Properties of alkali-activated systems with stone powder sludge

This article investigates the effects of stone powder sludge on the microstructure and strength development of alkali-activated fly ash and blast furnace slag mixes. Stone powder sludge produced from a crushed aggregate factory was used to replace fly ash and granulated blast furnace slag at replacement ratios of 0%, 10%, 20%, and 30% by mass. The unit weight and compressive strength of the samples were measured, and scanning electron microscopy/energy dispersive spectroscopy and X-ray diffraction (XRD) analyses were performed. The test results indicated that the compressive strength of alkali-activated blast furnace slag mixes using stone powder sludge was higher than that of the alkali-activated blast furnace slag control mix, but the compressive strength of alkali-activated fly ash mixes decreased with increasing replacement ratio of stone powder sludge. Microscopy results indicated that for alkaliactivated blast furnace slag samples, broken surfaces were more evident than for the alkali-activated fly ash samples. For all XRD diagrams, broad and diffuse peaks were observed around 2θ = 35° (d = 2.96–3.03 Å), implying amorphous or short-ordering structure phases.     

大港油田苦咸再生水反渗透工艺自动控制研究

分析了大港油田污水回用深度处理工程苦咸再生水反渗透工艺仪表配置及自动控制方式,介绍了苦咸再生水反渗透系统亟待解决的各类问题。着重论述了仪表设置、余氯控制、结垢污堵控制、微生物污堵控制的实际运行方式,探讨了苦咸再生水反渗透工艺的技术可行性和可靠性。     

莱特生物强化技术处理高浓度有机废水的中试

采用莱特生物强化技术(LTBR—Littoral BioReactor),对兰州石化公司化工园区高浓度有机废水进行了中试试验,进行了正常运行的常规标定、水量冲击标定、浓度冲击标定。结果表明:采用LTBR生物处理工艺,使用特效微生物和营养基质,可以在高COD、高含盐等不利条件下正常进行有机物降解,达到了必须将废水中的COD降至2000mg/L以下的试验要求,为处理高浓度有机化工废水的工程应用开辟了新思路。     

Isotopes as tracers of sources of lead and strontium in aerosols (TSP & PM2.5) in Beijing

Even after its being phased out in gasoline in the late 90s, lead (Pb) is still present at relatively high levels in the atmosphere of Beijing, China (0.10–0.18 μg m^?3). Its origin is subject to debate as several distinct sources may contribute to the observed pollution levels. This study proposes to constrain the origin(s) of Pb and strontium (Sr) in aerosols, by coupling both Pb and Sr isotope systematics. The characterisation of the main pollution sources (road traffic, smelters, metal refining plants, coal combustion, cement factories, and soil erosion) shows that they can unambiguously be discriminated by the multi-isotope approach (²⁰⁶Pb/²⁰⁴Pb and ⁸⁷Sr/⁸⁶Sr). The study of total suspended particulates (TSP) and fine particles (PM_2.5) from Beijing and its vicinity indicates that both size fractions are controlled by the same sources. Lead isotopes indicate that metal refining plants are the major source of atmospheric lead, followed by thermal power stations and other coal combustion processes. The role of this latter source is confirmed by the study of strontium isotopes. Occasionally, emissions from cement plants and/or input from soil alteration are isotopically detectable.     

Concentration and characterization of plutonium in soils of Hubei in central China

To study the Pu concentration and isotope ratio distributions present in China, the ^239+240Pu total activities and ²⁴⁰Pu/²³⁹Pu atom ratios in core soil samples from Hubei Province in central China were investigated using Accelerator Mass Spectrometry (AMS). The activities ranged from 0.019 to 0.502 mBq g⁻¹ and the ^239+240Pu inventories of 45 and ∼55 Bq m⁻² agree well with that expected from global fallout. The ²⁴⁰Pu/²³⁹Pu atom ratios in the soil ranged from 0.172 to 0.220. The ratios are similar to typical global fallout values. Hence, any close-in fallout contribution from the Chinese nuclear weapons tests, mainly conducted in the 1970s, must have either been negligible or had a similar ²⁴⁰Pu/²³⁹Pu ratio to that of global fallout. The top 10 cm layer of the soil contributes ∼90% of the total inventory and the maximum concentrations appeared in the 2-4 cm or 4-6 cm layers. It is suggested that climatic conditions and organic content are the two main factors that affect the vertical migration of plutonium in soil.     

