach and the lack of scientific tools that are useful to decision-makers. More work needs to be performed on the evaluation of approaches developed in both countries that could be applied in the other countries. In addition, more cooperation and information/technology transfer between the two countries should be encouraged in the future.     

Predispersal seed herbivores, not pollinators, exert selection on floral traits via female fitness

Herbivores that oviposit in flowers of animal-pollinated plants depend on pollinators for seed production and are therefore expected to choose flowers that attract pollinators. This provides a mechanism by which seed herbivores and pollinators could impose conflicting selection on floral traits. We measured phenotypic selection on floral traits of Lobelia siphilitica (Lobeliaceae) via female fitness to determine the relative strength of selection by pollinators and a specialist predispersal seed herbivore. We were able to attribute selection on flowering phenology to the herbivores. However, no selection could be attributed to pollinators, resulting in no conflicting selection on floral traits. Unlike pollinators, whose preference for certain floral traits does not always translate into higher fitness, any discrimination by seed herbivores is likely to decrease fitness of the preferred floral phenotype. Thus predispersal seed herbivores may be a significant agent of selection on floral traits.     

Biophysical‐Regulatory Classification and Profiling of Streams Across Management Units and Ecoregions1

Caruso, Brian S. and Joshua Haynes, 2011. Biophysical‐Regulatory Classification and Profiling of Streams Across Management Units and Ecoregions. Journal of the American Water Resources Association (JAWRA) 00(0):1‐22. DOI: 10.1111/j.1752‐1688.2010.00522.x Abstract: Aquatic resources management in the United States (U.S.) under Clean Water Act Section 404 has become more complex after recent Supreme Court decisions and U.S. Army Corps of Engineers and Environmental Protection Agency (USEPA) guidance. Many intermittent/ephemeral and headwater streams may not be jurisdictional if they lack a significant nexus with navigable waters. Streams in semiarid USEPA Region 8 were classified based on hydrologic permanence and stream order using National Hydrography Dataset (NHD) Plus and GIS to provide information across broad spatial scales to aid with jurisdictional determinations (JDs). Four classes were developed for profiling across management units and ecoregions. Based on medium‐resolution NHDPlus data, intermittent streams comprise >¾, and first order streams constitute >½ of the total stream length in Region 8. Mountain states and ecoregions have the largest percentage of perennial first order streams, whereas the Dakotas, plains, and desert ecoregions have the greatest percentages of intermittent first order and intermittent higher order streams. In the Upper Colorado River Basin, >50% of reaches are intermittent first order, and 9% are perennial first order. NHDPlus data can significantly underestimate the length of headwater and intermittent streams, but can still be a valuable tool to help develop stream classes and for regional JD planning and analysis. Refinement of the stream classes using high resolution NHD data and other key catchment parameters can improve their utility for JDs.     

Assessing aquaculture sustainability: a comparative methodology

Little work dealing with the evaluation of aquaculture system sustainability has so far been undertaken on a global and comparative basis. Moreover, such work is mostly based on very unbalanced approaches in terms of the dimensions of sustainable development that are taken into account. The approach adopted in this article is designed to encompass all the dimensions of sustainability including the institutional one (governance). The taking into account of this latter, in particular, together with the role played by aquaculture in sustainability at the territorial level gives the approach its original and innovative nature. The process of establishing the checklist of sustainability indicators in aquaculture relies on a hierarchical nesting approach which makes it possible to link indicators with general sustainability criteria and principles. At once multidisciplinary and participatory, the approach compares several countries with highly differentiated types of aquaculture system. An original finding from this work is that the technically most intensive farming model scores better than more extensive systems, which might have been thought to be closer to natural systems in their environmental dimension and therefore intuitively more ‘sustainable’. This result suggests relating sustainability outcomes to the level of control and of devolved responsibilities.     

Origin and Distribution of Suspended Organic Matter As Inferred From Carbon Isotope Composition in A Mediterranean Semi-Enclosed Marine System

The origin and distribution of suspended organic matter, the trophic features and the stable carbon isotopic composition of particulate organic carbon (POC) were studied monthly in a Western Mediterranean semi-enclosed basin. Sampling stations were selected as a function of wind-exposure and the degree of vegetation cover and then compared with an adjacent unvegetated site. the predominant vegetation was seagrass (Posidonia oceanica and Cymodocea nodosa) and Caulerpa prolifera. Water samples were analyzed for total suspended matter (inorganic and organic fractions), photosynthetic pigments (chlorophyll-a and phaeopigments), dissolved organic carbon, particulate organic carbon and their isotopic composition. Temperature and salinity were also measured at the same sampling sites within range of Mediterranean limits. the suspended organic matter concentration was 1.77 ± 1.55 mg l^-1; the chlorophyll-a concentration was low (0.35 ± 0.24 μg l^-1); the disolved organic carbon concentration was 2,140 ± 2,010 μg l^-1; the particulate organic carbon concentration was 212 ± 106 μg l^-1 and the isotopic composition was 18.77 ± 2.51%_°. There were significant temporal differences except for phaeopigments, POC and its POC isotopic composition, and there were no spatial differences other than for δ¹³C. This picture highlighted a general seasonal trend and trophical features similar to adjacent sea.

Spatial differences in δ¹³C showed that the source of suspended organic matter was different between stations as that between sources and wind-hydrodynamic constraints. In     

Determination of organophosphorus fire retardants and plasticizers in wastewater samples using MAE-SPME with GC-ICPMS and GC-TOFMS detection

Determination of organophosphorus fire retardants and plasticizers at trace levels in wastewater is described. In this work, microwave assisted extraction (MAE) and solid-phase microextraction (SPME) are used for sample preparation to extract and preconcentrate the analytes, followed by analysis by gas chromatography coupled to inductively coupled plasma mass spectrometry (GC-ICP-MS) for phosphorus-specific detection. Gas chromatography coupled to time of flight mass spectrometry (GC-TOF-MS) was used to confirm the organphosphorus fire retardants in wastewater. The detection limits of organophosphorus fire retardants (OPFRs) were 29 ng L(-1) for tri-n-butyl phosphate (TnBP), 45 ng for L(-1) for tris(2-butoxyethyl)phosphate (TBEP), and 50 ng L(-1) for tris(2-ethylhexyl)phosphate (TEHP). Optimized extraction conditions were performed at 65 degrees C for 30 min and with 10% NaCl. Application of MAE during the sample preparation prior to the SPME allowed the detection of tris(2-ethylhexyl) phosphate, which has been difficult to determine in previous work. Application of the method to wastewater samples resulted in detecting 3.1 microg L(-1) P from TnBP, 5.0 microg L(-1) P from TBEP, and 4.0 microg L(-1) P from TEHP. The presence of these compounds were also confirmed by SPME-GC-TOF-MS.