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101.
Toxicity of copper excess on the lichen Dermatocarpon luridum: antioxidant enzyme activities 总被引:2,自引:0,他引:2
The aim of this study was to investigate the toxicity of copper on the aquatic lichen Dermatocarpon luridum focusing on the activities of some antioxidant enzymes. Investigations were conducted using increasing copper concentrations (0.00, 0.25, 0.50, 0.75 and 1.00 mM CuSO(4) x 5H(2)O) in synthetic freshwater that emulated the major ion compositions of its natural water biota; time course measurement was 0, 3, 6, 12, 24 and 48 h. The copper concentration in thalli increased with its increase in the medium and the duration of treatment. Copper induced lipid peroxidation, measured using the hydroperoxi-conjugated dienes (HPCD) concentration. The decrease in the protein concentrations was similar in thalli exposed to copper concentrations above 0.50 mM and the decrease was twice lower in thalli exposed to 0.25 mM copper. The activities of antioxidant enzymes measured were differently affected by copper excess. For 0.25 mM copper, the activities of SOD (superoxide dismutase) and APX (ascorbate peroxidase) were unchanged when compared with unstressed thalli whereas the CAT (catalase) activity increased and the GR (glutathione reductase) activity decreased. The activities of SOD and APX increased in thalli exposed to concentrations above 0.50mM copper. The CAT activity increased after the first 3h of experiments at these concentrations and then decreased with the duration of treatment at an activity lower than in the unstressed plant. Whereas the APX activity increased, the GR activity similarly decreased for the copper concentration tested whatever the duration of the experiment. 相似文献
102.
Pyrolysis experiments were conducted to elucidate the effects of metal chlorides on the thermal degradation of low-density polyethylene on a continuous pyrolysis temperature range of 600 degrees C to 1100 degrees C. The present work focusses on the ratio of aromatics generated on increasing the pyrolysis temperature in the presence of metal salts, iron(II), iron(III) and copper(II) chlorides. It was observed that beside alpha,omega-dienes, alpha-olefins and n-alkanes which are usually observed during the thermal decomposition of polyethylene, the level of aromatics noticeably increases with the addition of metal salts. At high temperatures, the formation of these aromatics took place in such a way that they become the major products when polyethylene is pyrolyzed in presence of FeCl(3) and CuCl(2). Quantification of the effect of metal salts has been tempted comparing the variation of the ratio of aromatics with pyrolysis temperatures. Mechanisms responsible for the formation of these aromatics in presence of metal salts have been tentatively investigated. They are proposed to result from cyclization/dehydrogenation reactions similar to those observed during the thermal decomposition of polyethylene, but with an increased efficiency due to the metal salts. 相似文献
103.
The degradation of metribuzin [4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one] as influenced by soil type, temperature, humidity, organic fertilizers, soil sterilization, and ultra-violet radiation was studied in two soil types of Lebanon under laboratory conditions. The two soil types were sandy loam and clay. Deamination of metribuzin in the sandy loam soil to its deaminometribuzin (DA) derivative was basically a result of biological activity. In the clay soil the first metabolite diketometribuzin (DK) was a result of oxidative desulfuration, while diketo-deaminometribuzin (DADK) was the product of reductive deamination. The two soils represented major differences in the pesticide transformation processes. Photodecomposition on the soil surface and in aqueous media was also an important process in the degradation of metribuzin. Furthermore, the increase in soil organic matter enhanced degradation. 相似文献
104.
Schertz M Michel H Barci-Funel G Barci V 《Journal of environmental radioactivity》2006,85(2-3):380-388
Transuranics and fission products have been measured in lake sediment samples, collected in an alpine wetland, to determine their vertical distribution and calculate inventories. The radionuclides considered are 90Sr, 137Cs, 238Pu, 239/240Pu and 241Am. From the results, a better knowledge of radionuclide accumulation mode and behaviour was obtained. In addition, the origins of the individual pollutants could be deduced from activity ratios. Analyses were made on different sediment cores. The sampling sites were chosen to enable future determination of the mass balances of the radiopollutants. As the selected study area is in a recreational area used by urban populations, a rough estimate was made of the mean external dose from 137Cs for comparison with the French regulation. 相似文献
105.
106.