中国环境效率评价及其影响因素实证研究

环境效率是实际污染排放和潜在污染排放的一种度量。本文运用包含污染排放的环境DEA模型,测算了1998-2007年中国省际环境效率,检验了其收敛情况。结果显示,全国环境效率总体水平较低,省际、区域间差距较大,表明现阶段实行地区间减排合作、推动环保技术在区域间扩散的现实必要性;分别从20032、005年开始,省际、区域环境效率差距逐渐缩小,存在一定的收敛趋势;同时,本文采用Tobit模型分析了影响环境效率因素,研究发现人均GDP对提高环境效率具有积极影响,而工业比重上升、财政分权度的提高以及贸易自由化对环境效率具有显著的负面影响。最后,基于实证研究的结果,就减少地区污染排放、提高我国环境效率给出了相关政策建议。     

城市规划区内集体土地房屋拆迁制度研究

由于国家层面统一立法的缺失,我国各地城市规划区内集体土地房屋拆迁制度,如房屋拆迁是否涉及土地征收、房屋拆迁许可的条件及实施、拆迁法律关系的内容及争议的解决等方面存在较大差异,并且在是否适用、如何适用国务院《城市房屋拆迁管理条例》方面也不相同。这种状况一方面体现了各地方不同经济社会发展水平的要求,说明城市规划区内集体土地房屋拆迁与国有土地房屋拆迁存在区别,具有一定的合理性;另一方面对这种差异若不给予必要的规控和调整,也有可能对我国的法制统一造成负面影响。因此,通过对地方立法文本的比较与分析,将有助于各地方在制度完善中相互取长补短,进而为该领域的统一立法奠定坚实基础。依照国务院修改《城市房屋拆迁管理条例》的基本思路,城市规划区内集体土地房屋拆迁立法应当尽可能地全国统一立法,并做到先补偿再征收、先征收再拆迁,并强化拆迁许可证的管理。     

2005年秋季长江口及其邻近水域浮游植物群集

采用Utermhl分析方法,对长江口及其邻近水域（30.5° ~ 32.5° N,121.0° ~ 123.5° E）2005年秋季浮游植物进行了分析,并对其与环境之间的关系做了进一步的探讨。结果表明：调查区初步鉴定浮游植物95种（含变种和变型）,硅藻是主要的浮游植物类群,其丰度比例达到93.1%;生态类型多为温带近岸种,少数为暖水种和大洋种;优势种主要为中肋骨条藻〖WTBX〗（Skeletonema costatum）、具槽帕拉藻（Paralia sulcata）、菱形海线藻（Thalassionema nitzschioides）和圆海链藻（Thalassiosira rotula）〖WTBZ〗;浮游植物平均丰度为2.04 cells/mL,高值出现在长江口门偏南水域;Margalef指数、Shannon Wiener指数以及Pielou指数的分布显示：秋季调查区离岸海域浮游植物多样性程度高,物种均一性好。Pearson相关分析结果显示：海水温度和硝酸盐含量是控制调查区浮游植物分布格局的主要环境因子;优势种中肋骨条藻与温度呈极显著负相关,与硝酸盐呈极显著正相关。     

Pb and Cd binding to natural freshwater biofilms developed at different pH: the important role of culture pH

The effects of solution pH on adsorption of trace metals to different types of natural aquatic solid materials have been studied extensively, but few studies have been carried out to investigate the effect of pH at which the solid materials were formed on the adsorption. The purpose of present study is to examine this effect of culture pH on metal adsorption to natural freshwater biofilms. The adsorption of Pb and Cd to biofilms which were developed at different culture pH values (ranging from 6.5 to 9.0) was measured at the same adsorption pH value (6.5). The culture pH had considerable effects on both composition and metal adsorption ability of the biofilms. Higher culture pH usually promoted the accumulation of organic material and Fe oxides in the biofilms. The culture pH also affected the quantity and species of algae in the biofilms. The adsorption of Pb and Cd to the biofilms generally increased with the increase of culture pH. This increase was minor at lower pH range and significant at higher pH range and was more remarkable for Cd adsorption than for Pb adsorption. The notable contribution of organic material to the adsorption at higher culture pH values was also observed. The profound impacts of culture pH on adsorption behavior of biofilms mainly resulted from the variation of total contents of the biofilm components and were also affected by the alteration of composition and properties of the components.