Jaïro Falla Philippe Laval-Gilly Michel Henryon Dominique Morlot Jean-françois Ferard 《Environmental monitoring and assessment》2000,64(3):627-644
Air quality monitoring is currently ensured by captors measuring few physicochemical parameters, then they cannot evaluate unforeseen compounds and the interaction effects of pollutants. On the contrary, the use of bioindicators can answer these problems. Among them, plants are used in two ways:1) Passive bioindicators: trees, lichens and mosses are used to determine the distribution and even the contaminants long-term effects on vast zones and, possibly, the concentrations of pollutants to which they were exposed.2) Active bioindicators: tobacco and mosses make available the defective zones in plants and enable determination of deposition fluxes.Moreover, techniques based on biomarkers identification should increase the answer's sensitivity. However, the plants present the disadvantage of being unable to provide a response in a time lapse comparable with that of the on-line analysers. Lastly, the development of tools using animal cells should allow, in the near future, to measure the total polluting load under conditions close to those of the routine techniques. Then, the real impact of the contaminant on public health could be approached. 相似文献
107.
Michel Jules Dreyfus-Len 《Ecological modelling》1999,120(2-3)
A model to mimic the search behaviour of fishermen is built with two neural networks to cope with two separate decision-making processes in fishing activities. One neural network deals with decisions to stay or move to new fishing grounds and the other is constructed for the purpose of finding prey within the fishing areas. Some similarities with the behaviour of real fishermen are found: concentrated local search once a prey has been located to increase the probability of remaining near a prey patch and the straightforward movement to other fishing grounds. The artificial fisherman prefers areas near the port when conditions in different fishing grounds are similar or when there is high uncertainty in its world. In the latter case a reluctance to navigate to other areas is observed. The artificial fisherman selects areas with higher concentration of prey, even if they are far from the port of departure, unless a high uncertainty is related to the fishing ground. Connected areas are preferred and followed in orderly fashion if a higher catch is expected. The observed behaviour of the artificial fisherman in uncertain scenarios can be described as a risk-averse attitude. The approach seems appropriate for an individual-based modelling of fishery systems, focusing on the learning and adaptive characteristics of fishermen and on interactions that take place at a fine scale. 相似文献
108.
Laurent Dupont Jamila Bouanda Jacques Dumonceau Michel Aplincourt 《Environmental Chemistry Letters》2005,2(4):165-168
We studied the removal of copper and zinc ions from aqueous solutions using a lignocellulosic substrate obtained by an acido-basic treatment of wheat bran. The sorption capacity of this material was investigated through batch and column experiments. Batch experimental results showed that the retention capacity of the lignocellulosic substrate was 0.20×10–3 mol g–1 at pH 4.5 for copper(II) and 0.24×10–3 mol g–1 at pH 6.5 for zinc(II). Column experiments showed a reduced sorption capacity for both ions compared to batch experiments. Batch and column data were analysed using the Langmuir equation in order to determine the affinity constant and the binding capacity of the sorbent and to compare both retention processes. 相似文献
109.
Anik Lambert-Bélanger Sacha Dubois Bruce Weaver Nadia Mullen Michel Bédard 《Journal of Safety Research》2012,43(5-6):333-338
IntroductionWe wished to determine the extent to which number of passengers, driver age, and sex were associated with aggressive driving actions (ADAs) in young drivers involved in a fatal crash.MethodsWe used U.S. fatal-crash data from Fatality Analysis Reporting System (FARS), 1991 –2008. Proxy measures of aggressive driving included ADA presence and speed differential (posted speed limit minus estimated travel speed). We examined the odds of an ADA and speed differential in young drivers (aged 16 to 25) by passenger status.ResultsCompared to driving alone young drivers (aged 16) had increased odds of an ADA between 14% (OR: 1.14; 95% CI: 1.07; 1.22) and 95% (OR: 1.95; 95% CI: 1.40; 2.74) when accompanied by one and five passengers, respectively. Further, carrying a higher number of passengers was a stronger predictor of speeding in younger drivers.ConclusionsThis study supports the use of graduated licensing approaches. Specifically, developing interventions to reduce aggressive driving appear imperative.Impact on IndustryWhile the results of our study support the use of graduated licensing approaches there is room for improvement. Our study indicates that tackling impaired driving is not sufficient to drastically reduce aggressive driving among the youngest drivers. Further research on young drivers is required to understand the influence of peers and the role of gender on driving behavior. Strategies to reduce aggressive driving behaviors among the youngest drivers may not only prevent crashes during their early driving careers but may also translate into a reduced crash risk over their lifetime. 相似文献
110.